FePt3 nanosuspension synthesized from different precursors – a morphological comparison by SAXS, DLS and TEM

• Autorzy: Sarmphim P. , Soontaranon S. , Sirisathitkul C. , Harding P. , Kijamnajsuk S. , Chayasombat B. , Pinitsoontorn S. , Chingunpitak J.

Identyfikatory

DOI

10.1515/bpasts-2017-0010

• Języki publikacji: EN

Abstrakty

EN

Annealed iron-platinum (FePt) is ferromagnetic in a nanoscale regime which is necessary for energy and data storage, whereas the as-synthesized form of FePt-based nanoparticles exhibits superparamagnetism useful for biomedical applications. In this study, as-synthesized nanosuspensions from the reaction of Pt(acac)2 with Fe(acac)3 and Fe(hfac)3 are compared. X-ray diffraction (XRD) peaks for both samples are assigned to the FePt3 phase. As shown by transmission electron microscopy (TEM) and small angle X-ray scattering (SAXS), nanoparticles synthesized by using Fe(acac)3 have a smaller average diameter, but larger polydispersity index and particle agglomerations. On the other hand, the nanoparticles synthesized by using Fe(hfac)3 can self-assemble into a longer range of patterned monolayer. Dynamic light scattering (DLS), measuring the size of cluster of nanoparticles as well as oleic acid and oleylamine at their surface, confirms that larger agglomerations in the sample were synthesized by using Fe(acac)3. In addition to the size distribution, magnetic properties were influenced by the composition of these nanoparticles.

Słowa kluczowe

EN

magnetic nanosuspension; Fe(acac)3; Fe(hfac)3; DLS; TEM; SAXS

PL

Fe(acac)3; Fe(hfac)3; DLS; TEM; SAXS

• Wydawca: Polska Akademia Nauk, Wydział IV Nauk Technicznych
• Czasopismo: Bulletin of the Polish Academy of Sciences. Technical Sciences
• Rocznik: 2017
• Tom: Vol. 65, nr 1
• Strony: 79--84
• Opis fizyczny: Bibliogr. 22 poz., tab., wykr., rys.

Twórcy

autor

Sarmphim P.

• Molecular Technology Research Unit, Walailak University, Nakhon Si Thammarat, Thailand

autor

Soontaranon S.

• Synchrotron Light Research Institute, Nakhon Ratchasima, Thailand

autor

Sirisathitkul C.

• Molecular Technology Research Unit, Walailak University, Nakhon Si Thammarat, Thailand

autor

Harding P.

• Molecular Technology Research Unit, Walailak University, Nakhon Si Thammarat, Thailand

autor

Kijamnajsuk S.

• National Metal and Materials Technology Center, Pathumthani, Thailand

autor

Chayasombat B.

• National Metal and Materials Technology Center, Pathumthani, Thailand

autor

Pinitsoontorn S.

• Integrated Nanotechnology Research Center, Khon Kaen University, Khon Kaen, Thailand

autor

Chingunpitak J.

• School of Pharmacy, Walailak University, Nakhon Si Thammarat, Thailand

Bibliografia

• [1] P. Wang, “FePt magnetic nanoparticles and their assembly for future magnetic media”, Proceedings of IEEE 96, 1847‒1863 (2008).
• [2] O. Crisan, A.D. Crisan, I. Mercioniu, R. Nicula, and F. Vasiliu, “Development and structural characterization of exchangespring- like nanomagnets in (Fe, Co)-Pt bulk nanocrystalline alloys”, J. Magn. Magn. Mater. 401, 711‒715 (2016).
• [3] Y. Shi, M. Lin, X. Jiang, and S. Liang, “Recent advances in FePt nanoparticles for biomedicine”, J. Nanomater. 2015, 467873 (2015).
• [4] V. Nandwana, K. E. Elkins, N. Poudyal, G. S. Chaubey, K. Yano, and J. P. Liu, “Size and shape control of monodisperse FePt nanoparticles”, J. Phys. Chem. C 111, 4185‒4189 (2007).
• [5] M. Farahmandjou, “Comparison of the Fe and Pt nanoparticles with FePt alloy prepared by polyol process: Shape and composition study”, Acta Phys. Pol. A 123, 277‒278 (2013).
• [6] Y. Wang, M. Yang, B. Xu, Z. Yang, N. Hu, L. Wei, B. Cai, and Y. Zhang, “Controlled assembly of FePt nanoparticles monolayer on solid substrates”, J. Colloid Interf. Sci. 417, 100‒108 (2014).
• [7] Y. Xia, T. D. Nguyen, M. Yang, B. Lee, A. Santos, P. Podsiadlo, Z. Tang, S. C. Glotzer, and N. A. Kotov, “Self-assembly of self-limiting monodisperse supraparticles from polydisperse nanoparticles”, Nature Nanotechnol. 6, 580‒587 (2011).
• [8] W. Tangwatanakul, K. Chokprasombat, C. Sirisathitkul, P. Jantaratana, and Y. Sirisathitkul, “Magnetic phase transition of annealed FePt based nanoparticles”, J. Alloys Compd. 654, 234‒239 (2016).
• [9] W. Neumann, H. Kirmse, I. Häusler, A. Mogilatenko, C. Zheng, and W. Hetaba, “Advanced microstructure diagnostics and interface analysis of modern materials by high-resolution analytical transmission electron microscopy”, Bull. Pol. Ac.: Tech. 58, 237‒253 (2010).
• [10] J. K. Lim, S. P. Yeap, H. X. Che, and S. C. Low, “Characterization of magnetic nanoparticle by dynamic light scattering”, Nanoscale Res. Lett. 8, 381 (2013).
• [11] R. De Palma, S. Peeters, M. J. Van Bael, H. Van den Rul, K. Bonroy, W. Laureyn, J. Mullens, G. Borghs, and G. Maes, “Silane ligand exchange to make hydrophobic superparamagnetic nanoparticles water-dispersible”, Chem. Mater. 19, 1821‒1831 (2007).
• [12] T. Rieker, A. Hanprasopwattana, A. Datye, and P. Hubbard, “Particle size distribution inferred from small-angle X-ray scattering and transmission electron microscopy”, Langmuir 15, 638‒641 (1999).
• [13] M. Murawska, A. Skrzypczak, and M. Kozak, “Structure and morphology of gold nanoparticles in solution studied by TEM, SAXS and UV_Vis”, Acta Phys. Pol. A 121, 888‒892 (2012).
• [14] H. Borchert, E.V. Shevehenko, A. Robert, I. Mekis, A. Kornowski, G. Grubel, and H. Weller, “Determination of nanocrystal sizes: A comparison of TEM, SAXS, and XRD studies of highly monodisperse CoPt3 particles”, Langmuir 21, 1931‒1936 (2005).
• [15] K. Chokprasombat, K. Koyvanich, C. Sirisathitkul, P. Harding, and S. Rugmai, “Investigation of surfactant effect on size distribution of FePt-based nanoparticles by synchrotron SAXS and TEM”, Trans Ind. Inst. Met. 69, 733‒740 (2016).
• [16] S. Gopinath, and J. Philip, “Preparation of metal oxide nanoparticles of different sizes and morphologies, their characterization using small angle X-ray scattering and study of thermal properties”, Mater. Chem. Phys. 145, 213‒221(2014).
• [17] K. Chokprasombat, P. Harding, C. Sirisathitkul, W. Tangwatanakul, S. Pinitsoontorn, and P. Muneesawang, “Substituent effect of Fe(β-diketonate)3 on the control of self-assembly FePtbased nanoparticles”, J. Nanopart. Res.16, 2436 (2014).
• [18] G. Beaucage, “Approximations leading to a unified exponential/ power-law approach to small-angle scattering”, J. Appl. Cryst. 28, 717‒728 (1995).
• [19] G. Beaucage, and D. W. Schaefer, “Structural studies of complex systems using small-angle scattering: A unified Guinier/ power-law approach”, J. Non-Cryst. Solids. 172‒174 , 797‒805 (1994).
• [20] J. Kohlbrecher, “A program for fitting elementary structure models of small angle scattering data”, Paul Scherrer Institute, https://kur.web.psi.ch/sans1/SANSSoft/sasfit.pdf (2014).
• [21] D. W. Schaefer, and R. S. Justice, “How nano are nanocomposites?”, Macromolecules 40, 8501- (2007).
• [22] G. Beaucage, H. K. Kammler, and S. E. Pratsinis, “Particle size distributions from small-angle scattering using global scattering functions”, J. Appl. Cryst. 37, 523‒535 (2004).

Uwagi

PL

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).