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The paper investigates the efficiency of adsorption of organic pollutants present in natural water on powdered activated carbon (PAC). A PAC adsorption capacity is related to the mass exchange driving force between water and sorbent. During the study, it was confirmed that the mass transfer driving force in the homogeneous flocculator with simultaneous PAC adsorption was lower than in the filter column. The filter showed a better utilization of PAC adsorption capacity than the volume system, for the optimal PAC dose. The authors proposed a new method where adsorption was carried out in the filter column with PAC applied to its upper layer. The powdered sorbent was applied to the bed at the end of a backwashing cycle. Two models of PAC adsorption in transient states for the homogeneous flocculator and the column mass exchanger were presented. The simulation calculations confirmed that there was still a possibility to double the PAC adsorption capacity concerning commonly used adsorption with coagulation in the homogeneous flocculator.
Czasopismo
Rocznik
Tom
Strony
83--97
Opis fizyczny
Bibliogr. 14 poz., rys., tab.
Twórcy
autor
- Cracow University of Technology, Faculty of Environmental and Power Engineering, Department of Water Supply, Sewerage and Environmental Monitoring, Warszawska 24, 31-155 Cracow, Poland
Bibliografia
- [1] ADAMSKI W., SZLACHTA M., Water treatment technology. Principles and Modeling, Wrocław University of Technology, Wrocław 2011.
- [2] INA K., JOLL C., HEITZ A., Powdered activated carbon coupled with enhanced coagulation for natural organic matter removal and disinfection by-product control. Application in a Western Australian water treatment plant, Chemosphere, 2011, 83, 661–667. DOI: 10.1016/j.chemosphere.2011.02.017.
- [3] NAJM I.N., SNOEYINK V.L., LYKINS B.W., ADAMS J.Q., Using powdered activated carbon. A critical review, J. Am. Water Works Assoc., 1991, 83 (1), 65–76. DOI: 10.1002/j.1551-8833.1991.tb07087.x.
- [4] SANDRUCCI P., MERLO G., GENON G., MEUCCI L., PAC activity vs. by-product precursors in water disinfection, Water Res., 1995, 29 (10), 2299–2308. DOI: 10.1016/0043-1354(95)00044-L.
- [5] NEWCOMBE G., MORRISON J., HEPPLEWHITE C., Simultaneous adsorption of MIB and NOM onto activated carbon. I. Characterization of the system end NOM adsorption, Carbon, 2002, 40 (12), 2135–2146. DOI: 10.1016/S0008-6223(02)00097-0.
- [6] NEWCOMBE G., MORRISON J., HEPPLEWHITE C., KNAPPE D.R.U., Simultaneous adsorption of MIB and NOM onto activated carbon. II. Competitive effects, Carbon, 2002, 40 (12), 2147–2156. DOI: 10.1016/S0008-6223(02)00098-2.
- [7] FABRIS R., CHOW C.W.K., DRIKAS M., Practical application of a combined treatment process forremoval of recalcitrant NOM – alum and PAC, Water Sci. Tech.-W. Sup., 2004, 4 (4), 89–94. DOI:10.2166/ws.2004.0065.
- [8] UYAK V., YAVUZ S., TOROZ I., OZAYDIN S., GENCELI E.A., Disinfection by-products precursors removal by enhanced coagulation and PAC adsorption, Desalin., 2007, 216, 334–344. DOI: 10.1016/j.desal.2006.11.026.
- [9] CARRIERE A., VACHON M., BELISLE J.-L., BARBEAU B., Supplementing coagulation with powdered activated carbon as a control strategy for trihalomethanes: application to an existing utility, J. Water Supply Res. T., 2009, 58 (5), 363–371. DOI: 10.2166/aqua.2009.197.
- [10] COULSON J.M., RICHARDSON J.F., Coulson and Richardson’s Chemical Engineering. Vol. 1, Fluid Flow, Heat Transfer and Mass Transfer, Elsevier, 1999.
- [11] BIELSKI A., Modelling of mass transport in watercourses considering mass transfer between phases in unsteady states. Part II. Mass transport during absorption and adsorption processes, Environ. Prot. Eng., 2011, 4 (37), 71–89.
- [12] BIELSKI A., Modelling of mass transport in watercourses at unsteady states, Environ. Prot. Eng., 2012, 3 (38), 159–173. DOI: 10.5277/EPE120314.
- [13] BIELSKI A., ZYMON W., Filter beds supplemented with powdered activated carbon, Environ. Prot. Eng., 2017, 2 (43), 173–191. DOI: 10.5277/epe170214.
- [14] BIELSKI A., ZYMON W., ŻABA T., Adsorption efficiency of powdered activated carbon applied to a filter bed, Pol. J. Environ. Stud., 2017, 26 (3), 985–993. DOI: 10.15244/pjoes/67652.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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