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Tytuł artykułu

The influence of cyanide salts and ferrous sulphate on pyrite flotation

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The effect of cyanide salts as depressants, i.e. sodium cyanide (NaCN) and complex cyanide salts such as potassium ferricyanide (K3Fe(CN)6) and potassium ferrocyanide (K4Fe(CN)6), as well as combination of sodium cyanide with ferrous sulphate (FeSO4/NaCN) on pyrite flotation was investigated. Tests covered the frothless flotation of pyrite under different concentrations of depressants at various solution pH’s with potassium butyl xanthate (KBX) as collector. Flotation test results have shown that NaCN, and even more the combination of reagents FeSO4/NaCN are more successful in pyrite depression than complex cyanide salts, such as K3Fe(CN)6 and K4Fe(CN)6. Surface characteristics of pyrite were studied using rest potential (Eh) measurements and infrared attenuated total reflection spectroscopy (ATR-IR). In the presence of tested reagents in the flotation system, iron cyanide compounds and hydrated iron oxides were formed on pyrite surface. The composition of formed compounds depends not only on cyanide ions in the solution, but also on the pH of the system and solution species. These compounds, depending on the reagents used, are responsible for the resulting efficiency of the pyrite depression.
Słowa kluczowe
Rocznik
Strony
609--619
Opis fizyczny
Bibliogr. 26 poz., rys., tab.
Twórcy
autor
  • University of Belgrade, Faculty of Mining and Geology, Mineral Processing Department, Djusina 7, 11000 Belgrade, Serbia
autor
  • University of Belgrade, Faculty of Mining and Geology, Mineral Processing Department, Djusina 7, 11000 Belgrade, Serbia
Bibliografia
  • ADAMS M. D., 1992, The removal of cyanide from aqueous solution by use of ferrous sulphate, J. S. Afr. Inst. Min. Metall., 92, 17-25.
  • BICAK O., EKMEKCI Z., BRADSHAW D. J., HARRIS P.J., 2007, Adsorption of guar gum and cmc on pyrite, Miner. Eng., 20, 996-1002.
  • BULUT G., CEYLAN A., SOYLU B., GOKTEPE F., 2011, role of starch and metabisulphite on pure pyrite and pyritic copper ore flotation, Physicochem. Probl. Miner. Process., 48, 39-48.
  • CALDEIRA C.L., CIMINELLI V.S.T., DIAS A., OSSEO-ASARE K., 2003, Pyrite oxidation in alkaline solutions: nature of the product layer, Int. J. Min. Process., 72, 373-386.
  • COOK M.A., LAST A.W., 1952, Collector-depressant equilibria in flotation, J. Phys. Chem., 54, 445-448.
  • DONATO P.D, KONGOLO M., BARRES O., YVON J., ENDERLE F., BOUQUET E., 1999, Chemical surface modifications of sulphide minerals after comminution, Powd. Techn., 105, 141-148.
  • ELGILLANI D.A., FUERSTENAU M.C., 1968, Mechanisms involved in cyanide depression of pyrite, Trans. SME/AIME, 241, 437-444.
  • GADSEN J.A., 1975. Infrared spectra of minerals and related inorganic compounds, Butterworths, London.
  • GAUDIN A.M., 1957, Flotation, Mc Grow Hill Book Co., Inc., New York.
  • GUO B., PENG Y., ESPINOSA-GOMEZ R., 2014, Cyanide chemistry and its effect on mineral flotation, Miner. Eng., 66, 25-32.
  • JANETSKI N.D., WOODBURN S.I., WOODS R., 1977, An electrochemical investigation of pyrite flotation and depression, Int. J. Miner. Process., 4, 227-239.
  • KHMELEVA T.N., SKINNER W., BEATTIE D.A., GEORGIEV T. V., 2002, The effect on the xanthate-induced flotation of copper-activated pyrite, Physicochem. Probl. Miner. Process., 36, 185-195.
  • KOSTOVIC M., 2011, Depression of Pyrite Mineral with Cyanide and Ferrous/Ferric Salts, Undergr. Min. Eng., 19, 149-155.
  • KOSTOVIC M., VUCINIC D., PAVLICA J., 1990, alterations on pyrite in the pyrite - cyanide - xanthate flotation system and depression mechanism, Proceed. 3rd Intern. Min. Process. Sympos., Istanbul, Turkiye, 165-172.
  • LOPEZ VALDIVIESO A., CELEDON CERVANTES T., SONG S., ROBLEDO CABRERA A., LASKOWSKI J. S., 2004, dextrin as a non-toxic depressant for pyrite in flotation with xanthates as collector, Miner. Eng., 17, 1001-1006.
  • MAJUMDAR K.K., 1954, On the mechanism of depression of pyrite, J. Sci. Ind. Research., 13, 586-589.
  • NYQUIST R.A., KAGEL R.O., 1971, Infrared spectra of inorganic compounds, Academic Press, New York and London.
  • PAVLICA J., DRASKIC D., CALIC N., 2011, Application of depressors FeSO4/NaCN on Pb-Zn ores - 20 years later, XIV Balkan Mineral Processing Congress, Tuzla, Bosnia and Herzegovina, 274-278.
  • PRESTIDGE C.A., RALSTON J., SMART R.ST.C., 1993, The competitive adsorption of cyanide and ethyl xanthate on pyrite and pyrrhotite surfaces, Int. J. Miner. Process., 38, 205-233.
  • RATH R.K., SUBRAMANIAN S., PRADEEP T., 2000, Surface chemical studies on pyrite in the presence of polysaccharide-based flotation depressants, J. Colloid Interface Sci., 229, 82-91.
  • RINELLI G., MARABINI A.M., ALESSE V., 1980, Depression action of permanganate on pyrite and galena flotation, Complex Sulphide Ores Conference, Rome, 199-206.
  • TAGGART A.F., 1951, Elements of ore dressing, John Wiley& Sons, Inc., New York.
  • TAKENO N., 2005, Atlas of Eh-pH diagram, Intercomparison of Thermodynamic Databases, Nat. Ins Adv. Ind. Sci. Techn. http://www.fssm.ucam.ac.ma/biblioadmin/opac_css/chimie/Atlas_Eh-pH_diagrams.pdf.
  • WANG X.H., FORSSBERG K.S.E., 1996, The solution electrochemistry of sulfide – xanthate – cyanide systems in sulfide mineral flotation, Miner. Eng., 9, 527-546.
  • WET J.R., PISTORIUS P.C., SANDENBERGH R.F., 1997,The influence of cyanide on pyrite flotation from gold leach residues with sodium isobutyl xanthate, Int. J. Miner. Process., 49, 149-169.
  • WET J.R., SANDENBERGH R.F., 1993, The behavior of mild steel in aqueous cyanide solutions at high temperatures, J. South Afr. Inst. Min. Metall., 93, 105-112.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-6f9532a2-333a-4388-a97b-b26afa41dfa9
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