Evaluation on Curing Properties and Kinetics of Isophthalonitrile Oxide

• Autorzy: Fan Y. , Tang C. , Hu Q. , Lei Y. , Huo J.

Identyfikatory

DOI

10.2478/pjct-2018-0036

• Języki publikacji: EN

Abstrakty

EN

N,N-dihydroxybenzene-1,3-dicarboximidoyl dichloride was synthesized from benzene-1,3-dicarboxaldehyde and characterized by fourier transform infrared spectroscopy (FT-IR) and nuclear magnetic resonance  ¹H and ¹³C NMR). The elastomer was prepared through the 1,3-dipolar cycloaddition of reaction between liquid polybutadiene (LPB) and isophthalonitrile oxide in this work. The tensile strength of different elastomer was enhanced from 0.14 MPa to 0.33 MPa as the elongation at break decreased from 145% to 73%, and the modulus increased from 0.09 kPa to 0.47 kPa. The parameters of kinetic indicated that the curing reaction was first order reaction and the apparent activation energy of each curing system was less than 10.10 kJ/mol when the content of N,N-dihydroxybenzene-1,3- dicarboximidoyl dichloride was increased from 7% to 12%. These results suggested that nitrile oxides achieved curing of polymer binders at room temperature and this work had definite guiding significance for the application of nitrile oxides in polymer binders.

Słowa kluczowe

EN

N,N-dihydroxybenzene-1,3-dicarboximidoyl dichloride; kinetics; elastomer; synthesis; 1,3-dipolar cycloaddition

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2018
• Tom: Vol. 20, nr 3
• Strony: 37--46
• Opis fizyczny: Bibliogr. 28 poz., rys.

Twórcy

autor

Fan Y.

• Southwest University of Science and Technology, School of Materials Science and Engineering, Mianyang ,621010, People’s Republic of China

autor

Tang C.

• Southwest University of Science and Technology, School of Materials Science and Engineering, Mianyang ,621010, People’s Republic of China

autor

Hu Q.

• Yixing Danson Science & Technology Co., Ltd., Yixing, 214200, People’s Republic of China

autor

Lei Y.

• Southwest University of Science and Technology, School of Materials Science and Engineering, Mianyang ,621010, People’s Republic of China

autor

Huo J.

• Southwest University of Science and Technology, School of Materials Science and Engineering, Mianyang ,621010, People’s Republic of China

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).