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Selection of appropriate types of collectors as the main basis of flotation can have a significant impact on the process efficiency. In this regard, 2, 5-Dimercapto-1, 3, 4-thiadiazole (DMDT) was introduced as a new collector. And, its performance was compared with the prevalent collector C7240 (a mixture of 10–20 wt% sodium alkyl dithiophosphate and 20–30 wt% sodium mercaptobenzothiozole) and Sodium Isobutyl Xanthate (SIBX) on the flotation of copper sulfide ores. The effect of the reagent dosage (collector and frother) and pH level were studied using a design of experiment (DOE). Results showed effect of factors was significant in the case of copper recovery and grade of product. Consequently, the optimum range of the DMDT was 8 g/t at pH=11.8 in which the maximum grade and recovery were obtained. Also, the application of chemical agents also had a significant effect on flotation performance, so that the result of sequential addition of the collector indicated significantly improved recovery and grade. The use of a combination of collectors resulting in both physisorbed and chemisorbed surface products can also affect the froth structure and influence the final grade achieved. Accordingly, the best route of collector addition was DMDT at first, then C7240, and finally SIBX. Through this offer, the maximum recovery and grade of product were achieved 86.2% and 14.1% respectively. So, DMDT as a mixture of two others has a positive effect on the copper flotation efficiency.
Słowa kluczowe
Rocznik
Tom
Strony
71--79
Opis fizyczny
Bibliogr. 28 poz., rys. kolor.
Twórcy
autor
- Mining Engineering Department, Engineering Faculty, Shahid Bahonar University, Kerman, Iran
autor
- Mining Engineering Department, Engineering Faculty, Shahid Bahonar University, Kerman, Iran
Bibliografia
- NGUYEN, A. V., SCHULTZE, H. J. 2004. Colloidal science of flotation.
- FUERSTENAU, M. C., JAMESON, G. J., YOON, R. H. (EDS.). 2007. Froth flotation: a century of innovation. SME.
- XING, Y., GUI, X., PAN, L., PINCHASIK, B. E., CAO, Y., LIU, J., KAPPL, M., BUTT, H.J. 2017a. Recent experimental advances for understanding bubble-particle attachment in flotation. Advances in colloid and interface science, 246, 105-132.
- XING, Y., GUI, X., CAO, Y. 2017B. The hydrophobic force for bubble–particle attachment in flotation–a brie review. Physical Chemistry Chemical Physics, 19(36), 24421-24435.
- LI, S., SCHWARZ, M. P., YANG, W., FENG, Y., WITT, P., SUN, C. 2020. Experimental observations of bubble–particie collisional interaction relevant to froth flotation, and calculation of the associated forces. Minerals Engineering, 151, 106335.
- GAUTAM, S., JAMESON, G. J. 2019. The detachment of particles from bubbles at various locations in a turbulent flotation cell. Minerals Engineering, 132, 316-325.
- MCFADZEAN, B., MHLANGA, S.S., O’CONNOR, C.T. 2013. The effect of thiol collector mixtures on the flotation of pyrite and galena. Minerals Engineering, 50, 121-129.
- LIU, G., YANG, X., ZHONG, H. 2017. Molecular design of flotation collectors: A recent progress. Advances in Colloid and Interface Science, 246, 181-195.
- MUGANDA, S., ZANIN, M., GRANO, S. R. 2011. Influence of particle size and contact angle on the flotation of chalcopyrite in a laboratory batch flotation cell. International Journal of Mineral Processing, 98(3-4), 150-162.
- CHIPFUNHU, D., ZANIN, M., GRANO, S. 2012. Flotation behaviour of fine particles with respect to contact angle. Chemical engineering research and design, 90(1), 26-32.
- HAN, G., WEN, S., WANG, H., FENG, Q., 2021. Surface sulfidization mechanism of cuprite and its response to xanthate adsorption and flotation performance. Minerals Engineering 169, 106982.
- ZHANG, Q., WEN, S., FENG, Q., LIU, J., 2021a. Surface modification of azurite with lead ions and its effects on the adsorption of sulfide ions and xanthate species. Applied Surface Science 543, 148795.
- ZHANG, Q., WEN, S., FENG, Q., LIU, Y., 2021b. Activation mechanism of lead ions in the flotation of sulfidized azurite with xanthate as collector. Minerals Engineering 163, 106809.
- BRADSHAW, C.T. 1998. Synergistic interactions between reagents in sulphide flotation. Journal of the Southern African Institute of Mining and Metallurgy, 98(4), 189-193.
- LOTTER, N. O., BRADSHAW, D. J. 2010. The formulation and use of mixed collectors in sulphide flotation. Minerals engineering, 23(11-13), 945-951.
- WAKAMATSU, T., NUMATA, Y., PARK, C.H. 1980. Fundamental study on the flotation of minerals using two kinds of collectors. In Fine Particle Processing (Vol. 1, pp. 787-801). AIME New York, NY.
- WOODS, R., 1984. Electrochemistry of sulphide flotation. In: Fuerstenau, M.C. (Ed.), Flotation: A.M. Gaudin Memorial Volume. AIME, New York, pp. 298–334.
- MCFADZEAN, B., CASTELYN, D.G., O’CONNOR, C.T. 2012. The effect of mixed thiol collectors on the flotation of galena. Minerals Engineering, 36, 211-218.
- BAGCI, E., EKMEKCI, Z., BRADSHAW, D. 2007. Adsorption behaviour of xanthate and dithiophosphinate from their mixtures on chalcopyrite. Minerals Engineering, 20(10), 1047-1053.
- CRITCHLEY, J. K., RIAZ, M. 1991. Study of synergism between xanthate and dithiocarbamate collectors in flotation of heazlewoodite. Transactions of the Institution of Mining and Metallurgy Section C-Mineral Processing and Extractivve Metallurgy, 100, C55-C57.
- DHAR, P., THORNHILL, M., KOTA, H.R. 2019. Comparison of single and mixed reagent systems for flotation of copper sulphides from Nussir ore. Minerals Engineering, 142, 105930.
- SHOUJI, E., YOKOYAMA, Y., POPE, J.M., OYAMA, N., BUTTRY, D.A. 1997. Electrochemical and Spectroscopic Investigation of the Influence of Acid− Base Chemistry on the Redox Properties of 2, 5-Dimercapto-1, 3, 4-thiadiazole. The Journal of Physical Chemistry B, 101(15), 2861-2866.
- HUANG, L., SHEN, J., REN, J., MENG, Q., YU, T. 2001. The adsorption of 2, 5-dimer-capto-1, 3, 4-thiadiazole (DMTD) on copper surface and its binding behavior. Chinese Science Bulletin, 46(5), 387-389.
- NURI, O. S., IRANNAJAD, M., MEHDILO, A. 2019. Effect of surface dissolution on kinetic parameters in flotation of ilmenite from different gangue minerals. Transactions of Nonferrous Metals Society of China, 29(12), 2615-2626.
- KANG, J., FAN, R., HU, Y., SUN, W., LIU, R., ZHANG, Q., LIU, H., MENG, X. 2018. Silicate removal from recycled wastewater for the improvement of scheelite flotation performance. Journal of Cleaner Production, 195, 280-288.
- TAGUTA, J., MCFADZEAN, B., O'CONNOR, C. 2019. The relationship between the flotation behaviour of a mineral and its surface energy properties using calorimetry. Minerals Engineering, 143, 105954.
- MOHAMMADI-JAM, S., BURNETT, D.J., WATERS, K.E. 2014. Surface energy of minerals–Applications to flotation. Minerals Engineering, 66, 112-118.
- IRANNAJAD, M., NURI, O.S., MEHDILO, A. 2019. Surface dissolution-assisted mineral flotation: A review. Journal of Environmental Chemical Engineering, 7(3), 103050.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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