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Abstrakty
Nano TiO2 and TiO2/MWCNT nanocomposite synthesized by the sol-gel method were characterized by XRD, BET, SEM, EDAX and FTIR techniques. These nanoparticles were used for photocatalytic decolorisation and degradation of three different reactive dyes such as Reactive Orange 16 (RO 16), Reactive Yellow 145 (RY 145) and Reactive Red 195 (RR 195) and real textile composite wastewater under the UVA and UVA-LED irradiation at room temperature. The maximum color removal of 96% and COD removal of 72% were achieved after 5 h in the presence of TiO2/MWCNT and H2O2 under UVA-LED irradiation. The kinetic studies obey pseudo-first order kinetics which is discussed in terms of the Langmuir–Hinshelwood kinetic model. The maximum degradation of 50% was achieved after 5 h in the presence of H2O2 using TiO2/MWCNT/UVA-LED for real textile composite wastewater. This study revealed that TiO2/MWCNT has improved the photocatalytic activity when compared to that of bare TiO2 under similar conditions. UVA-LED could be an alternative light source for the replacement of the conventional UV light for the photocatalytic treatment of reactive dyes.
Czasopismo
Rocznik
Tom
Strony
95--116
Opis fizyczny
Bibliogr. 30 poz., tab., rys.
Twórcy
autor
- Centre for Environmental Studies, Anna University, Chennai – 600025, Tamil Nadu, India
autor
- Centre for Environmental Studies, Anna University, Chennai – 600025, Tamil Nadu, India
Bibliografia
- [1] NATARAJAN T.S., NATARAJAN K., BAJAJ H.C., TAYADE R.J., Energy efficient UV-LED source and TiO2 nanotube array-based reactor for photocatalytic application, Ind. Eng. Chem. Res., 2011, 50, 7753.
- [2] TAYADE R.J., NATARAJAN T.S., BAJAJ H.C., Photocatalytic degradation of methylene blue dye using ultraviolet light emitting diodes, Ind. Eng. Chem. Res., 2009, 48, 10262.
- [3] NATARAJAN K., NATARAJAN T.S., BAJAJ H.C., TAYADE R.J., Photocatalytic reactor based on UV-LED/TiO2 coated quartz tube for degradation of dyes, Chem. Eng. J., 2011, 178, 40.
- [4] NATARAJAN T.S., THOMAS M., NATARAJAN K., BAJAJ H.C., Study on UV-LED/TiO2 process for degradation of Rhodamine B dye, Chem. Eng. J., 2011, 169, 126.
- [5] ZHAO D., YANG X., CHEN C., WANG X., Enhanced photocatalytic degradation of methylene blue on multiwalled carbon nanotubes–TiO2, J. Coll. Int. Sci., 2013, 398, 234.
- [6] CHAUDHARY D., ANSARI M.Z., KHARE N., VANKAR V.D., Preparation, characterization and photocatalytic activity of anatase, rutile TiO2/multiwalled carbon nanotubes nanocomposite for organic dye degradation, J. Nanosci. Nanotechnol., 2017, 17, 1894.
- [7] HSIEH S.-H., CHEN W.-J., Synthesis and characterization of TiO2/CNT nanocomposites for azo dye degradation, Mater. Sci. Forum, 2017, 909, 243.
- [8] HAMID S.B.A., TAN T.L., LAI C.W., SAMSUDIN E.M., Multiwalled carbon nanotube/TiO2 nanocomposite as a highly active photocatalyst for photodegradation of reactive black 5 dye, Chinese. J. Cat., 2014, 35, 2014.
- [9] NATARAJAN K., KURESHY R.I., BAJAJ H.C., TAYADER J., Photocatalytic degradation of Indigo carmine dye using hydrothermally synthesized anatase TiO2 nanotubes under ultraviolet light emitting diode irradiation, Mater. Sci. Forum Online: 2016-05-19 ISSN: 1662-9752, 855, 45.
- [10] YANG C.-C., DOONG R.-A., CHEN K.-F., CHEN G.-S., TSAI Y.-P., The photocatalytic degradation of methylene blue by green semiconductor films that is induced by irradiation by a light emitting diode and visible light, J. Air Waste Manage. Assoc., 2018, 69 (1), 29.
- [11] BUITRAGO L.A.B., VASQUEZ C., VEITIA L., ECHEVERRY O.O., VALLEJO J.R., BURGOS J.B., CABRALES N.M., MARTÍNEZ F.M., An approach to the utilization of artificial high power LED UV-A radiation in photoreactors for methylene blue degradation, Photochem. Photobiol. Sci., 2017, 16, 79.
- [12] JO W.K., TAYADE R.J., Facile photocatalytic reactor development using nano-TiO2 immobilized mosquito net and energy efficient UVLED for industrial dyes effluent treatment, J. Environ. Chem. Eng., 2016, 4, 319.
- [13] SILVEIRA J.E., CLARO E., PAZ W., OLIVEIRA A., ZAZO J.A., CASAS J.A., Optimization of Disperse Blue 3 mineralization by UV-LED/FeTiO3 activated persulfate using response surface methodology, J. Taiwan Inst. Chem. Eng., 2017, 1.
- [14] SHARMA A., KARN R.K., PANDIYAN S.K., Synthesis of TiO2 nanoparticles by sol-gel method and their characterisation, J. Basic Appl. Eng. Res., 2014, 1, 1.
- [15] DIN 38 404, German methods for the examination of water, wastewater and sludge, physical and physical-chemical parameters (group C). Determination of color, Deutsches Inst. für Normung, Berlin 1991, 1.
- [16] SONI H., KUMAR J.I.N., PATEL K., KUMAR R.N., Photocatalytic decoloration of three commercial dyes in aqueous phase and industrial effluents using TiO2 nanoparticles, Desalin. Water Treat., 2016, 57, 6355.
- [17] KOLI V.B., DHODAMANI A.G., DELEKAR S.D., PAWAR S.H., In situ sol-gel synthesis of anatase TiO2-MWCNTs nanocomposites and their photocatalytic applications, J. Photochem. Photobiol., A, Chem., 2017, 333, 40.
- [18] MAMBA G, MBIANDA X.Y.,MISHRA A.K., Enhanced visible light photocatalytic degradation of Erichrome Black T and Eiosin Blue shade in water using tridopedtitania decorated on SWCNTs and MWCNTs. Effects of the type of carbon nanotube incorporated, Mater. Chem. Phys., 2015, 149–150, 734.
- [19] MAMBA G., MBIANDA X.Y., MISHRA A.K., Gadolinium oxide decorated multiwalled carbon nanotube/ tridoped titania nanocomposites or improved dye degradation under simulated solar light irradiation, Mater. Res. Bull., 2016, 75, 59.
- [20] FLORES U.C., ROMERO J.L., MEDINA J.Z., BATISTA M.J.M., ACUNA R.H., MUNOZ E.M.R., CORTES J.R., Enhanced photocatalytic activity of MWCNT/TiO2 heterojunction photocatalysts obtained by microwave assisted synthesis, Catal. Today, 2016, 266, 102.
- [21] LI X., WANG T., QU G., LIANG D., HU S., Enhanced degradation of azo dye in wastewater by pulsed discharge plasma coupled with MWCNTs-TiO2/γ-Al2O3 composite photocatalyst, J. Environ. Manage., 2016, 172, 186.
- [22] GIWA A., NKEONYE P.O., BELLO K.A., KOLAWOLE E.G., Solar photocatalytic degradation of Reactive Yellow 81 and reactive violet 1 in aqueous solution containing semiconductor oxides, Int. J. Appl. Sci. Technol., 2012, 2 (4), 90.
- [23] ALAHIANE S., QOURZAL S., OUARDI M.E., ABAAMRANE A., ASSABBANE A., Factors influencing the photocatalytic degradation of Reactive Yellow 145 by TiO2-coated non-woven fibers, Am. J. Anal. Chem., 2014, 5, 445.
- [24] VIJAYAN B.K., DIMITRIJEVIC N.M., SHAPIRO D.F., WU J., GRAY K.A., Coupling titania nanotubes and carbon nanotubes to create photocatalytic nanocomposites, ACS Catal., 2012, 2, 223.
- [25] WANG W., SERP P., KALCK P., FARIA J.L., Visible light photodegradation of phenol on MWNT-TiO2 composite catalysts prepared by a modified sol-gel method, J. Mol. Catal. A, Chem., 2005, 235, 194.
- [26] KAUR N., KAUR S., SINGHA V., Preparation, characterization and photocatalytic degradation kinetics of Reactive Red dye 198 using N, Fe codoped TiO2 nanoparticles under visible light, Desalin. WaterTreat., 2015, 1.
- [27] LEI Z., ZEDA M., CHUN O.W., Fabrication and characterisation of tailored TiO2 and WO3/MWCNT composites for methylene blue decomposition, Chinese J. Catal., 2011, 32, 926.
- [28] ZOUZELKA R., KUSUMAWATI Y., REMZOVA M., RATHOUSKY J., Photocatalytic activity of porous multiwalled carbon nanotube-TiO2 composite layers for pollutant degradation, J. Hazard. Mater., 2016, 3117, 52.
- [29] MAHMOODI N.M., Photocatalytic degradation of dyes using carbon nanotube and titania nanoparticle, Water, Air, Soil Poll., 2013, 224, 1612.
- [30] KHAN W.Z, NAJEEB I., ISHTIAQUE S., Photocatalytic degradation of a real textile wastewater using titanium dioxide, zinc oxide and hydrogen peroxide, Int. J. Eng. Sci., 2016, 5, 7, 61.
Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-7d2c60d7-80d7-46a3-b180-862a56ab3965