Modelling of the Nitration of 2-Methylpyrimidine-4,6-dione (MPD)

• Autorzy: Belaada A. , Trzciński W. A. , Chyłek Z. C.

Identyfikatory

DOI

10.22211/cejem/92443

• Języki publikacji: EN

Abstrakty

EN

The conditions and kinetics of nitration of 2-methylpyrimidine-4,6-dione (MPD), which leads to the formation of 1,1-diamino-2,2-dinitroethene (DADNE, FOX7) via 5,5-dinitro-2-(dinitromethylene)pyrimidine-4,6-dione, are presented. An analysis of literature data enabled us to propose a simple model of the nitration of MPD. The model was verified on the basis of literature data and our own experimental data. The influence of the rate of addition of nitric acid, into a model reactor, on temperature and composition of the reaction mixture was investigated numerically. The proposed nitration model could be useful in a study of the MPD nitration process on a large scale.

Słowa kluczowe

EN

2-methylpyrimidine-4,6-dione; modelling of the nitration; kinetics

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2018
• Tom: Vol. 15, no. 3
• Strony: 516--533
• Opis fizyczny: Bibliogr. 8 poz., rys., tab.

Twórcy

autor

Belaada A.

• Military University of Technology, Gen. W. Urbanowicza 2 St., 00-908 Warsaw, Poland

autor

Trzciński W. A.

• Military University of Technology, Gen. W. Urbanowicza 2 St., 00-908 Warsaw, Poland

autor

Chyłek Z. C.

• Military University of Technology, Gen. W. Urbanowicza 2 St., 00-908 Warsaw, Poland

Bibliografia

• [1] Bellamy, A. J.; Latypov, N. V.; Goede, P. Studies on the Nitration of New Potential Precursors for FOX-7. New Trends Res. Energ. Mater., Proc. Semin., 7th, Pardubice, Czech Republic 2004, 75-82.
• [2] Latypov, N. V.; Langlet, A.; Wellmar, U. New Chemical Compound Suitable for Use as an Explosive, Intermediate and Method for Preparing the Compound. Patent WO99/03818, 1999.
• [3] Ostmark, H.; Bergman, H.; Bemm, U.; Goede, P.; Holmgren, E.; Johansson, M.; Langlet, A.; Latypov, N.; Pettersson, A.; Pettersson, M. L.; Wingborg, N.; Vorde, C.; Stenmark, H.; Karlsson, L.; Hihkio, M. 2,2-Dinitro-ethene-1,1-diamine (FOX-7) – Properties, Analysis and Scale-up. 32nd Int. Annu. Conf. ICT, Karlsruhe, Germany 2001, July 3-6.
• [4] Mandal, A. K.; Sahu, S. K.; Jadhav, V. V.; Narasimhan, V. L. Reaction Kinetics and Process Optimization for Nitration of 2-Methyl-4,6-dihydroxy-pyrimidine. Int. Autumn Seminar on Propellants, Explosive and Pyrotechnics, Xian, China 2007, 78-85.
• [5] Chyłek, Z. Investigation of Kinetics of Nitration of 2-Methyl-4,6-pyrimidine-4,6(1H,5H)-dione. (in Polish) Biuletyn WAT 2008, 56(3): 27-37.
• [6] Chyłek, Z.; Trzciński, W. A. Calorimetric and Theoretical Investigation of Heat Effects and Reaction Kineticsfor Nitration of 2-Methyl-4,6-dihydroxy-pyrimidine. (in Polish) Biuletyn WAT 2012, 61(3): 303-317.
• [7] Kushtaev, A.; D’yakonov, A. Nitration Kinetics of 6-Hydroxy-2-methylpyrimidin-4(3H)-one and 2-Methoxy-2-methylimidazolidine-4,5-dione. Russ. J. Appl. Chem. 2009, 82(10): 1785-1791.
• [8] Trzciński, W. A.; Chyłek, Z. Modelling of the Synthesis of 1,1-Diamino-2,2-dinitroethene (DADNE). Cent. Eur. J. Energ. Mater. 2012, 9(2): 101-117.

Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).