Design, preparation and properties of novel flame retardant thermosetting vinyl ester copolymers based on castor oil and industrial dipentene

• Autorzy: Mao W. , Li S. , Li M. , Huang K. , Xia J.

Identyfikatory

DOI

10.1515/pjct-2017-0040

• Języki publikacji: EN

Abstrakty

EN

A novel bio-based flame-retardant thermosetting vinyl ester resin monomer was synthesized from castor oil. The chemical structures of the monomer was characterized by FTIR and 1H-NMR. In order to improve its rigidity and expand its application in the field of bio-based materials, it was mixed with certain proportions of another reactive bio-based VER monomer, which had rigid and strong polar groups, and then a series of copolymers were prepared with thermal curing method. Then their tensile property, hardness, morphology of fractured surface, flame retardant property, DMA and thermostability were all investigated. The results indicated that the copolymers had relatively high tensile strength of 11.2 MPa, and the limiting oxygen index is above 23% in all prepared copolymers. DMA demonstrates that the glass transition temperature of the cured resins is up to 56.1°C. Thermogravimetric analysis shows that the copolymers have excellent thermal stability.

Słowa kluczowe

EN

castor oil; vinyl ester resin; copolymers; flammability; thermal properties

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2017
• Tom: Vol. 19, nr 3
• Strony: 1--8
• Opis fizyczny: Bibliogr. 31 poz., rys., tab.

Twórcy

autor

Mao W.

• Institute of Chemical Industry of Forestry Products, CAF, Key Laboratory of Biomass Energy and Material, National Engineering Laboratory for Biomass Chemical Utilization, Key and Laboratory on Forest Chemical Engineering, SFA, Nanjing 210042, Jiangsu Province, China

autor

Li S.

• Institute of Chemical Industry of Forestry Products, CAF, Key Laboratory of Biomass Energy and Material, National Engineering Laboratory for Biomass Chemical Utilization, Key and Laboratory on Forest Chemical Engineering, SFA, Nanjing 210042, Jiangsu Province, China
• Institute of Forest New Technology, CAF, Beijing 10091,China

autor

Li M.

• Institute of Chemical Industry of Forestry Products, CAF, Key Laboratory of Biomass Energy and Material, National Engineering Laboratory for Biomass Chemical Utilization, Key and Laboratory on Forest Chemical Engineering, SFA, Nanjing 210042, Jiangsu Province, China
• Institute of Forest New Technology, CAF, Beijing 10091,China

autor

Huang K.

• Institute of Chemical Industry of Forestry Products, CAF, Key Laboratory of Biomass Energy and Material, National Engineering Laboratory for Biomass Chemical Utilization, Key and Laboratory on Forest Chemical Engineering, SFA, Nanjing 210042, Jiangsu Province, China
• Institute of Forest New Technology, CAF, Beijing 10091,China

autor

Xia J.

• Institute of Chemical Industry of Forestry Products, CAF, Key Laboratory of Biomass Energy and Material, National Engineering Laboratory for Biomass Chemical Utilization, Key and Laboratory on Forest Chemical Engineering, SFA, Nanjing 210042, Jiangsu Province, China
• Institute of Forest New Technology, CAF, Beijing 10091,China

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).