Effects of long-term storage of phosphate sludges on their physicochemical properties, the distribution and mobility of heavy metals, and acid generation

• Autorzy: Arroug Lamya , Elaatmani Mohamed , Zegzouti Abdelouahad , Afqir Mohamed , Ibnoussina Mounsif , Babram Mohammed Ait

Identyfikatory

DOI

10.37190/epe210205

• Języki publikacji: EN

Abstrakty

EN

Some phosphate sludges (Ps) were collected in 2009, 2014, and 2018. Results of their analyses by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM-SED), differential thermal and thermogravimetric analyses (TG-DTA) and X-ray fluorescence spectrometry (XRF) confirmed that the Ps are highly carbonated. Descriptive and exploratory statistical procedures for heavy metals (HM) concentrations and chemical parameters were performed and revealed the differences between the Ps of three different ages. The results indicate that there are three sources responsible for the behavior of Ps over years: common origin and accumulation of HIM and solar radiation exposure. The sequential extraction shows that the residual fractions of Cd, Ni, Zn, Pb, and Cr were predominant The mobility factor was quite low and did not change over the years, except for Cd. The net acid generation pH for the three samples was greater than 4.5 classifying the Ps as non-acid-generating.

Słowa kluczowe

EN

phosphate sludge; X-ray diffraction; soil; contamination

PL

osad fosforowy; dyfrakcja rentgenowska; gleba; zanieczyszczenie

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2021
• Tom: Vol. 47, nr 2
• Strony: 59--81
• Opis fizyczny: Bibliogr. 25 poz., rys., tab.

Twórcy

autor

Arroug Lamya

• Laboratory of Materials Science and Process Optimization, Cadi Ayyad University, Semlalia Faculty of Science, Marrakech, Morocco

• https://orcid.org/0000-0001-5698-7121

autor

Elaatmani Mohamed

• Laboratory of Materials Science and Process Optimization, Cadi Ayyad University, Semlalia Faculty of Science, Marrakech, Morocco

• https://orcid.org/0000-0002-0986-0045

autor

Zegzouti Abdelouahad

• Laboratory of Materials Science and Process Optimization, Cadi Ayyad University, Semlalia Faculty of Science, Marrakech, Morocco

• https://orcid.org/0000-0002-4447-3876

autor

Afqir Mohamed

• Laboratory of Materials Science and Process Optimization, Cadi Ayyad University, Semlalia Faculty of Science, Marrakech, Morocco

• https://orcid.org/0000-0002-2636-8810

autor

Ibnoussina Mounsif

• Laboratory of Geodynamics, Geomatics, and Geotechnics, Cadi Ayyad University, Semlalia Faculty of Science, Marrakech, Morocco

• https://orcid.org/0000-0003-0733-687X

autor

Babram Mohammed Ait

• Department of Mathematics of the Faculty of Science and Technology, Cadi Ayyad University, Marrakech, Morrocco

• https://orcid.org/0000-0003-1958-466X

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