Sensitivity change of the modified carbon paste electrodes for detection of chlorinated phenoxyacetic acids

• Autorzy: Białek Arkadiusz , Skrzypczyńska Katarzyna , Kuśmierek Krzysztof , Świątkowski Andrzej

Identyfikatory

DOI

10.24425/cpe.2019.130209

• Języki publikacji: EN

Abstrakty

EN

Carbon paste electrode (CPE) was modified with F-300 commercial activated carbon or Norit SX- 2 powdered activated carbon. CPEs were prepared for detection of 2,4-dichlorophenoxyacetic acid (2,4-D), 2,6-dichlorophenoxyacetic acid (2,6-D) and 2,4,6-trichlorophenoxyacetic acid (2,4,6-T). The electrochemical behavior of these materials was investigated employing cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The modifier was found to enhance the electroactive surface area and the peak current in comparison to the bare (unmodified) carbon paste electrode. The intensity of the signal increased with the increase in adsorption ability of the modifiers. Compared to the unmodified electrode, all the new paste electrodes showed a much greater sensitivity for detection of chlorinated phenoxyacetic acids in water samples.

Słowa kluczowe

EN

2,4-D; 2,6-D; 2,4,6-T; voltammetry; carbon paste electrode; adsorption

PL

2,4-D; 2,6-D; 2,4,6-T; woltamperometria; elektroda pasty węglowej; adsorpcja

• Wydawca: Komitet Inżynierii Chemicznej i Procesowej Polskiej Akademii Nauk
• Czasopismo: Chemical and Process Engineering
• Rocznik: 2019
• Tom: Vol. 40, nr 3
• Strony: 315--–325
• Opis fizyczny: Bibliogr. 35 poz., tab., rys.

Twórcy

autor

Białek Arkadiusz

• Łukasiewicz Research Network – Institute of Industrial Organic Chemistry, 6 Annopol St., 03-236 Warsaw, Poland

autor

Skrzypczyńska Katarzyna

• Military University of Technology, Institute of Chemistry, 00-908 Warsaw, Poland

autor

Kuśmierek Krzysztof

• Military University of Technology, Institute of Chemistry, 00-908 Warsaw, Poland

autor

Świątkowski Andrzej

• Military University of Technology, Institute of Chemistry, 00-908 Warsaw, Poland

Bibliografia

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).