Removal of Cr(III) ions from water and wastewater by sorption onto peats and clays occurring in an overburden of lignite beds in central Poland

• Autorzy: Kyzioł-Komosińska J. , Rosik-Dulewska Cz. , Dzieniszewska A. , Pająk M. , Krzyżewska I.

Identyfikatory

DOI

10.5277/epe140101

• Języki publikacji: EN

Abstrakty

EN

Sorption capacities of low-moor peats and Neogene clays from the overburden of lignite beds in Central Poland for Cr(III) ions as chloride and metalorganic complex ions have been investigated. The binding mechanisms and sorption parameters were determined based on the Freundlich and Langmuir nonlinear sorption isotherms. The sorption capacities of studied materials for Cr(III) ions depended on their properties (porosity, average pore diameters, specific surface area and content of Fe hydroxyoxides) as well as charge of Cr(III) ions, functional groups and their diagonal lengths. Cr(III) ions from chlorides were bound onto sorbents via Coulomb attraction and by Fe hydroxy-oxides. However the complex Cr(III) ions were bound to the sorbent surface via hydrogen bonds between the dye -OH groups and =O of the sorbent functional groups. The equation parameters of sorption isotherms indicate cooperative heterogeneous adsorption at low Cr(III) concentrations and chemisorption at high Cr(III) concentrations

Słowa kluczowe

EN

chromium compounds; chlorine compounds; hydrogen bonds; iron compounds; isotherms; lignite; peat; sorption; metal-organic complexes; water; wastewater

PL

związki chromu; związki chloru; wiązania wodorowe; związki żelaza; izotermy; węgiel brunatny; torf; sorpcja; kompleksy metaloorganiczne; woda; ścieki

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2014
• Tom: Vol. 40, nr 1
• Strony: 5--22
• Opis fizyczny: Bibliogr. 25 poz., tab., rys.

Twórcy

autor

Kyzioł-Komosińska J.

• Institute of Environmental Engineering, Polish Academy of Sciences, ul. Skłodowskiej-Curie 34, 41-819 Zabrze, Poland
• Opole University, Department of Land Protection, ul. Oleska 22, 45-052 Opole, Poland

autor

Rosik-Dulewska Cz.

• Institute of Environmental Engineering, Polish Academy of Sciences, ul. Skłodowskiej-Curie 34, 41-819 Zabrze, Poland
• Opole University, Department of Land Protection, ul. Oleska 22, 45-052 Opole, Poland

autor

Dzieniszewska A.

• Institute of Environmental Engineering, Polish Academy of Sciences, ul. Skłodowskiej-Curie 34, 41-819 Zabrze, Poland

autor

Pająk M.

• Institute of Environmental Engineering, Polish Academy of Sciences, ul. Skłodowskiej-Curie 34, 41-819 Zabrze, Poland

autor

Krzyżewska I.

• Institute of Environmental Engineering, Polish Academy of Sciences, ul. Skłodowskiej-Curie 34, 41-819 Zabrze, Poland

Bibliografia

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