Preparation of MCM-41 Supported Benzene Sulphonic Acid, a Catalyst for the Synthesis of CL-20 from TAIW

• Autorzy: Chen Shixiong , Yang Chaofei , Qian Hua , Liu Dabin , Kai Wang , Li Rui

Identyfikatory

DOI

10.22211/cejem/112136

• Języki publikacji: EN

Abstrakty

EN

Pure MCM-41 anchored benzene sulphonic acid (BSA/MCM-41), an efficient heterogeneous catalyst, was prepared for the synthesis of CL-20 from TAIW. The prepared catalysts were fully characterized by FTIR, XRD, TEM, TG, N2 adsorption techniques, elemental analysis and acidity tests. It was observed that the catalyst (BSA/MCM-41) retained the mesoporous structure like MCM-41, exhibited excellent thermal stability and high activity. Compared with a blank, the high catalytic activity promoted shorter reaction times by a factor of 3/5. In addition, this catalyst could be reused at least five times without significant loss of its catalytic potential. Moreover, the BSA/MCM-41 catalyst exhibited an optimal catalytic performance, with a high to excellent yield of CL-20 (92.5%) with a purity of 98.3%, under the optimum synthesis conditions.

Słowa kluczowe

EN

CL-20; catalytic; MCM-41; benzene sulphonic acid; TAIW

• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2019
• Tom: Vol. 16, no. 3
• Strony: 343--359
• Opis fizyczny: Bibliogr. 32 poz., rys., tab.

Twórcy

autor

Chen Shixiong

• School of Chemical Engineering, Nanjing University of Science and Technology, 200 Xiaoling Rd, Nanjing, 210094, China

autor

Yang Chaofei

• School of Chemical Engineering, Nanjing University of Science and Technology, 200 Xiaoling Rd, Nanjing, 210094, China

autor

Qian Hua

• School of Chemical Engineering, Nanjing University of Science and Technology, 200 Xiaoling Rd, Nanjing, 210094, China

autor

Liu Dabin

• School of Chemical Engineering, Nanjing University of Science and Technology, 200 Xiaoling Rd, Nanjing, 210094, China

autor

Kai Wang

• School of Chemical Engineering, Nanjing University of Science and Technology, 200 Xiaoling Rd, Nanjing, 210094, China

autor

Li Rui

• ZNDY Ministerial Key Laboratory, Nanjing University of Science and Technology, 200 Xiaoling Rd, Nanjing, 210094, China

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).