Multivoltaic GaSe clathrate as new hybrid functional nanostructure

• Autorzy: Ivashchyshyn Fedir , Pidluzhna Anna , Calus Dariusz , Hryhorchak Orest , Chabecki Piotr , Makarchuk Oleksandr

Identyfikatory

DOI

10.24425/bpasts.2021.136726

• Języki publikacji: EN

Abstrakty

EN

The electrical properties and behaviour in constant magnetic field of fourfold expanded GaSe matrix intercalated with SmCl 3 guest were investigated by means of impedance spectroscopy and cyclic voltammetry. It was determined that the synthesized GaSe< SmCl 3> clathrate of 4-fold expansion demonstrates the coexistence of mechanisms of generation, transformation and accumulation of electric energy on a quantum level. These mechanisms are driven from external sources of magnetic, thermal and electric field without Faradaic reactions. Therefore, investigated GaSe< SmCl 3> structure is of great attraction in multivoltaics as a prototype of new class of materials. Quantum mechanical model of electro motive force of spin nature is proposed. The main focus of work lies in the prospects of synthesized clathrates for the development of power nanosources and gyrator-free delay nanolines controlled by means of magnetic field.

Słowa kluczowe

EN

impedance analysis; GaSe; multiferroic; thermogalvanic effect; negative capacity

PL

analiza impedancji; GaSe; multiferroiki; efekt termogalwaniczny; pojemność ujemna

• Wydawca: Polska Akademia Nauk, Wydział IV Nauk Technicznych
• Czasopismo: Bulletin of the Polish Academy of Sciences. Technical Sciences
• Rocznik: 2021
• Tom: Vol. 69, nr 2
• Strony: art. no. e136726
• Opis fizyczny: Bibliogr. 28 poz., rys.

Twórcy

autor

Ivashchyshyn Fedir

• Czestochowa University of Technology, Al. Armii Krajowej 17, 42-200 Czestochowa, Poland
• Lviv Polytechnic National University, Bandera 12, Lviv, 79013, Ukraine

• https://orcid.org/0000-0002-6919-5841

autor

Pidluzhna Anna

• Czestochowa University of Technology, Al. Armii Krajowej 17, 42-200 Czestochowa, Poland

• https://orcid.org/0000-0003-1138-8736

autor

Calus Dariusz

• Czestochowa University of Technology, Al. Armii Krajowej 17, 42-200 Czestochowa, Poland

autor

Hryhorchak Orest

• Ivan Franko Lviv National University, Cyril and Methodius 8, Lviv, 79005, Ukraine

• https://orcid.org/0000-0003-0668-1903

autor

Chabecki Piotr

• Czestochowa University of Technology, Al. Armii Krajowej 17, 42-200 Czestochowa, Poland

autor

Makarchuk Oleksandr

• Czestochowa University of Technology, Al. Armii Krajowej 17, 42-200 Czestochowa, Poland
• Lviv Polytechnic National University, Bandera 12, Lviv, 79013, Ukraine

• https://orcid.org/0000-0002-9817-6113

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).