Wpływ przygotowania próbek na wynik frakcjonowania chemicznego chromu w osadach rzecznych zanieczyszczonych ściekami garbarskimi

Trojanowska, M.; Świetlik, R.

doi:10.12912/23920629/66990

Artykuł - szczegóły

Tytuł artykułu

Wpływ przygotowania próbek na wynik frakcjonowania chemicznego chromu w osadach rzecznych zanieczyszczonych ściekami garbarskimi

Autorzy

Trojanowska M. , Świetlik R.

Treść / Zawartość

Pełne teksty:

trojanowska_wplyw_przygotowania_1_2017.pdf

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Identyfikatory

DOI

10.12912/23920629/66990

Warianty tytułu

The effect of sample pretreatment on the result of chemical fractionation of chromium in river sediments contaminated with tannery sewage

Języki publikacji

Abstrakty

Frakcjonowanie chemiczne jest powszechnie stosowane do oceny mobilności i biodostępności metali ciężkich obecnych w stałych próbkach środowiskowych. Choć wynik frakcjonowania chemicznego może być determinowany sposobem przygotowania próbek do badań, w przypadku prac dotyczących oceny środowiskowych skutków zanieczyszczenia chromem to zagadnienie jest często niedoceniane. Celem tych badań była ocena wpływu sposobów przygotowania próbek na wyniki frakcjonowania chemicznego chromu zdeponowanego w osadach rzecznych zanieczyszczonych ściekami garbarskimi. Uwagę skoncentrowano na ocenie wpływu suszenia i rozdrobnienia osadów. Frakcjonowanie prowadzono zgodnie z procedurą Tessiera, umożliwiającą podział zawartości chromu na pięć frakcji o różnej mobilności i biodostępności (jonowymienną, węglanową, tlenkową, organiczną i pozostałą). Wykazano, że rozdrabnianie osadów nie jest właściwym sposobem przygotowania próbek do badań ponieważ zmienia znacząco wyniki frakcjonowania i tym samym może prowadzić do błędnej oceny mobilności i biodostępności chromu zdeponowanego w osadach rzecznych. Suszenie osadów w zakresie temperatur 20–105 °C nie zmienia pierwotnej dystrybucji chromu między fazy biogeochemiczne.

Chemical fractionation is generally used to assess the mobility and bioavailability of heavy metals present in solid environmental samples. Although fractionation results are determined by sample pretreatment methods, authors of publications usually disregard this issue and study exclusively the distribution of metals among biogeochemical phases. The aim of this work was to assess the effect of preparation of samples on results of chemical fractionation of chromium deposited in river sediments contaminated with tannery wastes. Attention was focused on the evaluation of the effect of drying and grinding of sediments. Fractionation was carried out according to the procedure of Tessier which makes it possible to divide total chromium content into five fractions of different mobility and bioavailability (ion-exchange, carbonate, oxide, organic and residual fractions). It has been found that sediment grinding is not an appropriate method of sample pretreatment, because it significantly changes fractionation results and thus it can lead to an incorrect assessment of mobility and bioavailability of chromium deposited in river sediments. Drying of the sediments at a range of 20–105 °C does not change the original distribution of chromium among biogeochemical phases.

Słowa kluczowe

chrom osad rzeczny frakcjonowanie chemiczne przygotowanie próbek

chromium sediment chemical fractionation sample pretreatment

Wydawca

Polskie Towarzystwo Inżynierii Ekologicznej

Czasopismo

Inżynieria Ekologiczna

Rocznik

2017

Tom

Vol. 18, nr 1

Strony

88--97

Opis fizyczny

Bibliogr. 52 poz., tab., rys.

Twórcy

autor

Trojanowska M.

m.trojanowska@uthrad.pl

Katedra Ochrony Środowiska, Uniwersytet Technologiczno-Humanistyczny im. Kazimierza Pułaskiego w Radomiu, ul. Chrobrego 27, 26-600 Radom

autor

Świetlik R.

Katedra Ochrony Środowiska, Uniwersytet Technologiczno-Humanistyczny im. Kazimierza Pułaskiego w Radomiu, ul. Chrobrego 27, 26-600 Radom

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-7b6dda46-11f0-4d84-93ea-036a62085e84