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In this paper, the nanocrystalline (Nd0.85Dy0.15)10Fe83Zr1B6 ribbons produced by melt-spinning have been investigated by the X-ray diffraction method (XRD), vibrating sample magnetometer (VSM) and magnetic force microscopy (MFM). The XRD studies showed that material investigated was mainly composed of Re2Fe14B and α-Fe phases with fine grain sizes of 25 and 9 nm, respectively. The magnetic parameters determined from the hysteresis loop measurements are as follows: μ0HC = 0.96 T, μ0MR = 0.76 T, μ0MS = 1.09 T, (BH)max = 88 kJ/m3. The large remanence ratio (μ0MR/μ0MS) of 0.7 results from the exchange coupling between the soft and hard magnetic grains. The large surface interaction domains revealed by MFM confirmed the existence of strong exchange coupling between nanosize grains.
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Tom
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117--122
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Bibliogr. 10 poz., rys., wykr.
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- Institute of Physics, Częstochowa University of Technology, al. Armii Krajowej 19, 42 200 Częstochowa, Poland
autor
- Institute of Physics, Częstochowa University of Technology, al. Armii Krajowej 19, 42 200 Częstochowa, Poland
autor
- Institute of Physics, Częstochowa University of Technology, al. Armii Krajowej 19, 42 200 Częstochowa, Poland
autor
- Institute of Physics, Częstochowa University of Technology, al. Armii Krajowej 19, 42 200 Częstochowa, Poland
autor
- Institute of Materials Engineering, Częstochowa University of Technology, al. Armii Krajowej 19, 42 200 Częstochowa, Poland
Bibliografia
- [1] THE N.D., HOA N.Q., OH S.K., YU S.C., ANH H.D., VU L.V., CHAU N., Crystalline evolution and large coercivity in Dy-doped (Nd,Dy)2Fe14B/α-Fe nanocomposite magnets, Journal of Physics D: Applied Physics 40(1), 2007, pp. 119–122.
- [2] ZHONGMIN CHEN, OKUMURA H., HADJIPANAYIS G.C., QUN CHEN, Enhacement of magnetic properties of nanocomposite Pr2Fe14B/α-Fe magnets by small substitution of Dy for Pr, Journal of Applied Physics 89(4), 2001, pp. 2299–2303.
- [3] WANG C., YAN M., LI Q., Effects of Nd and B contents on the thermal stability of nanocomposite (Nd,Zr)2Fe14B/α-Fe magnets, Materials Science and Engineering B 150(1), 2008, pp. 77–82.
- [4] XIAOQIAN BAO, JIE ZHU, WEI LI, XUEXU GAO, SHOUZENG ZHOU, Influence of zirconium addition on microstructure, magnetic properties and thermal stability of nanocrystalline Nd12.3Fe81.7B6.0 alloy, Journal of Rare Earths 27(5), 2009, pp. 843–847.
- [5] DOŚPIAŁ M., PŁUSA D., ŚLUSAREK B., Study of the magnetic interaction in nanocrystalline Pr–Fe–Co––Nb–B permanent magnets, Journal of Magnetism and Magnetic Materials 324(5), 2012, pp. 843–848.
- [6] SZMAJA W., GROBELNY J., CICHOMSKI M., HIROSAWA S., SHIGEMOTO Y., Magnetic force microscopy investigation of the domain structure of nanocomposite Nd2Fe14B/ Fe3B magnets, Acta Materialia 59(2), 2011, pp. 531–536.
- [7] AL-KHAFAJI M.A., RAINFORTH W.M., GIBBS M.R.J., DAVIES H.A., BISHOP J.E.L., Magnetic force microscopy of nanocrystalline NdFeB ribbons: A study of tip-sample interaction using a well--characterized sample, Journal of Magnetism and Magnetic Materials 182(1–2), 1998, pp. 111–123.
- [8] AL-KHAFAJI M.A., RAINFORTH W.M., GIBBS M.R.J., DAVIES H.A., BISHOP J.E.L., The effect of phase constitution on the magnetic structure of nanophase NdFeB alloys observed by magnetic force microscopy, Journal of Magnetism and Magnetic Materials 188(1–2), 1998, pp. 109–118.
- [9] STONER E.C., WOHLFARTH W.P., A mechanism of magnetic hysteresis in heterogeneous alloys, Philosophical Transactions of the Royal Society A 240(826), 1948, pp. 599–642.
- [10] GRÖNEFELD M., KRONMÜLLER H., Initial magnetization curve and hardening mechanism in rapidly quenched NdFeB magnets, Journal of Magnetism and Magnetic Materials 88(3), 1990, pp. L267–L274.
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Bibliografia
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