Application of deep eutectic solvents combined with vortex assisted dispersive liquid-liquid microextraction for five organophosphorus pesticides in juice and green tea beverage

• Autorzy: Zhao Mingyu , Zhao Ercheng , Wu Junxue , Li Yuqi , Baotong Li

Identyfikatory

DOI

10.1556/1326.2020.00866

• Języki publikacji: EN

Abstrakty

EN

In this study, a new microextraction method based on hydrophobic deep eutectic solvents was developed for the extraction and preconcentration of organophosphorus pesticides from beverage samples. The hydrophobic deep eutectic solvents were synthesized from choline chloride and 4-chlorophenol. Main experimental parameters of the microextraction method were investigated to improve the extraction efficiency. The proposed method achieved a satisfactory linear range between 50 and 2,000 μg L^-1 with coefficient of determination greater than 0.9939. The extraction recoveries and enrichment factor of five organophosphorus pesticides at three added levels ranged from 71.68 to 113.18% and 71.43–111.11 were obtained with the acceptable relative standard deviation ranged from 1.37 to 11.92%. Limits of detection and quantification were found to be 0.05–0.3 μg L^-1 and 0.17–1 μg L^-1, respectively. Finally, the methods were successfully applied for the determination of five organophosphorus pesticide in orange juice and green tea.

Słowa kluczowe

EN

beverage; deep eutectic solvents; dispersive liquid–liquid microextraction; organophosphorus pesticides

• Wydawca: University of Silesia in Katowice ; Akademiai Kiado
• Czasopismo: Acta Chromatographica
• Rocznik: 2022
• Tom: Vol. 34, no. 1
• Strony: 53--60
• Opis fizyczny: Bibliogr. 28 poz., rys., tab.

Twórcy

autor

Zhao Mingyu

• College of Land Resources and Environment, Jiangxi Agricultural University, Nanchang, China
• Institute of Plant and Environment Protection, Beijing Academy of Agricultural and Forestry Sciences, Beijing, China

• https://orcid.org/0000-0001-6594-6014

autor

Zhao Ercheng

• Institute of Plant and Environment Protection, Beijing Academy of Agricultural and Forestry Sciences, Beijing, China

autor

Wu Junxue

• Institute of Plant and Environment Protection, Beijing Academy of Agricultural and Forestry Sciences, Beijing, China

autor

Li Yuqi

• College of Engineering, Jiangxi Agricultural University, Nanchang, China

autor

Baotong Li

• College of Land Resources and Environment, Jiangxi Agricultural University, Nanchang, China

• https://orcid.org/0000-0002-9435-4509

Bibliografia

• 1. Van Boxstael, S.; Habib, I.; Jacxsens, L.; De Vochtac, M.; Baerta, L.; Van De Perred, E.; Rajkovicae, A.; Lopez-Galveza, F.; Sampersaf, I.; Spanogheg, P.; De Meulenaerd, B.; Uyttendaelea, M. Food safety issues in fresh produce: Bacterial pathogens, viruses and pesticide residues indicated as major concerns by stakeholders in the fresh produce chain. Food Control 2013, 32(1), 190–7.
• 2. Menglei, X.; Jingbo, L.; Lu, J. Determination and control of pesticide residues in beverages: A review of extraction techniques, chromatography, and rapid detection methods. Appl. Spectroscopy Rev. 2014, 49(2), 97–120.
• 3. Ribeiro, C.; Ribeiro, A. R.; Maia, A. S.; Gonçalves, V. M. F.; Tiritan, M. E. New trends in sample preparation techniques for environmental analysis. Critical Rev. Analyt. Chem. 2014, 44(2), 142–85.
• 4. Anastassiades,M.; Lehotay, S. J.; Stajnbaher, D.; Schenck, F. J. Fast and easy multiresidue method employing acetonitrile extraction/partitioning and “dispersive solid-phase extraction” for the determination of pesticide residues in produce. J. AOAC Int. 2003, 86(2), 412–31.
• 5. Hennion, M. C. Solid-phase extraction: method development, sorbents, and coupling with liquid chromatography. J. Chromatogr A 1999, 856(1–2), 3–54.
• 6. Pena-Pereira, F.; Lavilla, I.; Bendicho, C. Miniaturized preconcentration methods based on liquid–liquid extraction and their application in inorganic ultratrace analysis and speciation: A review. Spectrochimica Acta B: Atomic Spectrosc., 2009, 64(1), 1–15.
• 7. Herrero, M. ; Mendiola, J. A. ; Cifuentes, A. ; Ibáñez, E. Supercritical fluid extraction: Recent advances and applications. J. Chromatogr. A 2010, 1217(16), 2495–2511.
• 8. Richter, B. E.; Jones, B. A.; Ezzell, J. L.; Porter, N. L.; Avdalovic, N.; Pohl, C. Accelerated solvent extraction: A technique for sample preparation. Analyt. Chem. 1996, 68(6), 1033–9.
• 9. Carasek, E.; Merib, J.; Mafra, G.; Spudeit, D. A recent overview of the application of liquid-phase microextraction to the determination of organic micro-pollutants. Trends Analyt. Chem. 2018, 108, 203–9.
• 10. Rezaee, M.; Assadi, Y.; Milani Hosseini, M. R.; Aghaee, E.; Ahmadi, F.; Berijani, S. Determination of organic compounds in water using dispersive liquid–liquid microextraction. J. Chromatogr. A 2006, 1116, 1–9.
• 11. Zgoła-Grześkowiak, A.; Grześkowiak, T. Dispersive liquid-liquid microextraction. TrAC Trends Analyt. Chem. 2011, 30(9), 1382–99.
• 12. Fisichella, M.; Odoardi, S.; Strano-Rossi, S. High-throughput dispersive liquid/liquid microextraction (DLLME) method for the rapid determination of drugs of abuse, benzodiazepines and other psychotropic medications in blood samples by liquid chromatography–tandem mass spectrometry (LC-MS/MS) and application to forensic cases. Microchem. J. 2015, 123, 33–41.
• 13. Jovanov, P. ; Guzsvány, V. ; Franko, M. ; Lazić, S. ; Sakač, M. ; Milovanović, I. ; Nedeljković, N. Development of multiresidue DLLME and QuEChERS based LC–MS/MS method for determination of selected neonicotinoid insecticides in honey liqueur. Food Res. Int. 2014, 55, 11–19.
• 14. Karami-Osboo, R.; Shojaee, M. H.; Miri, R.; Kobarfard, F.; Javidnia, K. Simultaneous determination of six fluoroquinolones in milk by validated QuEChERS-DLLME HPLC-FLD. Anal. Methods 2014, 6(15), 5632–8.
• 15. Huddleston, J. G.; Willauer, H. D.; Swatloski, R. P.; Visser, A. E.; Rogers, R. D. Room temperature ionic liquids as novel media for “clean” liquid–liquid extraction. Chem. Commun. 1998, 16, 1765–6.
• 16. Plechkova, N. V.; Seddon, K. R. Applications of ionic liquids in the chemical industry. Chem. Society Rev. 2008, 37(1), 123–50.
• 17. Abbott, A. P.; Boothby, D.; Capper, G.; Davies, D. L.; Rasheed, R. K.. Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids. J. Am. Chemical Soc. 2004, 126(29), 9142–7.
• 18. Smith, E. L.; Abbott, A. P.; Ryder, K. S. Deep Eutectic Solvents (DESs) and their applications. Chem. Rev. 2014, 114(21), 11060–82.
• 19. Zhang, Q. ; De Oliveira Vigier, K. ; Royer, S. ; Jérôme, F. Deep eutectic solvents: syntheses, properties and applications. Chem. Soc. Rev. 2012, 41(21), 7108–7146.
• 20. Chakrabarti, M. H.; Mjalli, F. S.; AlNashef, I. M.; Hashim, M. A.; Hussain, M. A.; Bahadori, L.; Low, C. T. J. Prospects of applying ionic liquids and deep eutectic solvents for renewable energy storage by means of redox flow batteries. Renew. Sustain. Energy Rev. 2014, 30, 254–70.
• 21. Carriazo, D. , Serrano, M. C. ; Gutiérrez, M. C. ; Ferrer, M. L. ; del Monte, F. Deep-eutectic solvents playing multiple roles in the synthesis of polymers and related materials. Chem. Soc. Rev. 2012, 41(14), 4996–5014.
• 22. Wagle, D. V.; Zhao, H.; Baker, G. A. Deep eutectic solvents: Sustainable media for nanoscale and functional materials. Account Chem. Res. 2014, 47(8), 2299–308.
• 23. Lu, W. D.; Liu, S. J.; Wu, Z. L. Recent application of deep eutectic solvents as green solvent in dispersive liquid–liquid microextraction of trace level chemical contaminants in food and water. Critical Rev. Analyt. Chem. 2020, 1–15.
• 24. Khezeli, T.; Daneshfar, A.; Sahraei, R. Emulsification liquid–liquid microextraction based on deep eutectic solvent: An extraction method for the determination of benzene, toluene, ethylbenzene and seven polycyclic aromatic hydrocarbons from water samples. J. Chromatogr. A 2015, 1425, 25–33.
• 25. Sun, P.; Gao, Y. L.; Xu, C.; Lian, Y. F. Determination of six organophosphorus pesticides in water samples by three-dimensional graphene aerogel-based solid-phase extraction combined with gas chromatography/mass spectrometry. RSC Adv. 2018, 8(19), 10277–83.
• 26. Tette, P. A. S. ; da Silva Oliveira, F. A. ; Pereira, E. N. C. ; Silva, G. ; de Abreu Glória, M. B. ; Fernandes, C. Multiclass method for pesticides quantification in honey by means of modified QuEChERS and UHPLC–MS/MS. Food Chem. 2016, 211, 130–139.
• 27. Farajzadeh, M. A.; Mohebbi, A. Development of magnetic dispersive solid phase extraction using toner powder as an efficient and economic sorbent in combination with dispersive liquid–liquid microextraction for extraction of some widely used pesticides in fruit juices. J. Chromatogr. A 2018, 1532, 10–9.
• 28. Farajzadeh, M. A.; Abbaspour, M.; Kazemian, R. Synthesis of a green high density deep eutectic solvent and its application in microextraction of seven widely used pesticides from honey. J. Chromatogr. A 2019, 1603, 51–60.

Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).