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The Influence of Mg Additive on the Structure and Electrical Conductivity of Pure Copper Castings

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The aim of this paper was to attain defect free, pure copper castings with the highest possible electrical conductivity. In this connection, the effect of magnesium additives on the structure, the degree of undercooling (ΔTα = Tα-Tmin, where Tα – the equilibrium solidification temperature, Tmin – the minimum temperature at the beginning of solidification), electrical conductivity, and the oxygen concentration of pure copper castings have been studied. The two magnesium doses have been investigated; namely 0.1 wt.% and 0.2 wt.%. A thermal analysis was performed (using a type-S thermocouple) to determine the cooling curves. The degree of undercooling and recalescence were determined from the cooling and solidification curves, whereas the macrostructure characteristics were conducted based on a metallographic examination. It has been shown that the reaction of Mg causes solidification to transform from exogenous to endogenous. Finally, the results of electrical conductivity have been shown as well as the oxygen concentration for the used Mg additives.
Rocznik
Strony
85--90
Opis fizyczny
Bibliogr. 31 poz., rys., tab., wykr.
Twórcy
autor
  • Foundry Research Institute, Zakopiańska 73, 30-418 Kraków, Poland
autor
  • AGH University of Science and Technology, Faculty of Foundry Engineering, Reymonta 23, 30-065 Krakow, Poland
autor
  • AGH University of Science and Technology, Faculty of Foundry Engineering, Reymonta 23, 30-065 Krakow, Poland
  • AGH University of Science and Technology, Faculty of Foundry Engineering, Reymonta 23, 30-065 Krakow, Poland
Bibliografia
  • [1] ASM Speciality Handbook, Copper and copper alloys. (2001). ASM International.
  • [2] Górny, Z. (2011). Copper and copper alloys with high conductivity. Cracow: Instytut Odlewnictwa.
  • [3] Vincent, C., Silvain, J.F., Heintz, J.M. & Chandra, N. (2012). Effect of porosity on the thermal conductivity of copper processed by powder metallurgy. J. Phys. Chem. Solids. 73, 499-504.
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  • [6] Hsu, Y.T. & O’Reilly, B. (1977). Impurity effects in high-conductivity copper. JOM. 29, 21-24.
  • [7] Bonderek, Z. & Rzadkosz, S. (2000). The phenomena of porosity in castings made of aluminium and magnesium alloys. Solidif. Met. Alloy. 2, 51-55.
  • [8] Lu, L., Shen, Y., Chen, X., Qian, L. & Lu, K. (2004). Ultrahigh Strength and High Electrical Conductivity in Copper. Science. 304, 422-426.
  • [9] Habibi, A., Ketabchi, M. & Eskandarzadeh, M. (2011). Nano-grained pure copper with high-strength and high-conductivity produced by equal channel angular rolling process. J. Mater. Process. Technol. 211, 1085-1090.
  • [10] Romankiewicz, F. (1995). Solidification of Copper and its alloys. Poznań- Zielona Góra: PAN.
  • [11] Zitňanský M. (1995). Refining of the Copper and investment casting. J. Mater. Process. Technol. 53, 499-507.
  • [12] Fu, Y., Chen, J., Liu, N., Lu, Y., Li, T. & Yin, G. (2011). Study of ultrahigh-purity copper billets refined by vacuum melting and directional solidification. Rare Met. 30, 304-309.
  • [13] Yamamura, S., Shiota, H., Murakami, K. & Nakajima, H. (2001). Evaluation of porosity in porous copper fabricated by unidirectional solidification under pressurized hydrogen, Mater. Sci. Eng. A. 318, 137-143.
  • [14] Lun, S., Sin, A. & Elsayed, C. (2013). Ravindran, Inclusions in magnesium and its alloys: a review, Int. Mater. Rev. 58, 419-436.
  • [15] Shahzeydi, M.H., Parvanian, A.M. & Panjepour, M. (2016). The distribution and mechanism of pore formation in copper foams fabricated by Lost Carbonate Sintering method. Mater. Charact. 111, 21-30.
  • [16] Li, B.Q. & Lu, X. (2011). The Effect of Pore Structure on the Electrical Conductivity of Ti. Transp. Porous Media. 87, 179-189.
  • [17] Cuevas, F.G., Montes, J.M., Cintas, J. & Urban, P. (2009). Electrical conductivity and porosity relationship in metal foams. J. Porous Mater. 16, 675-681.
  • [18] Gu, C.F., Hoffman, M., Toth, L.S. & Zhang, Y.D. (2015). Grain size dependent texture evolution in severely rolled pure copper. Mater. Charact. 101, 80-188.
  • [19] Miyajima, Y., Okubo, S., Abe, H., Okumura, H., Fujii, T., Onaka, S. & Kato, M. (2015). Dislocation density of pure copper processed by accumulative roll bonding and equal-channel angular pressing. Mater. Charact. 104, 101-106.
  • [20] Zi, A. (2010). Pure copper processed by extrusion preceded equal channel angular pressing. Mater. Charact. 61, 141-144.
  • [21] Benchabane, G., Boumerzoug, Z., Thibon, I. & Gloriant T. (2008). Recrystallization of pure copper investigated by calorimetry and microhardness. Mater. Charact. 59, 1425-1428.
  • [22] Zhang, Z.H., Wang, F.C., Wang, L., Li, S.K., Shen, M.W. & Osamu S. (2008). Microstructural characteristics of large-scale ultrafine-grained copper. Mater. Charact. 59, 329-333.
  • [23] Chen, J., Yan, W., Liu, C.X., Ding, R.G. & Fan, X.H. (2011). Dependence of texture evolution on initial orientation in drawn single crystal copper. Mater. Charact. 62, 237-242.
  • [24] Han, S.Z., Goto, M., Ahn, J.-H., Lim, S.H., Kim, S. & Lee, J. (2014). Grain growth in ultrafine grain sized copper during cyclic deformation. J. Alloys Compd. 615, S587-S589.
  • [25] Han, S.Z., Goto, M., Lim, C., Kim, S.-H. & Kim, S. (2009). Fatigue damage generation in ECAPed oxygen free copper. J. Alloys Compd. 483, 159-161.
  • [26] Kuhn, H.-A., Altenberger, I., Käufler, A., Hölzl, H. & Fünfer, M. (2012). Properties of High Performance Alloys for Electromechanical Connectors, in: Copp. Alloy. - Early Appl. Curr. Perform. - Enhancing Process. InTech, p 51-68.
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  • [28] Bydałek, A.W., Bydałek, A. & Czyż, M. (2000). The rational principle of the copper alloys refining. Solidif. Met. Alloy. 2, 65-71.
  • [29] Rzadkosz, S., Kozana, J. & Kranc, M. (2013). Researching the Influence of Chemical Composition and Technological Parameters on the Quality of Copper Alloys. Arch. Foundry Eng. 13, 153-158.
  • [30] Rzadkosz, S., Kranz, M., Nowicki, P. & Piękoś, M. (2009). Influence of refining operations on a structure and properties of copper and its selected alloys. Arch. Metall. Mater. 54, 299-304.
  • [31] Baker, H. Ed. (1992). ASM Handbook: Alloy phase diagrams. United States of America: 10th ed., ASM International.
Uwagi
PL
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-75b81c63-cee7-45fe-bfc1-4ddd5133fb32
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