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Application of the Energetic Complex [Cu(TNBI)(NH3)2(H2O)] in Heterogeneous Solid Rocket Propellants

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This paper presents results from the application of [Cu(TNBI)(NH3)2(H2O)] (CuTNO) to heterogeneous solid rocket propellants based on HTPB/AP, replacing RDX. A series of different compositions of solid heterogeneous rocket propellants based on HTPB and ammonium perchlorate, containing CuTNO or RDX, were prepared and investigated. The ballistic parameters of the examined propellants were determined by combustion in a laboratory rocket motor (LRM). The ballistic properties were evaluated in the pressure range 4-10 MPa and it was found that the linear burning rate at 10 MPa increased by more than 20% for the CuTNO containing propellant, compared to the RDX-based composition. By linear regression of the r = f(p) curves obtained, the burning laws for the investigated propellants were determined. It was found that the CuTNO additive increases the pressure coefficient by over 46%, compared to unmodified propellant. The determination of the sensitivities to friction and impact, the calorific value, hardness and decomposition temperature of the propellants obtained were also investigated.
Słowa kluczowe
Rocznik
Strony
391--402
Opis fizyczny
Bibliogr. 24 poz., rys., tab.
Twórcy
autor
  • Institute of Industrial Organic Chemistry, Annopol 6, 03-236 Warsaw, Poland
autor
  • Military University of Technology, Urbanowicza 2, 00-908 Warsaw, Poland
  • Institute of Industrial Organic Chemistry, Annopol 6, 03-236 Warsaw, Poland
autor
  • Institute of Industrial Organic Chemistry, Annopol 6, 03-236 Warsaw, Poland
Bibliografia
  • [1] Kubota, N. Propellants and Explosives: Thermochemical Aspects of Combustion. Wiley, Weinheim 2007; ISBN 9783527314249.
  • [2] Sutton, G. P.; Biblarz, O. Rocket Propulsion Elements. Wiley, New York 2001; ISBN 978-0471326427.
  • [3] Florczak, B. A Comparison of Properties of Aluminized Composite Propellants Containing HMX and FOX-7. Cent. Eur. J. Energ. Mater. 2008, 5(3-4): 103-111.
  • [4] Abd-Elghany, M.; Elbeih, A.; Hassanein, S. Thermal Behavior and Decomposition Kinetics of RDX and RDX/HTPB Composition Using Various Techniques and Methods. Cent. Eur. J. Energ. Mater. 2016, 13(3): 714-735.
  • [5] Bogusz, R.; Florczak, B. Research Heterogeneous Solid Rocket Propellants Based on HTPB Rubber. (in Polish) Przem. Chem. 2016, 95(12): 2448-2451.
  • [6] Ghosh, K.; Behera, S.; Kumar, A.; Padale, B. G.; Deshpande, D. G.; Kumar, A.; Gupta, M. Studies on Aluminized, High Burning Rate, Butacene® Based, Composite Propellants. Cent. Eur. J. Energ. Mater. 2014, 11(3): 323-333.
  • [7] Gore, G. M.; Tipare, K. R.; Bhatewara, R. G.; Prasad, U. S.; Gupta, M.; Mane, S. R. Evaluation of Ferrocene Derivatives as Burn Rate Modifiers in AP/HTPB-based Composite Propellants. Def. Sci. J. 1999, 49(2): 151-185.
  • [8] Styborski, J. A.; Scorza, M. J.; Smith, M. N.; Oehlschlaege, M. A. Iron Nanoparticle Additives as Burning Rate Enhancers in AP/HTPB Composite Propellants. Propellants Explos. Pyrotech. 2015, 40: 253-299.
  • [9] Bogusz, R.; Magnuszewska, P.; Florczak, B.; Maranda, A.; Drożdżewska, K. Studies of the Influence of Nano Iron(III) Oxide on Selected Properties of Solid Heterogeneous Propellants Based on HTPB. Cent. Eur. J. Energ. Mater. 2016, 13(4): 1051-1063.
  • [10] Davenas, A. Solid Rocket Propulsion Technology. Pergamon Press, Oxford 1993.
  • [11] Florczak, B.; Bogusz, R.; Skupiński, W.; Chmielarek, M. Study of the Effect of Nitrated Hydroxyl-terminated Polybutadiene (NHTPB) on the Properties of Heterogeneous Rocket Propellants. Cent. Eur. J. Energ. Mater. 2015, 12(4):841-854.
  • [12] Maksimowski, P.; Kasztankiewicz, A. B.; Kopacz, W. 3,3-Bis(azidomethyl) oxetane (BAMO) Synthesis via Pentaerythritol Tosyl Derivates. Propellants Explos. Pyrotech. 2017, 42: 1020-1026.
  • [13] Szala, M.; Lewczuk, R. New Synthetic Methods for 4,4’,5,5’-Tetranitro-2,2’-bi-1H-imidazole (TNBI). Cent. Eur. J. Energ. Mater. 2015, 12(2): 261-270.
  • [14] Lewczuk, R.; Szala, M.; Rećko, J.; Cudziło, S.; Klapötke, T. M.; Trzciński, W. A.; Szymańczyk, L. Explosive Properties of 4,4’,5,5’-Tetranitro-2,2’-bi-1H-imidazole Dihydrate. Cent. Eur. J. Energ. Mater. 2016, 13(3): 612-626.
  • [15] Lewczuk, R.; Szala, M.; Rećko, J.; Klapötke, T. M.; Cudziło, S. Synthesis and Properties of 4,4’,5,5’-Tetranitro-1H,1’H-2,2’-biimidazole Salts: Semicarbazidium, 3-Amino-1,2,4-triazolium, and 5-Aminotetrazolium Derivatives. Chem. Heterocycl. Compd. 2017, 53(6/7): 697-701.
  • [16] Talawar, M. B.; Agrawal, A. P.; Asthana, S. N. Energetic Co-ordination Compounds: Synthesis, Characterization and Thermolysis Studies on Bis-(5-nitro-2Htetrazolato-N2)tetraammine Cobalt(III) Perchlorate (BNCP) and its New Transition Metal (Ni/Cu/Zn) Perchlorate Analogues. J. Hazard. Mater. 2005, 120: 35-35.
  • [17] Cudziło, S.; Trzciński, W. A.; Nita, M.; Michalik, S.; Krompiec, S.; Kruszyński, R.; Kusz, J. Preparation, Crystal Structure and Explosive Properties of Copper(II) Perchlorate Complex with 4-Amino-1,2,4-Triazole and Water. Propellants Explos. Pyrotech. 2011, 36: 151-159.
  • [18] Tao, G-H.; Twamley, B.; Shreeve, J. M. Energetic Nitrogen-rich Cu(II) and Cd(II) 5,5′-Azobis(tetrazolate) Complexes. Inorg. Chem. 2009, 48: 9918-9923.
  • [19] Cudziło, S.; Trzciński, W. A.; Paszula, J.; Nita, M. Detonation and Decomposition Characteristics of Dichlorate(VII) μ-Tris(4-amino-1,2,4-triazole) Copper(II). Cent. Eur. J. Energ. Mater. 2014, 11: 539-552.
  • [20] Lewczuk, R.; Rećko, J.; Szala, M. Synthesis and Properties of a New High Energy Complex Compound [Cu(TNBI)(NH3)2(H2O)]. (in Polish) Chemik 2015, 69: 123-128.
  • [21] Florczak, B.; Sałaciński, T.; Maranda, A.; Sitkiewicz-Wołodko, R. Susceptibility Testing of Double-base Solid Propellants. (in Polish) Przem. Chem. 2013, 92(8):1464-1471.
  • [22] Suceska, M. Test Method for Explosives, Springer-Verlag, New York 1995; ISBN 978-0-387-94555-2.
  • [23] Minning Materials. Determination of Decomposition Temperature. (in Polish) Industry Standard BN-76/6091-08, 1976.
  • [24] Gupta, G.; Jawale, L.; Mehilal; Bhattacharya, B. Various Methods for the Determination of the Burning Rates of Solid Propellants − an Overview. Cent. Eur. J. Energ. Mater. 2015, 12(3): 593-620.
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-70fcfe21-44c6-432b-84e9-884060da5c87
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