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Identyfikacja źródeł zanieczyszczeń atmosfery na obszarach zurbanizowanych
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Abstrakty
Identification of PM10 particles in the city of Olomouc (the Czech Republic) was aimed at determining the proportion of inorganic and organic compounds. Organic compounds in PM10 represent 30–36% of PM10, of which 21–25% is biogenic material (spores were identified). The rest of 10 to 15% of organic matter is represented by anthropogenic processes. Combustion processes (35.1 to 40.9% of PM10) and emissions from transport (20.0 to 22.9% of PM10) have the main share in the PM particles, minerals from resuspension – weathering processes and mechanical processes of construction activity account for around 9% of the particles and Fe – particles also constitute about 9%. The iron concentration in the aerosol is in accordance with the values measured in other European cities. Mineral phases in the inorganic aerosol were determined by X-ray diffraction. Both natural and anthropogenic crystalline phases were identified – quartz, clay minerals (kaolinite), feldspar, calcite, dolomite, iron oxides (magnetite), gypsum, boussingaultite, mascagnite and koktaite.
Celem pracy była identyfikacja ziaren PM10 w atmosferze w mieście Ołomuniec (Czechy) w celu określenia proporcji składników organicznych i nieorganicznych. Składniki organiczne w PM10 stanowią 30–36%, z czego 21–25% jest materiałem biogenicznym (zidentyfikowano zarodniki). Pozostałe 10 do 15% materii organicznej powstała w wyniku procesów antropogenicznych. Procesy spalania (przyczyna powstania 35,1 do 49,9% ogółu PM10) oraz emisja z transportu (20,0 do 22,9% ogółu PM10) mają główny udział w ziarnach PM, minerały wtórne pochodzące z procesów mechanicznych związanych z budownictwem to około 9% ziaren a ziarna stanowią również kolejne 9%. Stężenie żelaza w aerozolu jest podobne do wartości zmierzonych w innych miastach Europy. Fazy mineralne w aerozolu nieorganicznym zostały zmierzone za pomocą dyfrakcji rentgenowskiej. Zarówno naturalne, jaki antropogeniczne fazy krystaliczne zostały zidentyfikowane, stwierdzono występowanie kwarcu, minerałów glinu (kaolinit), skalenie, kalcyt, dolomit, tlenki żelaza (magnetyt), gips, boussingaultyt, maskagnit oraz koktait.
Czasopismo
Rocznik
Tom
Strony
147--152
Opis fizyczny
Bibliogr. 18 poz., rys., tab., zdj.
Twórcy
autor
- VŠB – Technical University of Ostrava, Centre ENET, 17. listopadu Str. 15, 708 33 Ostrava – Poruba, Czech Republic
- VŠB – Technical University of Ostrava, Faculty of Mining and Geology, 17. listopadu Str. 15, 708 33 Ostrava – Poruba, Czech Republic
autor
- VŠB – Technical University of Ostrava, Centre ENET, 17. listopadu Str. 15, 708 33 Ostrava – Poruba, Czech Republic
- VŠB – Technical University of Ostrava, Faculty of Mining and Geology, 17. listopadu Str. 15, 708 33 Ostrava – Poruba, Czech Republic
autor
- VŠB – Technical University of Ostrava, Faculty of Mining and Geology, 17. listopadu Str. 15, 708 33 Ostrava – Poruba, Czech Republic
autor
- VŠB – Technical University of Ostrava, Centre ENET, 17. listopadu Str. 15, 708 33 Ostrava – Poruba, Czech Republic
- VŠB – Technical University of Ostrava, Faculty of Mechanical Engineering, 17. listopadu Str. 15, 708 33 Ostrava – Poruba, Czech Republic
autor
- VŠB – Technical University of Ostrava, Centre ENET, 17. listopadu Str. 15, 708 33 Ostrava – Poruba, Czech Republic
autor
- VŠB – Technical University of Ostrava, Centre ENET, 17. listopadu Str. 15, 708 33 Ostrava – Poruba, Czech Republic
Bibliografia
- 1. CHOËL, Marie et al. Single-particle analysis of atmospheric aerosols at Cape Gris-Nez, English Channel: Influence of steel works on iron apportionment. Atmospheric Environment, 41, 2007, p. 2820-2830.
- 2. DUARTE, Regina M. B. O et al. Carbonaceous materials in size-segregated atmospheric aerosols from urban and coastal-rural areas at the Western European Coast. Atmospheric Research, 90 (2-4), 2008, p. 253-263.
- 3. GIANINI, Matthias F.D. et al. Chemical composition of PM10 in Switzerland: An analysis for 2008/2009 and changes since 1998/1999. Atmospheric Environment, 54, 2012, p. 97-106.
- 4. LOZANO, Noemí Pérez. Variability of atmospheric particulate matter at an urban and a regional background in NE Iberian Peninsula. Barcelona, 2007, p. 107.
- 5. MORENO, Teresa et al. Daily and hourly sourcing of metallic and mineral dust in urban air contaminated by traffic and coal-burning emissions. Atmospheric Environment, 68, 2013, p. 33-44.
- 6. MORI, Ikuko et al. Possible particle-particle reaction between soil and ammonium sulfate aerosols. Journal of Aerosol Science, 29, 1998, p. 417-418.
- 7. MURANSZKY, Gábor et al. Chemical characterization of PM10 fractions of urban aerosol. Microchemical Journal, 98, 2011, p. 1-10.
- 8. PACHAURI, Tripti. Chemical characterization and source identification of PM2.5 and PM10 at a rural, sub-urban and traffic dominated site in Agra. Agra, 2012.
- 9. PUTAUD, Jean-P et al. A European aerosol phenomenology-2: chemical characteristics of particulate matter at kerbside, urban, rural and background sites in Europe. Atmospheric Environment, 38(16), 2004, p. 2579-2595.
- 10. QUEROL, Xavier et al. Speciation and origin of PM10 and PM2.5 in selected European cities. Atmospheric Environment, 38, 2004, p. 6547-6555.
- 11. ROGULA-KOZLOWSKA, Wioletta et al. Size resolved water-soluble ionic composition of ambient particles in an urban area in southern Poland. Journal of Environmental Protection, 4, 2013, p. 371-379.
- 12. SILLANPÄÄ, Mika et al. Organic, elemental and inorganic carbon in particulate matter of six urban environments in Europe. Atmospheric Chemistry and Physics, 5, 2005, p. 2869-2879.
- 13. SONG, Xiaoyan et al. Mineralogical and geochemical composition of particulate matter (PM10) in coal and non-coal industrial cities of Henan Province, North China. Atmospheric Research, 143, 2014, p. 462-472.
- 14. U.S. ENVIRONMENTAL PROTECTION AGENCY. Air Quality Criteria for Particulate Matter. 2001.
- 15. U.S. ENVIRONMENTAL PROTECTION AGENCY. Report to Congress on Black Carbon, 2012, p. 388.
- 16. WANG, Wan. Inorganic and Organic Speciation of Atmospheric Aerosols by ion Chromatography and Aerosol Chemical Mass Closure. Gent: Ghent University, 2010. ISBN 978-90-5989-384-9.
- 17. YAO, Xiao et al. The size dependence of chloride depletion in fine and coarse sea-salt particles. Atmospheric Environment, 37(6), 2003, p. 743-75.
- 18. YTTRI, Karl Espen et al. Elemental and organic carbon in PM10: a one year measurement campaign within the European Monitoring and Evaluation Programme EMEP. Atmospheric Chemistry and Physics, 7, 2007, p. 5711-5725.
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-714cdfef-6aeb-4802-905c-1ac5d8a0c0b8