Novel multicomponent functionalized biopolymers with enhanced thermal and dielectric properties

Rani, Sanjeeta; Ali, Syed Kashif; Kumar, Pawan; Anugrah, Kunwar Sugam; Saya, Laishram; Gambhir, Geetu; Gautam, Drashya; Hooda, Sunita; Verma, Manisha

doi:10.14314/polimery.2023.7.4

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Tytuł artykułu

Novel multicomponent functionalized biopolymers with enhanced thermal and dielectric properties

Autorzy

Rani Sanjeeta , Ali Syed Kashif , Kumar Pawan , Anugrah Kunwar Sugam , Saya Laishram , Gambhir Geetu , Gautam Drashya , Hooda Sunita , Verma Manisha

Treść / Zawartość

Pełne teksty:

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Identyfikatory

DOI

10.14314/polimery.2023.7.4

Warianty tytułu

Nowe wieloskładnikowe funkcjonalizowane biopolimery o poprawionych właściwościach termicznych i dielektrycznych

Języki publikacji

Abstrakty

A new functionalized biopolymer was obtained by modifying chitin using ethylenediaminetetraacetic acid and magnetite nanoparticles (Fe₃O₄). Thermogravimetric analysis was performed, and dielectric properties were examined. The obtained biopolymer showed better thermal stability, as evidenced by a higher onset temperature. The activation energy calculated using imaginary impedance data and Nyquist plots was found to be consistent. Moreover, the dielectric permittivity decreased rapidly with increasing frequency. At high frequencies, there was no dependence of dielectric loss on temperature and frequency. The obtained biopolymer can be used in many applications such as microwave devices, deflection yoke, high-frequency capacitors, sensors, etc.

Otrzymano nowy funkcjonalizowany biopolimer poprzez modyfikację chityny przy użyciu kwasu etylenodiaminotetraoctowego i nanocząstek magnetytu (Fe₃O₄). Przeprowadzono analizę termograwimetryczną i zbadano właściwości dielektryczne. Otrzymany biopolimer wykazywał lepszą stabilność termiczną, o czym świadczyła wyższa temperatura początku rozkładu. Wykazano zgodność energii aktywacji obliczonej z wykorzystaniem danych dotyczących urojonej impedancji oraz na podstawie wykresów Nyquista. Przenikalność dielektryczna zmniejszała się gwałtownie wraz ze wzrostem częstotliwości. Przy wysokich częstotliwościach nie stwierdzono zależności stratności dielektrycznej od temperatury i częstotliwości. Otrzymany biopolimer można wykorzystać w wielu zastosowaniach, takich jak urządzenia mikrofalowe, jarzmo odchylające, kondensatory wysokiej częstotliwości, czujniki itp.

Słowa kluczowe

biopolymers chitin nanoparticles magnetite dielectric properties

biopolimery chityna nanocząstki magnetyt właściwości dielektryczne

Wydawca

Sieć Badawcza Łukasiewicz – Instytut Chemii Przemysłowej

Czasopismo

Polimery

Rocznik

2023

Tom

Vol. 68, nr 7-8

Strony

386--395

Opis fizyczny

Bibliogr. 47 poz., rys., tab., wykr.

Twórcy

autor

Rani Sanjeeta

Department of Physics, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi 110019, India

https://orcid.org/0000-0002-5761-2134

autor

Ali Syed Kashif

Department of Chemistry, Faculty of Science, Jazan University, Jazan P.O. Box 82817, Saudi Arabia

https://orcid.org/0000-0002-3323-6672

autor

Kumar Pawan

Department of Physics, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi 110019, India

https://orcid.org/0009-0001-9464-2404

autor

Anugrah Kunwar Sugam

Department of Physics, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi 110019, India

https://orcid.org/0009-0007-2981-0305

autor

Saya Laishram

Department of Chemistry, Sri Venkateswara College, University of Delhi, Dhaula Kuan, New Delhi 110021, India
Polymer Research Laboratory, Department of Chemistry, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi 110019, India

https://orcid.org/0009-0003-7623-2350

autor

Gambhir Geetu

Advance Chemistry Research Laboratory, Department of Chemistry, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi 110019, India

https://orcid.org/0000-0002-8995-9714

autor

Gautam Drashya

Polymer Research Laboratory, Department of Chemistry, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi 110019, India

https://orcid.org/0000-0002-3374-0465

autor

Hooda Sunita

Polymer Research Laboratory, Department of Chemistry, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi 110019, India

https://orcid.org/0000-0001-8002-400X

autor

Verma Manisha

manishaverma@andc.du.ac.in

Department of Physics, Acharya Narendra Dev College, University of Delhi, Govindpuri, Kalkaji, New Delhi 110019, India

https://orcid.org/0000-0001-9092-2081

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-7ba1998f-36f4-44e3-9d50-65884ee17060