Stosowalność kwasu borowego do wytwarzania nanokompozytów TiB2/TiC/ZrO2 r.s. metodą in situ

• Autorzy: Moskała N. , Pyda W.

Warianty tytułu

EN

The applicability of boric acid for the production of TiB2/TiC/ZrO2s.s. nanocomposites using the in situ method

• Języki publikacji: PL EN

Abstrakty

PL

Ocenie poddano przydatność użycia kwasu ortoborowego do wytwarzanie metodą in situ nanometrycznych wtrąceń TiB2 i TiC w tetragonalnej osnowie tlenku cyrkonu. Kwas ortoborowy, żywicę fenolowo-formaldehydowę i nanoproszek cyrkoniowy stabilizowany 2,5% mol. Y2O3 i domieszkowany 18% mol. TiO2 zastosowano do syntezy wtrąceń TiB2 i TiC w cząstkach tlenku cyrkonu, którą prowadzono w zakresie 1100-1600 °C w próżni. Tak otrzymane proszki kompozytowe zawierały nanocząstki TiB2 i TiC o rozmiarach odpowiednio 60-80 nm i 25-40 nm. Proszki kompozytowe spiekano w temperaturze 1500 °C w próżni, aby uzyskać gęste materiały kompozytowe. Szczegółowej charakterystyce poddano skład fazowy proszków i kompozytów, zmierzono rozmiar cząstek TiB2 i TiC w proszkach, określono stan zagęszczenia spieków, zbadano mikrostrukturę i wybrane właściwości kompozytów. Właściwości mechaniczne kompozytów porównano z materiałem 3Y-TZP. Zbadano wpływ temperatury syntezy in situ na skład fazowy proszków i spieków oraz na właściwości mechaniczne kompozytów, wskazując rolę jaką pełni kwas ortoborowy w kształtowaniu się tych właściwości. Otrzymano gęste kompozyty z przewagą fazy tetragonalnej w osnowie cyrkoniowej, zawierające submikronowe i w części nanometryczne wtrącenia TiB2 i TiC, które charakteryzowały się podwyższoną odpornością na zużycie ścierne.

EN

The applicability of the use of orthoboric acid to production of nanometric inclusions of TiB2 and TiC in the tetragonal zirconium oxide matrix by the in situ method was evaluated. Orthoboric acid, phenol-formaldehyde resin and zirconia nanopowder stabilized with 2.5 mol% Y2O3 and doped with 18 mol% TiO2 were used for the synthesis of TiB2 and TiC inclusions in zirconia particles, which was carried out at 1100-1600 C in vacuum. The composite powders thus obtained contained TiB2 and TiC nanoparticles with sizes of 60-80 nm and 25-40 nm, respectively. Composite powders were sintered at 1500 C under vacuum to obtain dense composite materials. The phase composition of powders and composites was characterized in detail, the particle size of TiB2 and TiC in powders was measured, the state of compacting of sinters was determined, the microstructure and selected properties of composites were examined. The mechanical properties of the composites were compared with the 3Y-TZP material. The influence of the in situ synthesis temperature on the phase composition of powders and sinters as well as the mechanical properties of composites was examined, indicating the role of orthoboric acid in the formation of these properties. Dense composites with predominance of the tetragonal phase in the zirconium matrix were obtained, containing submicron and in part nanometric inclusions of TiB2 and TiC, which were characterized by increased resistance to abrasion.

Słowa kluczowe

PL

kompozyt z osnową ZrO2; TiB2; TiC; kwas ortoborowy; odporność na zużycie ścierne

EN

zirconia matrix composite; TiB2; TiC; ZrO2; orthoboric acid; abrasive wear resistance

• Wydawca: Polskie Towarzystwo Ceramiczne
• Czasopismo: Materiały Ceramiczne
• Rocznik: 2018
• Tom: T. 70, nr 4
• Strony: 371--389
• Opis fizyczny: Bibliogr. 40 poz., rys.

Twórcy

autor

Moskała N.

• AGH University of Science and Technology, Faculty of Materials Science and Ceramics, al. A. Mickiewicza 30, 30-059 Kraków

autor

Pyda W.

• AGH University of Science and Technology, Faculty of Materials Science and Ceramics, al. A. Mickiewicza 30, 30-059 Kraków

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