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Due to growing interest in the application of renewable resources in industry, there is a need for new carbon precursors. Lignin is a natural polymer and the main by-product of the paper industry, but its application on an industrial scale is limited. Due to its chemical composition and high aromatic carbon content, combined with a lack of toxicity, it may be a promising candidate for a carbon precursor, as well as – in carbon electrode technology – a carbon binder. The main disadvantage of lignins is the variety of their types, with differing properties. There is a need to establish the relationship between the structure of lignin and its carbon precursor potential. In this work, an attempt was made to find the dependence between the lignin structure and its properties before (chemical composition, structural studies) and after thermal treatment under an inert atmosphere (carbon residue, bonding properties and degree of carbonization and graphitization), using different techniques (FTIR, Raman spectroscopy, XPS, TG, SEM) on two softwood lignins – alkali lignin and kraft lignin. The results proved that both lignins are good candidates for carbon precursors (high mass residue after heat treatment), but only kraft lignin exhibits the bonding properties which are crucial for application as a carbon binder.
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Tom
Strony
19--34
Opis fizyczny
Bibliogr. 43 poz., rys., tab.
Twórcy
autor
- AGH-University of Science and Technology, Faculty of Materials Science and Ceramics, Kraków, Poland
autor
- AGH-University of Science and Technology, Faculty of Materials Science and Ceramics, Kraków, Poland
autor
- Tokai Cobex Polska sp. z o.o, Racibórz
autor
- AGH-University of Science and Technology, Faculty of Materials Science and Ceramics, Kraków, Poland
autor
- AGH-University of Science and Technology, Faculty of Materials Science and Ceramics, Kraków, Poland
Bibliografia
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- Alber A., Ehlting J. [2012]: Chapter 4 – Cytochrome P450s in lignin biosynthesis [Internet]. Advances in Botanical Research 61: 113-143. DOI: https://doi.org/10.1016/b978-0-12-416023-1.00004-5
- Asmadi M., Kawamoto H., Saka S. [2011a]: Gas- and solid/liquid-phase reactions during pyrolysis of softwood and hardwood lignins. Journal of Analytical and Applied Pyrolysis 92: 417-425. DOI: https://doi.org/10.1016/j.jaap.2011.08.003
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- Cabrera Y., Cabrera A., Jensen A., Felby C. [2017]: Purification of biorefinery lignin with alcohols 3813: 339-351. DOI: https://doi.org/10.1080/02773813.2016.1148168
- Cao Q., Guo L., Dong Y., Xie X., Jin L. [2015]: Autocatalytic modification of coal tar pitch using benzoyl chloride and its effect on the structure of char. Fuel Processing Technology 129: 61-66. DOI: https://doi.org/10.1016/j.fuproc.2014.08.017
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- Davin L.B., Lewis N.G. [2005]: Lignin primary structures and dirigent sites 16: 407-15. DOI: https://doi.org/10.1016/j.copbio.2005.06.011
- Demir M., Kahveci Z., Aksoy B., Palapati N.K.R., Subramanian A., Cullinan H.T., El-Kaderi H.M., Harris C.T., Gupta R.B. [2015]: Graphitic biocarbon from metal-catalyzed hydrothermal carbonization of lignin. Inustrial and Engineering Chemistry Research 54 [43]. DOI: 10.1021/acs.iecr.5b02614
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- Ghaffar S.H., Fan M. [2013]: Structural analysis for lignin characteristics in biomass straw. Biomass and Bioenergy 57: 264-279. DOI: https://doi.org/10.1016/j.biombioe.2013.07.015
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- Gutierrez-Pardo A., Ramirez-Rico J., Cabezas-Rodriguez R., Martinez-Fernandez J. [2015]: Effect of catalytic graphitization on the electrochemical behavior of wood derived carbons for use in supercapacitors. Journal of Power Sources 278: 18-26. DOI: https://doi.org/10.1016/j.jpowsour.2014.12.030
- Hu Z., Du X., Liu J., Chang H. and Jameel H. [2017]: Structural characterization of Pine kraft lignin : BioChoice lignin vs indulin AT. Journal of Wood Chemistry and Technology 36: 432-446. DOI: https://doi.org/10.1080/02773813.2016.1214732
- Huang Z.K., Lu Q.F., Lin Q., Cheng X. [2012]: Microstructure, properties and lignin-based modification of wood-ceramics from rice husk and coal tar pitch. Journal of Inorganic and Organometallic Polymers and Materials 22: 1113-1121. DOI: https://doi.org/10.1007/s10904-012-9708-6
- Huang Y., Wang L., Chao Y., Nawawi D.S., Yokoyama T. and Matsumoto Y. [2017a]: Analysis of lignin aromatic structure in wood based on the IR spectrum analysis of lignin aromatic structure in wood. Journal of Wood Chemistry and Technology 32: 294-303. DOI: https://doi.org/10.1080/02773813.2012.666316
- Huang Y., Wang Z., Wang L., Chao Y., Akiyama T., Yokoyama T. et al. [2017b]: Analysis of lignin aromatic structure in wood fractions based on IR spectroscopy. Journal of Wood Chemistry and Technology 36 [5]: 1-6. DOI: https://doi.org/10.1080/02773813.2016.1179325
- Jasiukaitytė-Grojzdek E., Kunaver M., Crestini C. [2017]: Lignin structural changes during liquefaction in acidified ethylene glycol. Journal of Wood Chemistry and Technology 3813: 342-360. DOI: https://doi.org/10.1080/02773813.2012.698690
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- Lumadue M.R., Cannon F.S., Brown N.R. [2012]: Lignin as both fuel and fusing binder in briquetted anthracite fines for foundry coke substitute. Fuel 97: 869-875. DOI:https://doi.org/10.1016/j.fuel.2012.02.061
- Mainka H., Hilfert L., Busse S., Edelmann F., Haak E., Herrmann A.S. [2015]: Characterization of the major reactions during conversion of lignin to carbon fiber.Integrative Medicine Research, Korea Institute of Oriental Medicine 4: 377-391. DOI: https://doi.org/10.1016/j.jmrt.2015.04.005
- Martinez C., Sedano M., Mendoza J., Herrera R., Rutiaga J.G., Lopez P. [2009]: Effect of aqueous environment in chemical reactivity of monolignols. A New Fukui Function Study. Journal of Molecular Graphics and Modelling, 28: 196-201. DOI: https://doi.org/10.1016/j.jmgm.2009.07.002
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- Stark N.M., Yelle D.J., Agarwal U.P. [2016]: 4 – Techniques for characterizing lignin [Internet]. Lignin in Polymer Composites: 49-66 DOI: https://doi.org/10.1016/B978-0-323-35565-0.00004-7
- Verma S.R., Dwivedi U.N. [2014]: Lignin genetic engineering for improvement of wood quality: Applications in paper and textile industries, fodder and bioenergy production. South African Journal of Botany, South African Association of Botanists 91: 107-125. DOI: https://doi.org/10.1016/j.sajb.2014.01.002
- Yan Q., Li J., Zhang X., Hassan E.B., Wang C., Zhang J., Cai Z. [2018]: Catalytic graphitization of kraft lignin to graphene-based structures with four different transitional metals. Journal of Nanoparticle Research 20: 233. DOI: https://doi.org/10.1007/s11051-018-4317-0
- You T.T., Zhang L.M., Zhou S.K., Xu F. [2015]: Structural elucidation of lignin-carbohydrate complex (LCC) preparations and lignin from Arundo donax Linn. Industrial Crops and Products 71: 65-74. DOI: https://doi.org/10.1016/j.indcrop.2015.03. 070
- Zambrzycki M., Frączek-Szczypta A. [2020]: Study on the synthesis and properties of hierarchically structured electrospun/vapour-grown carbon nanofibres nanocomposites. Journal ofIndustrial and Engineering Chemistry 86: 100-112. DOI: https://doi.org/10.1016/j.jiec.2020.02.017
- Zhang Q., Chen Q., Chen J., Wang K., Yuan S., Sun R. [2015]: Morphological variation of lignin biomacromolecules during acid-pretreatment and biorefinery-based fractionation. Industrial Crops and Products 77: 527-534. DOI: https://doi.org/10.1016/j.indcrop.2015.09.021
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Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-71cf9d5d-a709-43d8-95fd-bb5f186dde69