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Purification of halloysite by magnetic separation

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Rational use of mineral resources requires advanced separation methods in order to obtain high quality products. In this study chemical treatment with magnetic separation of halloysite from Dunino (Poland) is presented. Initial crushing, hydrochloric acid absorption treatment, sedimentation (settling) and polygradient magnetic separation in weak magnetic field were applied to separate aluminosilicates from iron and titanium oxides (impurities). The process allowed to obtain a product of approximately 98% purity of the aluminosilicate fraction (halloysite + kaolinite). The tailings from magnetic separation consisted of iron oxides, while the intermediate product consisted mainly of aluminosilicate and iron chlorides resulting from the HCl treatment. The obtained products can be used as a component of polymer nanocomposites, sorbents and in ceramics industry.
Słowa kluczowe
Rocznik
Strony
991--1001
Opis fizyczny
Bibliogr. 24 poz., rys., tab.
Twórcy
autor
  • Division of Nanocrystalline and Functional Materials and Sustainable Proecological Technologies Institute of Engineering Materials and Biomaterials, Silesian University of Technology, Konarskiego 18a, 44-100 Gliwice, Poland
autor
  • Institute of Mining, Faculty of Mining and Geology, Silesian University of Technology, Akademicka 2, 44-100 Gliwice
autor
  • PTH INTERMARK, Swietego Marka 9, 44-100 Gliwice
autor
  • CEWAP Sp. z o.o. , Kosciuszki 8, 59-700 Boleslawiec
Bibliografia
  • AMBIKADEVI V.R., LALITHAMBIKA M., 2000, Effect of organic acids on ferric iron removal from iron-stained kaolinite, Applied Clay Science, 16, 133-14.
  • BELKASSA K., BESSAHA F., MAROUF K., BATONNEAU I., COMPAROT J., KHELIFA A., 2013, Physicochemical and adsorptive properties of a heat-treated and acid-leached Algerian halloysite, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 421, 26-33.
  • BROZEK M, ANTONI C., PILCH W., 1991, Wstępne badania nad zastosowaniem separatora z magnesem nadprzewodzącym do wzbogacania Kaolinu, Fizykochemiczne Problemy Mineralogii 24, 203-209.
  • CIESLA A., 2012, Magnetic separation of kaolin clay using free helium superconducting magnet, Przegląd Elektrotechniczny, ISSN 0033-2097.
  • CIESLA A., 2003, Practical aspects of high gradient magnetic separation using superconducting magnets, Physicochemical Problems of Mineral Processing,169-18.
  • DRZYMALA J., 2007, Mineral Processing. Foundations of theory and practice of minerallurgy. Ofic Wyd PWr., Wroclaw.
  • HEDICKE-HOCHSTOTTER K., LIM G.T., ALTSTADT V., 2009, Novel polyamide nanocomposites based on silicate nanotubes of the mineral halloysite. Composites Science and Technology, 69, 330–334.
  • IANNICELLI J., PECHIN J., UEYAMA M., OHKURA K., HAYASHI K., SATO K., LAUDER A., REY C., 1997, Magnetic separation of kaolin clay using a high temperature superconducting magnet system, IEEE Transactions on Applied Superconductivity, Vol. 7, Issue: 2, 1061 – 1064.
  • JOUSSEIN E., PETIT S., FIALIPS C., VIEILLARD P., RIGHI D., 2006, Differences in the dehydration - rehydration behavior of halloysites: new evidence and interpretations, Clays and Clay Minerals, 54 (4), 473-484.
  • LEWICKA E., 2012, Innovative production technologies of kaolin raw materials, Przegląd Górniczy, T. 68, nr 3, 164 - 170.
  • MATUSIK J., 2014, Arsenate, orthophosphate, sulfate, and nitrate sorption equilibria and kinetics for halloysite and kaolinites with an induced positive chargé, Chemical Engineering Journal, 246, 244–253.
  • MAKARY B., PILCH W., SIWIEĆ A., TAJCHMAN Z, 1990, Badania nad opracowaniem technologii wzbogacania zwietrzeliny bazaltowej, Fizykochemiczne Problemy Mineralurgii, 22, 127-133.
  • MEIRELES M., BOURGEOIS F.,TOURBIN M., GUIRAUD P., FRANCES C., 2010, Removal of oversize & recovery of particles from suspensions in the nano size range, Research Report CNRS.
  • MOESER G.D., ROACH K.A., GREN W.H., HATTON T.A., 2004, High-gradient magnetic separation of coated magnetic nanoparticles, AIChE Journal , Volume 50, Issue 11, 2835–2848.
  • PYTLINSKI. A. MYJKOWSKI, 2003, Alkaliczno dyspersyjna metoda uszlachetniania kaolinów, Ceramika /Ceramics, vol. 76, Kraków.
  • KAMBLE R., GHAG M., GAIKAWAD S., KUMAR PANDA B., 2012, Halloysite Nanotubes and Applications: A Review, Journal of Advanced Scientific Research, 25-29.
  • SAKIEWICZ P., NOWOSIELSKI R., PILARCZYK W., GOŁOMBEK K., LUTYŃSKI M, 2011, Selected properties of the halloysite as a component of Geosynthetic Clay Liners (GCL). Journal of Achievements in Materials and Manufacturing Engineering, 48(2), 177–191.
  • SAKLAR S., YORUKOGLU A., 2015, Effects of acid leaching on halloysite, Physicochem. Probl. Miner. Process. 51(1), 83−94.
  • STECHMAN M., 2001, Bezodpadowa metoda otrzymywania sorbentów mineralnych z haloizytu, Chemik, 333-336.
  • SVOBODA J. FUJITA T., 2003, Recent developments in magnetic methods of material separation, Minerals Engineering, 16, 785-792
  • YUAN P., SOUTHON P.D., LIU Z., KEPERT C.J., 2012, Organosilane functionalization of halloysite nanotubes for enhanced loading and controlled release, Nanotechnology 23, 375705.
  • ZHANG A., PAN L., ZHANG H., LIU S., YE Y., XIA M., CHEN X., 2012, Effects of acid treatment on the physico-chemical and pore characteristics of halloysite, Colloids and Surfaces A: Physico-chemical and Engineering Aspects, 396, 182–188.
  • ZHANG Y., FU L., YANG H., 2012, Insights into the physicochemical aspects from natural halloysite to silica nanotubes. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 414, 115–119.
  • ZHANG Y., YANG H., 2012, Halloysite nanotubes coated with magnetic nanoparticles. Applied Clay Science, 56, 97–102.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-70c854e8-a041-46bd-963b-53d438f1c5c2
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