Characterization of SnO₂/TiO₂ with the Addition of Polyethylene Glycol via Sol-Gel Method for Self-Cleaning Application

• Autorzy: Halin Dewi Suriyani Che , Azliza Azani , Razak Kamrosni Abdul , Abdullah Mohd Mustafa Al Bakri , Salleh Mohd Arif Anuar Mohd , Wahab Juyana A , Chobpattana Varistha , Kaczmarek Łukasz , Nabiałek Marcin , Jeż Bartłomiej

Identyfikatory

DOI

10.24425/amm.2023.141500

• Języki publikacji: EN

Abstrakty

EN

TiO₂ is one of the most widely used metal oxide semiconductors in the field of photocatalysis for the self-cleaning purpose to withdraw pollutants. Polyethylene glycol (PEG) is recommended as a stabilizer and booster during preparation of water-soluble TiO₂. Preparation of SnO₂/TiO₂ thin film deposition on the surface of ceramic tile was carried out by the sol-gel spin coating method by adding different amount of PEG (0g, 0.2g, 0.4g, 0.6g, 0.8g) during the preparation of the sol precursor. The effects of PEG content and the annealing temperature on the phase composition, crystallite size and the hydrophilic properties of SnO₂/TiO₂ films were studied. The X-ray diffraction (XRD) spectra revealed different phases existed when the films were annealed at different annealing temperatures of 350°C, 550°C and 750°C with 0.4 g of PEG addition. The crystallite sizes of the films were measured using Scherrer equation. It shows crystallite size was dependent on crystal structure existed in the films. The films with mixed phases of brookite and rutile shows the smallest crystallite size. In order to measure the hydrophilicity properties of films, the water contact angles for each film with different content of PEG were measured. It can be observed that the water contact angle decreased with the increasing of the content of PEG. It shows the superhydrophilicity properties for the films with the 0.8 g of PEG annealed at 750°C. This demonstrates that the annealed temperature and the addition of PEG affect the phase composition and the hydrophilicity properties of the films.

Słowa kluczowe

EN

TiO2; SnO2; thin film; polyethylene glycol; self-cleaning

• Wydawca: Institute of Metallurgy and Materials Science of Polish Academy of Sciences ; Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences
• Czasopismo: Archives of Metallurgy and Materials
• Rocznik: 2023
• Tom: Vol. 68, iss. 1
• Strony: 243--248
• Opis fizyczny: Bibliogr. 26 poz., fot., rys., tab.

Twórcy

autor

Halin Dewi Suriyani Che

• Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CEGeoGTech), Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Perlis Malaysia

• https://orcid.org/0000-0003-0224-8029

autor

Azliza Azani

• Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CEGeoGTech), Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Perlis Malaysia

• https://orcid.org/0000-0002-7954-6385

autor

Razak Kamrosni Abdul

• Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CEGeoGTech), Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Perlis Malaysia

• https://orcid.org/0000-0002-5820-2401

autor

Abdullah Mohd Mustafa Al Bakri

• Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CEGeoGTech), Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Perlis Malaysia

• https://orcid.org/0000-0002-9779-8586

autor

Salleh Mohd Arif Anuar Mohd

• Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CEGeoGTech), Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Perlis Malaysia

• https://orcid.org/0000-0002-9523-7558

autor

Wahab Juyana A

• Universiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CEGeoGTech), Perlis, Malaysia
• Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Perlis Malaysia

• https://orcid.org/0000-0002-8234-1364

autor

Chobpattana Varistha

• Rajamangala University of Technology Thanyaburi (RMUTT), Faculty of Engineering, Department of Materials and Metallurgical Engineering, Thailand

• https://orcid.org/0000-0001-7611-0730

autor

Kaczmarek Łukasz

• Lodz University of Technology (TUL), Institute of Materials Science and Engineering,1/15, Stefanowskiego Str., 90-924 Lodz, Poland

• https://orcid.org/0000-0002-6163-3608

autor

Nabiałek Marcin

• Czestochowa University of Technology, Department of Physics, 19 Armii Krajowej Av., 42-200 Czestochowa, Poland

• https://orcid.org/0000-0001-6585-3918

autor

Jeż Bartłomiej

• Czestochowa University of Technology, Department of Physics, 19 Armii Krajowej Av., 42-200 Czestochowa, Poland

• https://orcid.org/0000-0002-7918-5946

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Uwagi

1. The author would like to acknowledge the support from the Fundamental Research Grant Scheme (FRGS) under a grant number of FRGS/1/2017/TK07/UNIMAP/02/6 from the Ministry of Education Malaysia and under grant number 9002-0082 from Tin Board Industry Grant. The authors wish to thank the Center of Excellence Geopolymer & Green Technology (CEGeoGTech), School of Materials, Engineering, Universiti Malaysia Perlis, UniMAP for their partial support.

2. Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).