Wpływ działania plazmy niskotemperaturowej na zmiany zwilżalności wybranych polimerów

• Autorzy: Hołysz Lucyna , Kamela (Rymuszka) Diana , Terpiłowski Konrad , Chibowski Emil

Identyfikatory

DOI

10.53584/wiadchem.2021.10.4

Warianty tytułu

EN

Effect of low-temperature plasma on changes in wettability of selected polymers

• Języki publikacji: PL

Abstrakty

EN

The effects of air, oxygen and argon plasma treatment on wetting and energetic properties of polymers: polymethylmethacrylate (PMMA), polyetheretherketone (PEEK), polyoxymethylene (POM), polyamide (PA6G), polycarbonate (PC) and polypropylene (PP) were studied. The changes in surface properties of PMMA, PEEK, POM, PA6G polymers after the air plasma treatment, and PP and PC polymers after the Ar or O₂ plasma treatment were determined via the measurement of advancing and receding contact angles of three liquids having different polarity, i.e. water, formamide and diiodomethane. Having the determined contact angles the surface free energy and its components of the polymers were calculated using three different theoretical approaches, namely: acid-base Lifsthitz-van der Waals (LWAB), contact angle hysteresis (CAH) and Owens and Wendt (O-W). The effects of plasma treatment were further determined by calculations of the adhesion work and work of spreading of water on modified polymer and compared to values calculated for the unmodified surfaces. Then for the PEEK and POM modified with the air plasma, their surface wettability was determined after 14 days from the exposure to the plasma. It was found that plasma treatment caused better wettability what reflected in a decreased contact angles measured on the modified polymer surfaces. The greatest changes appeared for polar liquids, i.e. water and formamide. It pointed to an increased the surface hydrophilicity after the plasma treatment. The changes correlated also with the increased polar interactions due to appearance polar groups on the surface. For the studied polymer surfaces, generally the dispersive interactions practically did not change, regardless the treatment time and plasma type. The total surface free energy values calculated for the polymers from three different approaches to interfacial interactions are similar. However, the energy values are apparent because they depend s upon the kind of liquid used for the contact angles measurement. Irrespectively of the plasma type, for all polymers an increase of the adhesion work of water in reference to the unmodified surfaces was observed. The most appropriate time to improve the adhesion between the polymer surface and liquid was found to be 25 or 60 s. However, the effects of plasma treatment are not permanent. With the storage time the contact angles have increased. This can be due to the structure reorganization within a few nm thick the surface layer.

Słowa kluczowe

PL

polimer; plazma niskotemperaturowa; zwilżalność; kąt zwilżania; swobodna energia powierzchniowa; adhezja

EN

polymer; low-temperature plasma; wettability; contact angle; surface free energy; adhesion

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Wiadomości Chemiczne
• Rocznik: 2021
• Tom: [Z] 75, 9-10
• Strony: 1270--1295
• Opis fizyczny: Bibliogr. 87 poz., wykr.

Twórcy

autor

Hołysz Lucyna

• Instytut Nauk Chemicznych, Wydział Chemii, Uniwersytet Marii Curie-Skłodowskiej w Lublinie, pl. Marii Curie-Skłodowskiej 3, 20-031 Lublin

• https://orcid.org/0000-0001-6479-0919

autor

Kamela (Rymuszka) Diana

• Instytut Nauk Chemicznych, Wydział Chemii, Uniwersytet Marii Curie-Skłodowskiej w Lublinie, pl. Marii Curie-Skłodowskiej 3, 20-031 Lublin

autor

Terpiłowski Konrad

• Instytut Nauk Chemicznych, Wydział Chemii, Uniwersytet Marii Curie-Skłodowskiej w Lublinie, pl. Marii Curie-Skłodowskiej 3, 20-031 Lublin

• https://orcid.org/0000-0002-8078-3644

autor

Chibowski Emil

• Instytut Nauk Chemicznych, Wydział Chemii, Uniwersytet Marii Curie-Skłodowskiej w Lublinie, pl. Marii Curie-Skłodowskiej 3, 20-031 Lublin

• https://orcid.org/0000-0003-4298-4696

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).