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Thermal Analysis and Sensitivity Studies on Guanylurea Dinitramide (GUDN or FOX-12) Based Melt Cast Explosive Formulations

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Guanylurea dinitramide (GUDN or FOX-12) is a stable salt of dinitramidic acid with good thermal stability, and is a good candidate for insensitive formulations. Thermal analysis reveals the compatibility of GUDN with benchmark explosives such as RDX and TNT in melt cast explosive formulations. The paper describes a thermal and sensitivity study of GUDN with RDX and TNT. In the present study GUDN was evaluated as a possible replacement for RDX/TNT based aluminized and non aluminized melt cast explosive formulations. The thermal properties of the composition were investigated as well as its sensitivity to impact and friction. Its thermal decomposition behavior was compared to a control composition based on RDX and TNT. The thermal and sensitivity results proved the worth of these compositions for melt cast explosive applications.
Rocznik
Strony
296--303
Opis fizyczny
Bibliogr. 12 poz., rys., tab.
Twórcy
autor
  • High Energy Materials Research Laboratory, Pune - 411 021, India
autor
  • High Energy Materials Research Laboratory, Pune - 411 021, India
Bibliografia
  • [1] Insensitive Munitions. Defence Instruction (General) DI(G) LOG 07-10, Australian Defence Organisation, Canberra 1993.
  • [2] Fouche, F.; Van S, TNT-based Insensitive Munitions. 27th Int. Annu. Conf. ICT, Karlsruhe, Germany 1996, paper 69.
  • [3] Barnard, P.; Fouche, F.; Bezuidenhout, H. Less Sensitive TNT-based Formulations. 3rd Australian Ordnance Symposium (Parari 97), Canberra 1997.
  • [4] Blomquist, H. Gas Generating Compositions Comprising Guanylurea Dinitramide. Patent US 6,117, 255, 2000.
  • [5] Bottaro, J. C. Recent Advances in Explosives and Solid Propellants. Chem. Ind. 1996, 10: 249.
  • [6] Bottaro, J.; Schmitt, R.; Penwell, P.; Ross, S. Dinitramide Salts and Method of Making Same. Patent US 5254324, 1993.
  • [7] Ostmark, H.; Bemm, U.; Bergman, H.; Langlet, A. N-guanylurea Dinitramide: a New Energetic Material with Low Sensitivity for Propellants and Explosives Applications. Thermochim. Acta 2002, 384: 253-258.
  • [8] Zhao, F.; Chen, P.; Yuan, H.; Gao, S.; Hu, R. Thermochemical Properties and Non-isothermal Decomposition Reaction Kinetics of N-Guanylurea Dinitramide (GUDN). Chin. J. Chem. 2004, 22: 136-141.
  • [9] Langlet, A., Ostmark, H., Wingborg, N. Method of Preparing Dinitramidic Acid and Salts thereof. Patent US 5976483 A, 1999.
  • [10] Mishra, V.; Vadali, S.; Garg, R.; Joshi, V.; Wsanik, R.; Asthana, S. Studies on FOX-7 Based Melt Cast High Explosives Formulations. Cent. Eur. J. Energ. Mater. 2013, 10(4): 569-580.
  • [11] Yan, Q.-L.; Gozin, M.; Zhao, F.-Q.; Cohen, A.; Pang, S.-P. Highly Energetic Compositions Based on Functionalized Carbon Nanomaterials. Nanoscale 2016, 8: 4799-4851.
  • [12] Kissinger, H. Reaction Kinetics in Differential Thermal Analysis. Anal. Chem. 1957, 29: 1702-1706.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-7298d84b-552f-44c0-994c-ce6b31cc9a1b
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