Wpływ CaCl2 na sorpcję metali ciężkich w biomasie

• Autorzy: Kłos A. , Rajfur M. , Dołhańczuk-Śródka A. , Krems P. , Jerz D.

Warianty tytułu

EN

The influence of CaCl2 on heavy metals sorption in biomass

• Języki publikacji: PL

Abstrakty

PL

Zbadano w warunkach laboratoryjnych wpływ chlorku wapnia na sorpcję wybranych kationów metali ciężkich: Cu²⁺, Zn²⁺ i Cd²⁺ w biomasie porostów Hypogymnia physodes, mchów Pleurozium schreberi, glonów słodkowodnych Spirogyra sp., glonów morskich Palmaria palmata oraz makrofitów Elodea canadensis L. Wykazano różne właściwości sorpcyjne biomasy, powodujące m.in. zmiany pH roztworów podczas procesu sorpcji. Wskazano na zmiany wydajności oraz preferencji sorpcyjnych pod wpływem wprowadzanych do roztworu kationów Ca²⁺, ale także anionów Cl‾, które przesuwają stan równowagi w kierunku tworzenia form jonowych, niebiorących udziału w procesie wymiany jonowej. Interesującym, niewyjaśnionym efektem jest brak wpływu stężenia chlorku wapnia, w zakresie od 0 do 100 mmol/dm³, na sorpcję miedzi, ale tylko w badanych glonach oraz makrofitach.

EN

The influence of calcium chloride on sorption of the selected heavy metal cations: Cu²⁺, Zn²⁺ and Cd²⁺ in the biomass of lichens Hypogymnia physodes, mosses Pleurozium schreberi, fresh water alga Spirogyra sp., sea alga Palmaria palmata and macrophyte Elodea Canadensis L. was tested under laboratory conditions. Various biomass sorption characteristics were determined, which cause, among others, the change of the pH of the solutions during the sorption process. Changes of efficiency and sorption preferences were identified, under the influence of Ca²⁺ cations and also Cl‾ anions, introduced to the solution, which shift the equilibrium towards creation of the ion forms, which do not participate in the process of ions exchange. The lack of the influence of calcium chloride concentration, within the range from 0 to 100 mmol/ dm³, on the sorption of copper is an interesting, unexplained effect, however, only in the tested alga and macrophyte.

Słowa kluczowe

PL

biosorpcja; wymiana jonowa; metale ciężkie; remediacja wód

EN

biosorption; heavy metals; ion exchange; water remediation

• Wydawca: Wydawnictwo Politechniki Częstochowskiej
• Czasopismo: Inżynieria i Ochrona Środowiska
• Rocznik: 2015
• Tom: T. 18, nr 2
• Strony: 169--178
• Opis fizyczny: Bibliogr. 35 poz.

Twórcy

autor

Kłos A.

• Uniwersytet Opolski, Samodzielna Katedra Biotechnologii i Biologii Molekularnej, ul. kard. B. Kominka 6, 45-032 Opole

autor

Rajfur M.

• Uniwersytet Opolski, Samodzielna Katedra Biotechnologii i Biologii Molekularnej, ul. kard. B. Kominka 6, 45-032 Opole

autor

Dołhańczuk-Śródka A.

• Uniwersytet Opolski, Samodzielna Katedra Biotechnologii i Biologii Molekularnej, ul. kard. B. Kominka 6, 45-032 Opole

autor

Krems P.

• Uniwersytet Opolski, Samodzielna Katedra Biotechnologii i Biologii Molekularnej, ul. kard. B. Kominka 6, 45-032 Opole

autor

Jerz D.

• Uniwersytet Opolski, Samodzielna Katedra Biotechnologii i Biologii Molekularnej, ul. kard. B. Kominka 6, 45-032 Opole

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