Construction chemicals production wastewaters treatment. Part 1. Sludge from one-stage pretreatment

• Autorzy: Rauckyte-Żak T. , Żak S.

Identyfikatory

DOI

10.2429/proc.2017.11(2)042

Warianty tytułu

PL

Oczyszczanie ścieków z produkcji chemii budowlanej. Część 1. Osady z jednostopniowego podczyszczania

• Konferencja: ECOpole’17 Conference (4-7.10.2017 ; Polanica Zdrój, Poland)
• Języki publikacji: EN

Abstrakty

EN

This section gives an overview of the results of the evaluation of sludge generated under conditions of full technological scale in three similar installations as a result of the use of single-stage, physicochemical pretreatment of mixed processing wastewater from the production of construction chemicals. The wastewater originated mainly from manufacturing water-based paints and silicone renders for façades of concrete structures and for interiors, adhesive mortars and glazes, protective and decorative plasters, gypsum finishing and putty coats, self-levelling compounds, as well as grouts and sealing coats. Sludge were separated due to coagulation and chemical precipitation and floatation thickening; their dewatering was conducted in filtering appliances in a form of open gravity bag filters or in a pressurized chamber filter press. For “non-anhydrous” samples of dewatered sludge obtained using PIX® based iron(III) or PAX® based aluminum coagulants, toxicity characteristic leaching procedures (TCLP) were carried out and using fractionation the risk assessment code (RAC) was determined. It was found that the sludge dewatered by gravity or pressure indicate a low risk (LR) against Cd, Cr, Cu, Ni, Mn, Pb and Zn. In accordance with the TCLP criteria, they were classified as non-toxic waste.

PL

W tej części przedstawiono wyniki oceny osadów generowanych w warunkach pełnej skali technologicznej na trzech zbliżonych konfiguracyjnie instalacjach w wyniku zastosowania jednostopniowego, fizykochemicznego podczyszczania mieszanych ścieków technologicznych z produkcji chemii budowlanej. Ścieki pochodziły głównie z linii wytwarzania wodorozcieńczalnych farb i tynków silikonowych do elewacji konstrukcji betonowych i wnętrz, zapraw klejących i glazur, tynków ochronnych oraz ozdobnych, gładzi gipsowych i szpachlowych, zapraw samopoziomujących, a także mas fugowych i powłok uszczelniających. Osady wydzielano w wyniku koagulacji i strącania chemicznego oraz flokulacyjnego zagęszczania, a ich odwadnianie prowadzono na zespołach filtracyjnych, stanowiących otwarte grawitacyjne filtry workowe, lub na ciśnieniowej, komorowej prasie filtracyjnej. Dla „niebezwodnych” prób odwodnionych osadów uzyskiwanych koagulantami żelazowymi klasy PIX® lub glinowymi klasy PAX® przeprowodzono procedury wymywalności TCLP oraz ocenę ryzyka za pomocą frakcjonowania, stosując kod RAC. Stwierdzono, że odwodnione grawitacyjnie lub ciśnieniowo osady wykazują niskie ryzyko (LR) względem Cd, Cr, Cu, Ni, Mn, Pb and Zn. Zgodnie z kryteriami TCLP, sklasyfikowano je jako odpady nietoksyczne.

Słowa kluczowe

EN

sludge from construction chemicals production; sludge from one-stage physicochemical pretreatment; TCLP test; risk assessment code; RAC

PL

ścieki technologiczne z produkcji chemii budowlanej; osady z jednostopniowego podczyszczania fizykochemicznego; test TCLP; kod oceny ryzyka; RAC

• Wydawca: Towarzystwo Chemii i Inżynierii Ekologicznej
• Czasopismo: Proceedings of ECOpole
• Rocznik: 2017
• Tom: Vol. 11, No. 2
• Strony: 403--414
• Opis fizyczny: Bibliogr. 53 poz., tab.

Twórcy

autor

Rauckyte-Żak T.

• Faculty of Chemical Technology and Engineering, University of Science and Technology, ul. Seminaryjna 3, 85-326 Bydgoszcz, Poland

autor

Żak S.

• Faculty of Chemical Technology and Engineering, University of Science and Technology, ul. Seminaryjna 3, 85-326 Bydgoszcz, Poland

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).