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Emissions of reactive nitrogen compounds (RNCs) from two vehicles with turbocharged spark ignition engines over cold start driving cycles

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Języki publikacji
EN
Abstrakty
EN
This paper reviews the emissions of reactive nitrogen compounds (RNCs) from modern vehicles fitted with spark ignition engines and three-way catalysts. Specific aspects of the pollutants involved - and their formation - are discussed. Cold start driving cycles are scenarios under which emissions of all four RNCs can be significant; the mechanisms behind emissions trends are explored. Experimental data obtained from two vehicles tested over two different cold start driving cycles are presented and analysed. The use of gravimetric and molar metrics are explored. Ammonia, a species which is currently not regulated for passenger cars in any automotive market, is identified as forming the majority of the RNC emissions over the entire driving cycle. While ammonia emissions are strongly linked to aftertreatment system warmup and periods of high load, significant ammonia emissions were also measured under certain hot-running, low load conditions, and even at idle. For the majority of the duration of the test procedures employed, the RNC profile was dominated by ammonia, which accounted for between 69% and 86% of measured RNCs in the exhaust gas. Emissions are compared to the available legislative precedents (i.e. emissions limits currently in force in various jurisdictions). Finally, possibilities for control of exhaust emissions of currently unregulated RNCs are briefly discussed.
Czasopismo
Rocznik
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3--9
Opis fizyczny
Bibliogr. 19 poz., il. kolor., wykr.
Twórcy
  • Exhaust Emission Laboratory, BOSMAL Automotive Research and Development Institute Ltd in Bielsko-Biała, Poland
Bibliografia
  • 1. BIELACZYC, P., KLIMKIEWICZ, D., WOODBURN, J. et al. Exhaust emission testing methods - BOSMAL’s legislative and development emission testing laboratories. Combustion Engines. 2019, 178(3), 88-98. https://doi.org/10.19206/CE-2019-316
  • 2. BIELACZYC, P., SZCZOTKA, A., PAJDOWSKI, P. et al. Development of automotive emissions testing equipment and test methods in response to legislative, technical and commercial requirements. Combustion Engines. 2013, 152(1).
  • 3. BIELACZYC, P., SZCZOTKA, A., WOODBURN, J. An overview of emissions of reactive nitrogen compounds from modern light duty vehicles featuring SI engines. Combustion Engines. 2014, 159(4), 48-53.
  • 4. BIELACZYC, P., WOODBURN, J., SZCZOTKA, A. Exhaust emissions of gaseous and solid pollutants measured over the NEDC, FTP-75 and WLTC chassis dynamometer driving cycles. SAE Technical Paper 2016-01-1008. 2016. https://doi.org/10.4271/2016-01-1008
  • 5. BOND, G.C., WEBB, G., HARRISON, B. et al. Catalysis of reactions involving the reduction of decomposition of nitrogen oxides. Catalysis. 1982, 5. https://doi.org/10.1039/9781847553171-00127
  • 6. DEMUYNCK, J. AECC demonstration projects and AECC position on Euro 7. AGVES meeting, 26 November 2020, https://www.aecc.eu/wp-content/uploads/2020/11/201126-AECC-presentation-AGVES-1.pdf
  • 7. ELSER, M., EL-HADDAD, I., MAASIKMETS, M. et al. High contributions of vehicular emissions to ammonia in three European cities derived from mobile measurements. Atmospheric Environment. 2018, 175, 210-220. https://doi.org/10.1016/j.atmosenv.2017.11.030
  • 8. FEV Magazine, Zero-Impact - Combustion Engine, 2020. https://magazine.fev.com/en/zero-impact-combustion-engine/
  • 9. GURALP, O., QI, G., LI, W. et al. Experimental study of NOx reduction by passive ammonia-SCR for stoichiometric SIDI engines. SAE Technical Paper 2011-01-0307. 2011. https://doi.org/10.4271/2011-01-0307
  • 10. HOEKMAN, S. Review of nitrous oxide (N2O) emissions from motor vehicles. SAE International Journal of Fuels and Lubricants. 2020, 13(1):79-98. https://doi.org/10.4271/04-13-01-0005
  • 11. MAROTTA, A., PAVLOVIC, J., CIUFFO, B. et al. Gaseous emissions from light-duty vehicles: moving from NEDC to the new WLTP test procedure. Environmental Science & Technology. 2015, 49(14), 8315-8322, https://doi.org/10.1021/acs.est.5b01364
  • 12. OSBORNE, R., LANE, A., TURNER, N. et al. A new-generation lean gasoline engine for reduced CO2 in an electrified world. Vienna Motor Symposium 2019, 15-17 May 2019. Vienna, Austria.
  • 13. PRADHAN, S. Development of an ammonia reduction after-treatment systems for stoichiometric natural gas engines for stoichiometric natural gas engines. Graduate Theses. Dissertations, and Problem Reports. 2017, 6447, https://researchrepository.wvu.edu/etd/6447
  • 14. STRZELEC, A., KASAB, J. Automotive emissions regulations and exhaust aftertreatment systems. SAE International, USA, 2020.
  • 15. SUAREZ-BERTOA, R., ASTORGA, C. Isocyanic acid and ammonia in vehicle emissions, Transportation Research Part D: Transport and Environment. 2016, 49, 259-270. https://doi.org/10.1016/j.trd.2016.08.039
  • 16. SUAREZ-BERTOA, R., MENDOZA-VILLAFUERTE, P., RICCOBONO, F. et al. On-road measurement of NH3 emissions from gasoline and diesel passenger cars during real world driving conditions. Atmospheric Environment. 2017, 166, 488-497. https://doi.org/10.1016/j.atmosenv.2017.07.056
  • 17. SUAREZ-BERTOA, R., ZARDINI, A., ASTORGA, C. Ammonia exhaust emissions from spark ignition vehicles over the New European Driving Cycle. Atmospheric Environment. 2014, 97, 43-53. https://doi.org/10.1016/j.atmosenv.2014.07.050
  • 18. The ICCT. Beyond NOx: emissions of unregulated pollutants from a modern gasoline car. 2019. https://theicct.org/sites/default/files/publications/NOx_Pollutants_LDV_FV_20190503_0.pdf
  • 19. UNECE Regulation No. 49. https://eur-lex.europa.eu/legal-content/EN/ALL/?uri=CELEX:42013X0624(01)
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-71d076ee-7b6b-4ce4-b5ed-b04298b082e2
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