Assessing some advanced oxidation processes in the abatement of phenol aqueous solutions

• Autorzy: Jaramillo-Sierra Bethsabet , Mercado-Cabrera Antonio , Peña-Eguiluz Rosendo , Hernández-Arias Alma Neli , López-Callejas Régulo , Rodríguez-Méndez Benjamín Gonzalo , Valencia-Alvarado Raúl

Identyfikatory

DOI

10.5277/epe190302

• Języki publikacji: EN

Abstrakty

EN

In this work, phenol oxidation in aqueous solution promoted by the effect of the oxidizing agents H₂O₂, O₃ and UV radiation and their synergy in four different advanced oxidation processes (O₃, O₃/UV, H₂O₂/O₃ and O₃/H₂O₂/UV) were assayed. Studies were performed with a closed-loop hydraulic circuit set up with a relatively high volume of solution (500 cm³) during 90 min of treatment time. Parameters such as concentration for oxidizing species, pH, presence of UV irradiation were evaluated. The resulting degradation efficiencies were evaluated using GC-MS. The agents here used were selected considering their ease of handling and low toxicity, generation of deposited matter or sludge, so a filtration treatment for the analysis of the samples was not required. In all cases, it was observed that with increasing treatment time better degradation efficiencies were obtained. The best results were obtained with the combination of O₃/H₂O₂/UV where up to 95% degradation was attained at pH 9, which is due to active species generated in the process, e.g., O₃ and OH˙, on the contaminant. SPE was performed for determining the presence of several by-products, mainly: catechol, resorcinol and hydroquinone, which were identified.

Słowa kluczowe

EN

AOP; oxidation of phenol; Advanced Oxidation Processes

PL

AOP; utlenianie fenolu; zaawansowane metody utleniania

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2019
• Tom: Vol. 45, nr 3
• Strony: 23--38
• Opis fizyczny: Bibliogr. 25 poz., tab., rys.

Twórcy

autor

Jaramillo-Sierra Bethsabet

• Tecnológico de Estudios Superiores de Tianguistenco, Carretera Tenango-La Marquesa km 22, Santiago Tianguistenco, Estado de México, C.P. 52650, México

autor

Mercado-Cabrera Antonio

• Instituto Nacional de Investigaciones Nucleares, Plasma Physics Laboratory AP 18-1027,11801 CDMX, México

autor

Peña-Eguiluz Rosendo

• Instituto Nacional de Investigaciones Nucleares, Plasma Physics Laboratory AP 18-1027,11801 CDMX, México

autor

Hernández-Arias Alma Neli

• Tecnológico de Estudios Superiores de Tianguistenco, Carretera Tenango-La Marquesa km 22, Santiago Tianguistenco, Estado de México, C.P. 52650, México

autor

López-Callejas Régulo

• Instituto Nacional de Investigaciones Nucleares, Plasma Physics Laboratory AP 18-1027,11801 CDMX, México

autor

Rodríguez-Méndez Benjamín Gonzalo

• Instituto Nacional de Investigaciones Nucleares, Plasma Physics Laboratory AP 18-1027,11801 CDMX, México

autor

Valencia-Alvarado Raúl

• Instituto Nacional de Investigaciones Nucleares, Plasma Physics Laboratory AP 18-1027,11801 CDMX, México

Bibliografia

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).