Pierwiastki ziem rzadkich (REE) w iłowcach z wybranych pokładów węgla kamiennego serii mułowcowej i piaskowcowej Górnośląskiego Zagłębia Węglowego

• Autorzy: Kokowska-Pawłowska M.

Identyfikatory

DOI

10.1515/gospo-2016-0028

Warianty tytułu

EN

Rare earth elements (REE) in claystones with selected coal seams of the mudstone and sandstone series of the Upper Silesian Coal Basin

• Języki publikacji: PL

Abstrakty

PL

W artykule przedstawiono wyniki badań zróżnicowania zawartości pierwiastków ziem rzadkich (REE ) w iłowcach towarzyszących wybranym pokładom węgla z warstw załęskich i rudzkich z zachodniej części Górnośląskiego Zagłębia Węglowego (GZW). Analizowano 75 próbek skał ilastych współwystępujących z pokładami węgla 405 i 408 pobranych w GZW. Zawartość wybranych REE oznaczona została za pomocą Instrumental Neutron Activation Analysis (INAA). Z uwagi na ograniczone możliwości oznaczono: skand (Sc), lantan (La), cer (Ce), neodym (Nd), samar (Sm), europ (Eu), terb (Tb), yterb (Yb) oraz lutet (Lu), zaś zawartość itru (Y) badano metodą Fusion-Inductively-Coupled Plasma (FUS-ICP). [...]

EN

In this paper results of investigation on the variability of REE contents in the clayey rocks accompanying selected coal seams from Zaleskie and Ruda beds of western part of Upper Silesia Coal Basin (USCB) have been presented. 75 samples have been analysed from the claystones coexisting with coal seams 405 and 408 collected from the USCB area. Contents of selected REE have been assessed with a use of the Instrumental Neutron Activation Analysis (INAA). In regard to the constraints of this method following elements underwent evaluation: scandium (Sc), lanthanum (La), cerium (Ce), neodymium (Nd), samarium (Sm), Europium (Eu), terbium (Tb), ytterbium (Yb), and lutetium (Lu). Contents of yttrium (Y) was determined with a use of the Fusion-Inductively-Coupled Plasma (FUSICP) method. [...]

Słowa kluczowe

PL

pierwiastki ziem rzadkich; iłowce; skała towarzysząca; pokład węgla; Górnośląskie Zagłębie Węglowe

EN

rare earth elements (REE); claystones; accompanying rock; coal seam; Upper Silesian Coal Basin

• Wydawca: Instytut Gospodarki Surowcami Mineralnymi i Energią PAN ; Komitet Zrównoważonej Gospodarki Surowcami Mineralnymi PAN
• Czasopismo: Gospodarka Surowcami Mineralnymi
• Rocznik: 2016
• Tom: T. 32, z. 3
• Strony: 39--66
• Opis fizyczny: Bibliogr. 55 poz., rys., tab., wykr.

Twórcy

autor

Kokowska-Pawłowska M.

• Politechnika Śląska, Wydział Górnictwa i Geologii, Instytut Geologii Stosowanej, Gliwice

Bibliografia

• [1] Alonso i in. 2012 – Alonso, E ., Sherman, A .M., Wallington, T.J., Everson, M.P., Field, F.R., Roth, R., Kirchain, R.E. 2012. Evaluating Rare Earth Element Availability: A Case with Revolutionary Demand from Clean Technologies. Environ. Sci. Technol. 46 (6), s. 3406–3414.
• [2] Brik, D. i White, J.C., 1991. Rare earth elements in bituminous coals and underclays of the Sydney basin, Nova Scotia – elements sites, distribution, mineralogy. International Journal of Coal Geology 19, s. 219-251.
• [3] Bukowy, S. i Jachowicz, A . 1985. Basic of stratigraphy and tectonic. Mat. Konf. pt. „Tektonika Górnośląskiego Zagłębia Węglowego”, s. 5–9. Sosnowiec.
• [4] Całus-Moszko, J. 2012. Statutory activity. Occurence of rare earth metals in the Polish hard coal [W:] Całus-Moszko, J., Białecka, B. 2013. Analysis of the possibilities of rare earth elements obtaining from coal and fly ash. Gospodarka Surowcami Mineralnymi – Mineral Resources Management t. 29, z. 1, s. 67–80.
• [5] Całus-Moszko, J. i Białecka, B., 2013. Analysis of the possibilities of rare earth elements obtaining from coal and fly ash. Gospodarka Surowcami Mineralnymi – Mineral Resources Management t. 29, z. 1, s. 67–80.
• [6] Castor, B. i Hedrick, J.B. 2006. Rare Earth Elements. Industrial Minerals and Rocks. Society for Mining Metallurgy and Explorations s. 769–792.
• [7] Chodyniecka, L . 1973. Carboniferous sferosiderite clayey from Upper Silesian Coal Basin (Study of mineralogical and chemical). Zeszyty Naukowe Pol. Śl., seria: Górnictwo z. 369.
• [8] Cullers, R.L. 1995. The controls on the major- and trace-element evolution of shales, siltstones and sandstones of Ordovician to Tertiary age in the Wet Mountains region, Colorado, USA. Chem. Geol. 123, s. 107–131.
• [9] Dai i in. 2002 – Dai, S.F., Ren, D.Y. i Li, S.S. 2002. Occurrence and sequential chemical extraction of rare earth element in coals and seam roofs. Journal of China University of Mining Technology 31(5), s. 349–353 (in Chinese with English abstract).
• [10] Dai i in. 2008 – Dai, S., Tian, L . i Chou, C. 2008. Mineralogical and compositional characteristic of Late Permian coals from an area of high lung cancer rate in Xuan Wei, Yunnan, China: Occurrence and origin of quartz and chamosite. International Journal of Coal Geology 76(4), s. 318–327.
• [11] Dai i in. 2012a – Dai, S., Ren D., Chou, C.L., Finkelman R.B., Seredin, V.V. i Zhou, Y. 2012a. Geochemistry of trace elements in Chines coals: A review of abundances, genetic types, impacts on human health, and industrial utilization. International Journal of Coal Geology 94, s. 3–21.
• [12] Dai i in. 2012b – Dai, S., Wang, X., Seredin, V.V., Hower, J.C., Ward, C.R., O Keefe, J.M.K., Huang, W., Li, T., Li, X., Liu, H., Xue, W. i Zhao, L . 2012b. Petrology, mineralogy, and geochemistry of the Ge-rich coal from the Wulantuga Ge ore deposit, Inner Mongolia, China: New data and genetic implications. International Journal of Coal Geology 90, s. 72–99.
• [13] Ekskenazy, G.M. 1999. Aspects of the geochemistry of rare earth elements in coal: an experimental approach. International Journal of Coal Geology 38, s. 285–295.
• [14] Elbaz-Poulichet, F. i Dupuy, C. 1999. Behaviour of rare earth elements at the freshwater–seawater interface of two acid mine rivers: The Tinto and Odiel (Andalucia, Spain). App. Geochem. 14, 8, s. 1063–1072.
• [15] Fu i in. 2011 – Fu, X. , Wang, J., Zeng, Y., Tan, F. i He J., 2011. Geochemistry andorigin of rare earth elements (REEs) in the Shengli Riveroilshale, northern Tibet, China. Chemie der Erde 71, s. 21–30.
• [16] Gabzdyl, W. i Ryszka, J. 1995. Phosphorus – rich Coaly Tonsteins and Coal Seams in Silesian. XIII International Congress on Carboniferous – Permian. Kraków. s. 40–41.
• [17] Gammons i in. 2005 – Gammons, C.H., Wood, S.A. i Nimick, D.A. 2005. Diel behavior of rare earth elements in a mountain stream with acidic to neutral pH. Geochim. Cosmochim. Acta 69, 15, s. 3747–3758. doi:10.1016/j.gca.2005.03.019.
• [18] Geological documentations: Szczygłowice Coal Mine 1996; Knurów Coal Mine 1995; Sośnica-Makoszowy Coal Mine 1994; Bielszowice Coal Mine 1995; Halemba-Wirek Coal Mine 1997; Wujek Coal Mine 1997; Chwałowice Coal Mine 1995; Jankowice Coal Mine 1998.
• [19] Guliford, J.P., 1965. Fundamental Statistics in Psychology and Education. N ew York – McGraw-Hill.
• [20] Hanak, B. i Kokowska-Pawłowska, M. 2003. Characterization of the content variability of selected trace elements in the associated rocks of coal seams 610 and 620. Zeszyty Naukowe Politechniki Śląskiej, seria Górnictwo nr 256, s. 95–101.
• [21] Hanak, B. i Kokowska-Pawłowska, M. 2006a. Characterization of the content of the trace elements in the associated rocks of coal seam 630. Zeszyty Naukowe Politechniki Śląskiej, seria Górnictwo nr 273, s. 27–32.
• [22] Hanak, B. i Kokowska-Pawłowska, M., 2006b. Variability of trace element contents in the coal lithotypes and their ashes presented on the background of the 630 coal seam profiles (U.S.C.B.). Gospodarka Surowcami Mineralnymi – Mineral Resources Management t. 22, z. 3, s. 68–77, Kraków.
• [23] Hanak i in. 2011 – Hanak, B., Kokowska-Pawłowska, M. i Nowak, J. 2011. The trace elements of the coal shales from the 405 coal seam. Kwartalnik Górnictwo i Geologia t. 6, z. 4. Gliwice, s. 27–38.
• [24] He i in. 2010 – He, J., Lu C-W., Xue, X., Liang, Y., Bai, S., Sun, Y., Shen, L -L., Mi, N . i Fan, Q-Y. 2010. Species and distribution of rare earth elements in the Baotou section of the Yellow River in China. E nviron. Geochem. Health 32, s. 45–58.
• [25] Hu i in. 2002 – Hu, X., Ding, Z., Chen, Y., Wang, X. i Dai L 2002. Bioacumulation of lanthanum and cerium and their effect on the growth of wheat (triticum aestivum L .) seedlings. Chemosphere 48, 6, s. 621–629.
• [26] Kabata-Pendias, A . i Pendias, H., 1999. Biogeochemistry of trace elements. Warszawa: PWN.
• [27] Kabata-Pendias, A . i Mukherjee, A .B. 2007. Trace elements from soil to human. 133–141. Springer.
• [28] Kato i in. 2011 – Kato, Y., Fujinaga, K., Nakamura K., Takaya, Y., Kitamura, K., Ohta, J., Toda, R., Nakashima, T. i Iwamori, H. 2011. Deep-sea mud in the Pacific Ocean as a potential resource for rare – earth elements. Nature Geoscience 4(8), s. 535–539.
• [29] Ketris, M.P. i Yudovich, Y.E. 2009. Estimations of Clarkes for Carbonaceous biolithes: World averages for trace element contents in black shales and coals. International Journal of Coal Geology 78(2), s. 135–148.
• [30] Kotas, A . 1995. Moravian-Cracovian region: Upper Silesian Coal Basin. In: The Carboniferous System in Poland. Prace PIG CXLVIII, s. 124–134. Warszawa.
• [31] Krawczyk, A . i Słomka T. 1986. Basic mathematical methods in geology. Skrypty Uczelniane 1026. AGH. Kraków.
• [32] Małecka,K., 2012. Geochemical variability of rare earth elements and heavy metals in profundal and littoral sediments from selected lakes of Poland. Biuletyn Państwowego Instytutu Geologicznego 450, s. 63–74.
• [33] Masto i in. 2011 – Masto, R.E., Ram, L .C. i Verma, S.K. 2011. Rare earth elements in Soils of Jahira Coal Field Impacts of opencast coal mine and mine fire on the trace elements content of the surrounding soil, vis-a-vis human health risk. Toxicologica and Environmental Chemistry 93(4), s. 223–237.
• [34] McLennan i in. 1983 – McLennan, S.M., Taylor, S.R., Eriksson, K.A., 1983. Geochemistry of Archean shales from the Pilbara Supergroup, Western Australia. Geochim. Cosmochim. Acta 47, s. 1211–1222.
• [35] McLennan, S.M. 1989. Rare earth elements in sedimentary rocks: influence of provenance and sedimentary processes. W: Geochemistry and mineralogy of rare earth elements (red. B.R. Lipin, G.A. McKay). Rev. Mineral. 21, s. 169–195.
• [36] Merteni in. 2004 – Merten, D., Kothe, E . i Buchel, G. 2004. Studies on microbial heavy metal retention from uranium mine drainage water with special emphasis on rare earth elements. Mine Water and the Environment 23, 34–43.
• [37] Moore, F. i Esmaeili, A . 2012. Mineralogy and geochemistry of the coals from Karmozd and Kiasar coal mines. Mazandran Provence, Iran. International Journal of Coal Geology 96–97, 9–21.
• [38] Palmer i in. 1990 – Palmer, C.A., Lyons, P.C., Brown, Z.A. i Mee, J.S. 1990. The use of trace element concentrations in vitrinite concentrates and companion whole coals (hyA-bituminous) to determine organic and inorganic association. GSA Special Paper 248, s. 55–62.
• [39] Polański, A . 1988. Base of geochemistry. Warszawa: Wyd. Geol. Querol i in. 1994 – Querol, X., Turiel, J.L.F. i Soler, A .E. 1994. The bechavior of mineral matter during combustion of Spanish subbituminous and brown coals. Mineralogical Magazine 58(390), s. 119–133.
• [40] Querol i in. 1995 – Querol, X., Fernandez-Turiej, JL. i Lopez-Soler, A . 1995. Trace elements in coal and their behaviour during combustion in a large power station. Fuel. vol. 74, is. 3, s. 331–343.
• [41] Ryka, W. i Maliszewska A . 1991. Petrographic dictionary. Warszawa: Wyd. Geol.
• [42] Stoch, L . 1974. Clay minerals. Warszawa: Wyd. Geol.
• [43] Stopa, S.Z. 1967. Problematyka stratygraficzna podziału karbonu krakowsko-śląskiego w świetle paleobotaniki. Rocz. Pol. Tow. Geol. 37. z. 1, Kraków.
• [44] Wang i in. 1989 – Wang, Z.G., Yu, X.Y. i Zhao, Z.H. 1989. Geochemistry of Rare Earth Elements. Science Press, Beijing (pp. 310–313 in Chinese).
• [45] Ward i in. 1999 – Ward, C.R., Spears D.A., Booth, C.A., Staton, I. i Gurba, L .W. 1999. Mineral matter and trace elements in coals of the Gunnedah basin, new South Wales, Australia. International Journal of Coal Geology 40, 281–308.
• [46] Worralla, F. i Pearson, D.G. 2001. Water-rock interaction in an acidic mine discharge as indicated by rare earth element patterns. Geochim. Cosmochim. Acta 65, 18, s. 3027–3040.
• [47] Vassiliev, S.V. i Vassilieva Ch.G., 1997. Geochemistry of coals, coal ashes and combustion wastes from coal-fired power stations. Fuel Processing Technology vol. 51, is. 1–2, s. 19–45.
• [48] Vassiliev i in. 2001 – Vassiliev, S.V., Eskenazy, G.M. i Vassilieva Ch.G. 2001. Behaviour of elements and minerales during preparation and combustion of the Pernik coal, Bulgaria. Fuel Processing Technology vol. 72, is. 2, s. 103–129.
• [49] Vinokurov i in. 2002 – Vinokurov, S.E., Koporulin, V.I. i Stukalova, I.E. 2002. Rare earth elements in coal-bearing deposits: Distribution Features and geochemical sigifance. Litology and Mineral Resources 37, s. 447–553.
• [50] Volokh i in. 1990 – Volokh, A .A., Gorbunov, A .V., Guondorina, S.F., Revich, B.A., Frontasyeva, M.V. i Chen, S.P. 1990. Phosphorus fertilizer production as a source of rare earth elements pollution of the environment. Sci. Total Environ. 95, s. 141–148.
• [51] Xu i in. 2002 – Hu, X., Ding, Z.,Chen, Y., Wang, X. i Dai, L . 2002. Bioacumulation of lanthanum and cerium and their effect on the growth of wheat (triticum aestivum L .) seedlings. Chemosphere 48, 6, s. 621–629.
• [52] Xu i in. 2004 – Xu, C., Zhang, H., Huang, Z.L., Liu, C.Q., Qi, L ., Li, W.B. i Guan T. 2004. Genesis of the carbonatite-syenite complex and REE deposit A T Maoniuping, Sichuan Province, China. E vidence from Pb isotope geochemistry. Geochemical Journal 31(1), s. 67–76.
• [53] Yang i in. 2012 – Yang, M., Liu, G.J., Sun, R.Y., Chou, C.L. i Zheng, L .G. 2012. Characterization of intrusive rocks and REE geochemistry of coals from the Zhuji Coal Mine, Huainan Coalfield, Anhui, China. International Journal of Coal Geology 94, s. 283–295.
• [54] Zhang, S. i Shan, X. 2001. Speciation of rare earth elements in soil and accumulation by wheat with rare earth fertilizer application. Environ. Pollut. 112, 3, s. 395–405.
• [55] Zheng i in. 2007 – Zheng, L ., Liu, G., Chou Ch.L., Qi, C. i Zhang, Y. 2007. Geochemistry of rare earth elements in Permian coals from the Huaibei Coalfield, China. Journal of Asian Earth Sciences 31, s. 167–176.

Uwagi

PL

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.