Preparation and Characterization of Ultrafine HMX/TATB Explosive Co-crystals

• Autorzy: An C. , Li H. , Zhang Y. , Ye B. , Xu C. , Wang J.

Identyfikatory

DOI

10.22211/cejem/77125

• Języki publikacji: EN

Abstrakty

EN

An explosive co-crystal of 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane (HMX) and 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) was prepared by the ball milling method. The raw materials and co-crystals were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), differential scanning calorimetry (DSC) and Raman spectroscopy. Impact and friction sensitivity of the co-crystals were tested and analyzed. The results showed that the HMX/TATB co-crystals are spherical in shape and 100-300 nm in size. The co-crystals are different from anintimate mixture of HMX/TATB and they exhibit a new co-crystal structure. HMX/TATB co-crystals are formed by N-O···H hydrogen bonding between −NO2 (HMX) and −NH2 (TATB). The drop height of ultrafine HMX/TATB explosive co-crystals is 12.7 cm higher than that of ultrafine HMX, whilst the explosion probability of friction is 20% lower than that of ultrafine HMX. Ultrafine HMX/TATB explosive co-crystals are difficult to initiate under impact and friction conditions.

Słowa kluczowe

EN

HMX; TATB; ultrafine co-crystals; ball milling; mechanical sensitivity

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2017
• Tom: Vol. 14, no. 4
• Strony: 876--887
• Opis fizyczny: Bibliogr. 31 poz., rys., tab.

Twórcy

autor

An C.

• School of Environment and Safety Engineering/Shanxi Engineering Technology Research Center for Ultrafine Powder, North University of China, Xueyuan Road No. 3, 030051 Shanxi Taiyuan, China

autor

Li H.

• School of Environment and Safety Engineering/Shanxi Engineering Technology Research Center for Ultrafine Powder, North University of China, Xueyuan Road No. 3, 030051 Shanxi Taiyuan, China

autor

Zhang Y.

• The 213th Research Institute of China Ordnance Industry, Xi’an 710061, Shaanxi, China

autor

Ye B.

• School of Environment and Safety Engineering/Shanxi Engineering Technology Research Center for Ultrafine Powder, North University of China, Xueyuan Road No. 3, 030051 Shanxi Taiyuan, China

autor

Xu C.

• School of Environment and Safety Engineering/Shanxi Engineering Technology Research Center for Ultrafine Powder, North University of China, Xueyuan Road No. 3, 030051 Shanxi Taiyuan, China

autor

Wang J.

• School of Environment and Safety Engineering/Shanxi Engineering Technology Research Center for Ultrafine Powder, North University of China, Xueyuan Road No. 3, 030051 Shanxi Taiyuan, China

Bibliografia

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).