Antibacterial Ti-Cu and Ta-Cu coatings for endoprostheses applied by magnetron sputtering onto Ti6Al4V alloy

• Autorzy: Alontseva Darya , Azamatov Bagdat , Borisov Alexander , Maratuly Bauyrzhan , Safarova (Yantsen) Yuliya , Voinarovych Sergii , Dzhes Alexey , Łatka Leszek

Identyfikatory

DOI

10.2478/adms-2024-0021

• Języki publikacji: EN

Abstrakty

EN

The paper presents new results of manufacturing coatings by magnetron sputtering to improve the functional properties of joint endoprostheses. The antibacterial properties of Ti-Cu and Ta-Cu coatings deposited by DC multi-magnetron sputtering on Ti6Al4V alloy substrates subjected of gas-abrasive treatment have been investigated. The roughness of the substrate was measured by optical profilometry. The coating hardness and elastic modulus were estimated by nanoindentation methods; the adhesion characteristics were assessed by Rockwell test. Scanning electron microscopy with energy-dispersive X-ray analysis verified the application of coatings with 25 at.% Cu, at thicknesses of 2 μm and 10 μm to roughened Ti6Al4V alloy. All coatings demonstrated sufficient adhesion, whereas Ta-Cu coatings generally revealed higher hardness, while the elastic modulus decreased with increasing coating thickness. Staphylococcus aureus strains were used for in vitro study of the antibacterial properties of Ti-Cu and Ta-Cu coatings. The largest zones of inhibition of bacteria S. aureus 23 mm were observed for 10 μm Ta-Cu coating thickness. The release dynamics of Cu ions from Ta-Cu and Ti-Cu coatings into physiological solution analyzed over seven days via inductively coupled plasma mass spectrometry, matched the inhibition zone growth. The Ti-Cu and Ta-Cu coatings of 2 μm thickness provided weaker antibacterial effect. The optimal parameters of magnetron sputtering of antibacterial Ti-Cu and Ta-Cu coatings on Ti6Al4 alloy substrates were selected. These findings support the potential of these coatings in developing endoprosthesis implants with enhanced antimicrobial and wear-resistant properties.

Słowa kluczowe

EN

magnetron sputtering; antibacterial coatings; titanium implants

PL

rozpylanie magnetronowe; powłoki antybakteryjne; implanty tytanowe

• Wydawca: Politechnika Gdańska
• Czasopismo: Advances in Materials Science
• Rocznik: 2024
• Tom: Vol. 24, nr 4(82)
• Strony: 23--41
• Opis fizyczny: Bibliogr. 46 poz., rys., tab., wykr.

Twórcy

autor

Alontseva Darya

• School of Digital Technologies and Artificial Intelligence, D. Serikbayev East Kazakhstan Technical University, Ust-Kamenogorsk, Kazakhstan

autor

Azamatov Bagdat

• School of Digital Technologies and Artificial Intelligence, D. Serikbayev East Kazakhstan Technical University, Ust-Kamenogorsk, Kazakhstan
• Smart Engineering Competence Centre, D. Serikbayev East Kazakhstan Technical University, Ust- Kamenogorsk, Kazakhstan

autor

Borisov Alexander

• Smart Engineering Competence Centre, D. Serikbayev East Kazakhstan Technical University, Ust- Kamenogorsk, Kazakhstan

autor

Maratuly Bauyrzhan

• Smart Engineering Competence Centre, D. Serikbayev East Kazakhstan Technical University, Ust- Kamenogorsk, Kazakhstan

autor

Safarova (Yantsen) Yuliya

• Laboratory of Bioengineering and Regenerative Medicine, National Laboratory Astana, Nazarbayev University, Astana, Kazakhstan

autor

Voinarovych Sergii

• E.O. Paton Electric Welding Institute of NAS of Ukraine, Kyiv, Ukraine

autor

Dzhes Alexey

• Smart Engineering Competence Centre, D. Serikbayev East Kazakhstan Technical University, Ust- Kamenogorsk, Kazakhstan

autor

Łatka Leszek

• Department of Metal Forming, Welding and Metrology, Faculty of Mechanical Engineering, University of Science and Technology, Wrocław, Poland

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr POPUL/SP/0154/2024/02 w ramach programu "Społeczna odpowiedzialność nauki II" - moduł: Popularyzacja nauki (2025).