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Higher - order field - dependent terms in spin Hamiltonians for transition ions : implications for high - magnetic field and high - frequency EMR measurements

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Treść / Zawartość
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Warianty tytułu
Konferencja
Electron Magnetic Resonance Forum EMR-PL (2; 16-18.05.2013; Częstochowa-Hucisko, Poland )
Języki publikacji
EN
Abstrakty
EN
An overview of theoretical background of the higher-order field-dependent (HOFD) terms in the generalized spin Hamiltonians for transition ions and current status of experimental studies of the HOFD terms is provided in the nutshell. The terms nonlinear in the magnetic field (B) of the type: B2S2, B3S, B5S or B2I2, B3I, B5I, where S and I is the electronic and nuclear spin, respectively, are of particular importance as compared with the usual linear Zeeman term B.g.S. This is due to the high B values, up to 100 T (pulsed fields), achievable at present in the high-magnetic field and/ or high-frequency electron magnetic resonance (HMF-EMR) measurements of magnetic and spectroscopic properties. A blueprint for future theoretical and experimental studies of the HOFD terms is proposed taking into account their implications for HMF-EMR measurements
Czasopismo
Rocznik
Strony
341--345
Opis fizyczny
Bibliogr. 27 poz., rys.
Twórcy
autor
  • Institute of Physics, West Pomeranian University of Technology, 17 Piastów Ave., 70-310 Szczecin, Poland, Tel.: +48 91 449 4585, Fax: +48 91 449 4181
Bibliografia
  • 1. Andersson KK, Peter P, Schmidt PP et al. (2003) Examples of high-frequency EPR studies in bioinorganic chemistry. J Biol Inorg Chem 8:235–247
  • 2. Aripin, Mitsudo S, Shirai T et al. (1999) Submillimeter wave ESR measurement for Cr3+ in ruby crystal using a gyrotron as a radiation source. Int J Infrared Millimeter Waves 20:1875–1887
  • 3. Bennati M, Prisner TF (2005) New developments in high field electron paramagnetic resonance with applications in structural biology. Rep Prog Phys 68:411–448
  • 4. Carretta P, Lascairlfari A (eds) (2007) NMR-MRI, μSR and Mössbauer spectroscopy in molecular magnets. Springer, New York
  • 5. Fittipaldi M, Sorace L, Barra AL et al. (2009) Molecular nanomagnets and magnetic nanoparticles: the EMR contribution to a common approach. Phys Chem Chem Phys 11:6555–6568
  • 6. Friedman JR, Sarachik MP (2010) Single-molecule magnets. Annu Rev Condens Matter Phys 1:109–128
  • 7. Gatteschi D, Sessoli R, Villain J (2006) Molecular nanomagnets. Oxford University Press, Oxford
  • 8. Grinberg O, Berliner LJ (eds) (2004) Very high frequency (VHF) ESR/EPR. Series: Biological magnetic resonance, vol. 22. Kluwer Academic, New York
  • 9. Hagiwara M, Kashiwagi T, Kimura S et al. (2007) Novel spin excitation in the high field phase of an S = 1 antiferromagnetic chain. J Magn Magn Mater 310:1272–1274
  • 10. Imanaka Y, Miura N, Nojiri H et al. (1998) ESR study of the Haldane gap system Y2BaNiO5 in high magnetic fields. Physica B 246/247:561–564
  • 11. Inagaki Y, Takeda S, Okubo S et al. (2004) Direct determination of magnetic anisotropy in S = 1 bond alternating system by high field ESR. J Magn Magn Mater 272/276:e661–e662
  • 12. Kimura S, Hagiwara M, Takeuchi T et al. (2011) Large change in the exchange interactions of HgCr2O4 under very high magnetic fields. Phys Rev B 83:214401-6
  • 13. Kuroda S, Motokawa M, Date M (1978) SH3 term in submillimeter ESR of cobalt Tutton salt. J Phys Soc Jpn 44:1797–1803
  • 14. Mabbs FE, Collison D (1992) Electron paramagnetic resonance of d transition-metal compounds. Elsevier, Amsterdam
  • 15. McGavin DG, Tennant WC (2009) Higher-order Zeeman and spin terms in the electron paramagnetic resonance spin Hamiltonian; their description in irreducible form using Cartesian, tesseral spherical tensor and Stevens’ operator expressions. J Phys: Condens Matter 21:245501 (14 pp)
  • 16. Motokawa M (2004) Physics in high magnetic fields. Rep Prog Phys 67:1995–2052
  • 17. Pilbrow JR (1990) Transition-ion electron paramagnetic resonance. Clarendon Press, Oxford
  • 18. Rudowicz C (1987) Concept of spin Hamiltonian, forms of zero field splitting and electronic Zeeman Hamiltonians and relations between parameters used in EPR. A critical review. Magn Reson Rev 13:1–89
  • 19. Rudowicz C, Chung CY (2004) Generalization of the extended Stevens operators to higher ranks and spins and systematic review of the tables of the tensor operators and their matrix elements. J Phys: Condens Matter 16:5825–5847
  • 20. Rudowicz C, Gnutek P (2009) Modeling techniques for analysis and interpretation of electron magnetic resonance (EMR) data for transition ions at low symmetry sites in crystals – a primer for experimentalists. Physica B 404:3582–3593
  • 21. Rudowicz C, Misra SK (2001) Spin-Hamiltonian formalisms in electron magnetic resonance (EMR) & related spectroscopies. Appl Spectrosc Rev 36:11–63
  • 22. Rudowicz C, Sung HWF (2003) Characteristics of the magnetically ordered high-spin S=2 Fe2+ ion systems potentially suitable for high-magnetic-field and high-frequency EMR studies. J Phys Soc Jpn 72;Suppl B:61–83
  • 23. Sakurai T, Taketani A, Tomita T et al. (2007) Development of high-pressure, high-field and multifrequency electron spin resonance system. Rev Sci Instrum 78:065107-6
  • 24. Santini P, Carretta S, Amoretti G et al. (2009) Multipolar interactions in f-electron systems: The paradigm of actinide dioxides. Rev Mod Phys 81:807–836
  • 25. Ubbink M, Worrall JAR, Canters GW (2002) Paramagnetic resonance of biological metal centers. Annu Rev Biophys Biomol Struct 31:393–422
  • 26. van Slageren J, Vongtragool S, Gorshunov B (2003) Frequency-domain magnetic resonance spectroscopy of molecular magnetic materials. Phys Chem Chem Phys 5:3837–3843
  • 27. Weil JA, Bolton JR, Wertz JE (1994) Electron paramagnetic resonance, elemental theory and practical applications. Wiley, New York
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-7ba39d72-5f0a-41f1-b096-99deeeb6c7a4
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