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The role of Ti, Zr and Ce in shaping of the Cr-Ni-Nb cast steel resistance to carburising

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Języki publikacji
EN
Abstrakty
PL
From the centrifugally cast Cr-Ni-Nb steel pipes, specimens were cut out and subjected to carburising for 100 hours in a mixture of charcoal (90%) and Na2CO3 (10%) at the temperatures of 950 and 1150°C. The specimens were cut in direction normal to the pipe axis and were examined by optical and scanning microscopy. As a parameter describing the resistance of the examined alloy to the carburising effect, the thickness of a carburised layer was accepted. It has been observed that additions of Ti and Zr, and of Ti+Zr+Ce introduced jointly, increase the thickness of the carburised layer, while the addition of Ce improves the alloy resistance to carburising. On the alloy surface, a layer composed of oxides, mainly of chromium, silicon and iron, has been formed. Changes in the chemical composition of the surface layer were examined by scanning microscopy.
Rocznik
Strony
144--148
Opis fizyczny
Bibliogr. 11 poz., rys., tab., wykr.
Twórcy
autor
  • AGH, Faculty of Foundry Engineering, Department of Cast Alloys and Composites Engineering, Reymonta street 23, 30-059 Cracow, Poland
autor
  • AGH, Faculty of Foundry Engineering, Department of Cast Alloys and Composites Engineering, Reymonta street 23, 30-059 Cracow, Poland
autor
  • AGH, Faculty of Foundry Engineering, Department of Cast Alloys and Composites Engineering, Reymonta street 23, 30-059 Cracow, Poland
Bibliografia
  • [1] V. W. Steinkusch, Aufkohlung von Schleudergussrohren in der petrochemischen Industrie und Erklärung dieses Verhaltens durch Laborversuche mit Cr-Ni-Stählen und-Werkstoffen im Temperaturbereich von 800÷1150°C Werkstoffe und Korrosion no 28 (1977) 1-6.
  • [2] Z. Bojarski i in., Exploitation problems of steam reformer catalytic tubes, Praca naukowa Uniwersytetu Śląskiego nr 266, Wydawnictwo Uniwersytetu Śląskiego (1978) (in Polish).
  • [3] J. Łabanowski, Examination of degradation process of catalytic tubes during exploitation in reformer methane, Wydawnictwo Politechniki Gdańskiej, Gdańsk (2003) (in Polish).
  • [4] G. Tęcza, R. Zapała, Technology of production segments of centrifugally tubes of Cr-Ni-Nb cast steels, XXIII Konferencja Naukowa z okazji Święta Odlewnika, Kraków (2004) s.53 – 57 (in Polish).
  • [5] M. Kupka, A. Wala A, Effect of carburization on some phisical properties of cast steel used in chemical and petrochemical installation, Ochrona przed Korozją no 6 (1979) 148–151 (in Polish).
  • [6] A. Rahmel, H.J. Grabke, W. Steinkusch, Carburization – introduction survey, Materials and Corrosion 49 (1998) 221-225.
  • [7] T. Shinohara, I. Kohchi, K. Shibata, J. Sugitani, K. Tsuchida, Development of nondestructive technique for measuring carburization thickness and of a new carburization-resistant alloy, Werkstoffe und Korrosion, no 37 (1986), 410-418.
  • [8] G. Palasantzas, H. J. Kooij, J. Th. M. De Hosson, Carbon induced metal dusting of iron-nickel-chromium alloy surfaces: a scanning auger microscopy study, Applied Surface Science no 229 (2004) 190-196.
  • [9] D. J. Tillack, J. E. Guthrie, Wrought and Cast Heat-Resistant Stainless Steels and Nickel Alloys for the Refining and petrochemical Industries, NiDI Technical Series, No. 10071 (1998).
  • [10] D.R.G Mitchell, D.J. Young, W. Kleemann, Carburisation of heat-resistant steel, Materials and Corrosion no 49 (1998) 231-236.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-77005b97-cf9e-48d2-83f6-5ced456a91fb
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