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Geochemical relationships in CO2-rich therapeutic waters of the Sudetes (Poland)

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Geochemical studies of CO2-rich therapeutic waters in the Sudetes have provided new data on a wide range of trace elements, going beyond standard chemical analyses of such waters. A consistent set of physicochemical data obtained using the same analytical methods was subjected to statistical analyses, including hierarchical clustering, factor analysis and nonparametric tests (Kruskal-Wallis, Tau Kendall), to reveal geochemical relationships between physicochemical and chemical parameters in the waters, and their relationships with the aquifer lithology. Distinct differences in the composition of waters found in crystalline rocks (mainly gneisses and mica schists) and sedimentary rocks were identified. The wide range of elements can be associated with the hydrolysis of silicate minerals, including alkali and alkali earth metals (Li, Na, K, Rb, Cs, Be) and (mostly) transition elements (Fe, Mn, Zn, Co, W, Mg). Carbonate equilibria are the next important factor as it determines the aggressiveness of the water towards the minerals of aquifer rocks and affects the concentrations of numerous solutes. The probable common origin of chlorides, bromides and sulphates together with Li, Na, Sr may be related to the relict saline component of deep circulating waters, a hypothesis that requires further investigations.
Rocznik
Strony
479--493
Opis fizyczny
Bibliogr. 36 poz., rys., tab.
Twórcy
  • University of Warsaw, Faculty of Geology, Department of Hydrogeology and Geophysics, Żwirki i Wigury 93, 02-089 Warszawa, Poland
  • University of Warsaw, Faculty of Geology, Department of Hydrogeology and Geophysics, Żwirki i Wigury 93, 02-089 Warszawa, Poland
  • University of Warsaw, Faculty of Geology, Department of Hydrogeology and Geophysics, Żwirki i Wigury 93, 02-089 Warszawa, Poland
  • University of Warsaw, Faculty of Geology, Department of Hydrogeology and Geophysics, Żwirki i Wigury 93, 02-089 Warszawa, Poland
Bibliografia
  • 1. Appelo, C. and Postma, D. 2005. Geochemistry, Groundwater and Pollution. 2nd Edition, Balkema, Rotterdam. https://doi.org/10.1201/9781439833544
  • 2. Bachliński, R. 2002. Petrological, geochemical, and geochronological studies of crystalline rocks from the vicinity of Kudowa. Unpublished PhD Thesis, 114 pp. Institute of Geological Sciences, Polish Academy of Sciences; Warsaw. [In Polish].
  • 3. Bakalowicz, M. 1994. Water geochemistry: Water quality and dynamics. In: Gilbert, J., Danielopol, D. L. and Stanford, J. A. (eds), Groundwater Ecology, 97–127. Academic Press; San Diego.
  • 4. Bażyński, J., Graniczny, M., Oberc, J. and Wilczyński, M.S. 1986. Photogeological Map of the Sudetes Mountains. Wydawnictwa Geologiczne, Warsaw.
  • 5. Ciężkowski, W. 1983. Hydrogeological unit of the Góry Izerskie carbon dioxide waters. Geological Quarterly, 27 (3), 595–604. [In Polish, with English summary]
  • 6. Ciężkowski, W. 1990. A study on the hydrogeochemistry of curative waters in the Polish Sudetes Mountains (SW Poland). Prace Naukowe Instytutu Geotechniki Politechniki Wrocławskiej, 60, 1–133 [In Polish, with English summary].
  • 7. Ciężkowski, W. 2003. CO2-rich waters and radon waters of the Karkonosze Mts-Izerskie Mts block. In: Ciężkowski, W., Wojewoda, J. and Żelaźniewicz, A. (Eds), Western Sudetes from the Wend to the Quaternary, 225–236. Wind; Wrocław. [In Polish, with English summary].
  • 8. Ciężkowski, W., Doktór, S., Graniczny, M., Kabat, T., Kozłowski, J., Liber-Madziarz, E., Przylibski, T., Teisseyre, B., Wiśniewska, M. and Zuber A. 1996. An attempt to determine the recharge areas of infiltration therapeutic water in Poland based on isotopic studies. Deposits: Świeradów, Czerniawa, Szczawno, Polanica, Duszniki, Kudowa, Długopole. Zdroje Ltd. Wrocław. Unpublished. [In Polish]
  • 9. Ciężkowski, W., Kiełczawa, B., Liber-Makowska, E., Przylibski, T. and Żak S. 2016. Mineral waters of the Sudetic region (SW Poland): selected problems. Przegląd Geologiczny, 64 (9), 671–682. [In Polish]
  • 10. Ciężkowski, W. and Zuber, A. 1996. Uncertainty in determining the age of waters by the tritium method on the example of the medicinal waters of the Sudetes Mountains. In: Ciężkowski, W. and Ossowski, J. (Eds), Hydrogeological problems in south-western Poland, 255–261. Wrocław. [In Polish]
  • 11. Dowgiałlo, J. 1978. The origin of carbon dioxide in carbonated waters of the Carpathians and the Sudetes in Poland. Biuletyn Państwowego Instytutu Geologicznego, 312, 191–217. [In Polish with English summary]
  • 12. Dowgiałło, J. and Fistek, J. 2003. New findings in the Wałbrzych-Kłodzko geothermal subregion (Sudetes, Poland). Geothermics, 32, 689–699.
  • 13. Dowgiałło, J. and Fistek, J. 2007. Sudetes Region. In: Paczyński, B. and Sadurski, A. (Eds), Regional hydrogeology of Poland, 2, 57–78. Państwowy Instytut Geologiczny; Warszawa. [In Polish]
  • 14. Dowgiałło, J., Hałas, S., Lis, J., Szaran, J. and Żuk, W. 1973. The isotopic composition of carbon and the origin of CO2 in some Sudetic acidulous waters. Bulletin de L’Academie Polonaise des Sciences, Série des Sciences de la Terre, 21, 2, 89–97.
  • 15. Drever, J.I. 1997. The Geochemistry of Natural Waters. 436 pp. Prentice-Hall; Englewood Cliffs.
  • 16. Fistek, J. 1967. Reconstruction of the CO2-rich water intakes in Długopole-Zdrój. Problemy Uzdrowiskowe, 4 (36), 598–622. [In Polish].
  • 17. Fistek, J. 1977. CO2-rich waters of the Kłodzko Valley and the Bystrzyckie Mountains. Biuletyn Geologiczny Uniwersytetu Warszawskiego, 22, 61–115. [In Polish]
  • 18. Fistek, J., Iwanowski, S., Iciek, A. and Jagodziński, A. 1975. Geological, geophysical and hydrogeological research as an example of a comprehensive solution to the problem of searching for medicinal waters in the Sudeten health resorts. Geofizyka: Biuletyn Informacyjny, 1, 5–30. [In Polish]
  • 19. Gierwielaniec, J. 1965. Geological setting of the vicinity of Kudowa. Biuletyn Instytutu Geologicznego, 185, 23–90. [In Polish]
  • 20. Ivanov, V.V. 1997. Rare f-elements. In: Burienkov, E.K. (Ed.), Ecological geochemistry of elements - 6 volumes set (Vol. 6, pp. 1–607). Nedra; Moscow. [In Russian]
  • 21. Kiełczawa, B., Ciężkowski, W. and Duda, M. 2018. Gorzanów - the New Reservoir of Curative Water in Sudety Mts, (SW Poland). Acta Balneologica, 4, 301–306. [In Polish, with English summary]
  • 22. Kiełczawa, B. and Liber-Makowska, E. 2017.Variability of selected physicochemical parameters of the Szczawno-Zdrój healing waters (Sudety Mountains). Przegląd Geologiczny, 65, 973–978. [In Polish]
  • 23. Kozłowski, J. 1999. Water mixing - the basic process of forming the final chemical composition of Polish therapeutic waters. Unpublished PhD Thesis, 135 pp. Wrocław University of Science and Technology; Wrocław. [In Polish]
  • 24. Liber-Makowska, E. and Kiełczawa, B. 2021. Medicinal CO2-rich water deposits in the Polish part of the Sudetes. Mining Sciences, 28, 247–261.
  • 25. Lipin, B.R. and McKay, G.A. (Eds) 1989. Geochemistry and Mineralogy of Rare Earth Elements. Reviews in Mineralogy and Geochemistry, Vol. 21, 348 pp. The Mineralogical Society of America; Washington D.C..
  • 26. Mazur, S. and Aleksandrowski, P. 2001. The Tepla(?)/Saxothuringian suture in the Karkonosze-Izera massif, western Sudetes, central European Variscides. International Journal of Earth Sciences, 90, 341–360.
  • 27. Oberc, J. 1972. The Sudetes Mts and adjacent areas. In: The geological structure of Poland, IV, Tectonics p. II., 307 pp. Wydawnictwa Geologiczne; Warsaw. [In Polish]
  • 28. Order 2006. Order of the Minister of Health concerning the scope of the research necessary to determine the therapeutic properties of natural medicinal raw materials and healing properties of the climate, the criteria for their evaluation and a model of certificate confirming these properties. Legislation Journal of the Republic of Poland 80: pos. 565. (https://isap.sejm.gov.pl/isap.nsf/DocDetails.xsp?id=WDU20060800565). Amended in 2016. (https://isap.sejm.gov.pl/isap.nsf/DocDetails.xsp?id=WDU20160001709)
  • 29. Paczyński, B. and Płochniewski, Z. 1996. Mineral and medicinal waters of Poland, 108 pp. Państwowy Instytut Geologiczny; Warsaw. [In Polish]
  • 30. Pačes, T. 1972. Flux of CO2 from the Lithosphere in the Bohemian Massif. Nature Physical Science, 240, 141–142.
  • 31. Przylibski, T. 2005. Radon. Specific component of medicinal waters in the Sudety Mountains, 329 pp. Oficyna Wydawnicza Politechniki Wrocławskiej; Wrocław. [In Polish]
  • 32. Sarbas, B. and Töpper, W. 1988. Y, La to Lu: Geochemistry - Hydrosphere. Atmosphere. Cosmo- and Geochemical Cycles. Balance. Vol. A6b. In: Sc, Y, La-Lu Rare Earth Elements. Gmelin Handbook of Inorganic Chemistry. 8th ed., 1–208. Springer; Berlin.
  • 33. White, W.B. 1988. Geochemistry of karst waters. In: White W.B., Geomorphology and hydrology of karst terrains, 191–219. Oxford University Press; New York and Oxford.
  • 34. Wiktorowicz, B. 2009. Hydrogeochemistry of CO2-rich waters from the Kudowa Depression. Biuletyn Państwowego Instytutu Geologicznego, 436, 523–528. [In Polish, with English summary]
  • 35. Żelaźniewicz, A. 1977. Granitoids of the Kudowa-Olešnice massif (Sudetes). Geologia Sudetica, 12 (1), 137–162. [In Polish with English summary]
  • 36. Żelaźniewicz, A., Aleksandrowski, P., Buła, Z., Karnkowski, P., Konon, A., Oszczypko, N., Ślączka, A., Żaba, J. and Żytko, K. 2011. Tectonic subdivision of Poland, 60 pp. Komitet Nauk Geologicznych PAN; Wrocław. [In Polish]
Uwagi
PL
Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-7b9ca839-50ee-4e1e-b313-f9a2d7e61700
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