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Long-Term Measurments of Atmospheric Mercury Species (TGM, TPM) and Hg Deposition in the Silesian Region, Poland : Concept of the Mercury Deposition Coefficient

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Warianty tytułu
PL
Długoterminowe oznaczanie specjacyjnych form rtęci (TGM, TPM) w powietrzu atmosferycznym oraz depozycji rtęci na obszarze województwa śląskiego : koncepcja współczynnika depozycji rtęci
Języki publikacji
EN
Abstrakty
EN
The aim of this work was to identify concentration levels of different chemical forms of mercury (TGM, TPM) in the ambient air in selected areas of the Silesian Region, characterized by low and high mercury emission. Based on the obtained data TGM and TPM concentration levels were determined. The project also focused on determination of dry and wet deposition of mercury compounds. Data concerning TGM and TPM flux rates in the ambient air and data on mercury deposition were used to determine a deposition coefficient. The coefficient was calculated as a share of mercury deposition on the land surface (dry and wet) to the amount of this contaminant transported with loads of air in the form of TGM and TPM in a given measurement station. At both monitoring stations the deposition coefficient did not exceed 0.2 %. The idea of calculating the deposition coefficient based on the analysis of TGM and TPM flux rate is a new solution. The proposed deposition coefficient allows to quantify information on a selected contaminant concentration and its potential impact resulting from deposition. Further studies on the deposition coefficient may contribute to the development of methods for estimating the impact of contaminants contained in the ambient air on other environmental components based on the analyses of the contaminant flux rate.
PL
Głównym celem tego projektu było określenie poziomów stężeń specjacyjnych form rtęci (TGM, TPM) w powietrzu atmosferycznym na wybranych obszarach Województwa Śląskiego charakteryzujących się zróżnicowanym oddziaływaniu źródeł emisji zanieczyszczeń powietrza. Na podstawie uzyskanych danych pomiarowych określono poziomy stężeń TGM i TPM jakie występują na badanym obszarze oraz wyznaczono wielkości suchej i mokrej depozycji związków rtęci. Na podstawie otrzymanych danych dotyczących natężeń strumieni TGM i TPM a także danych o wielkości depozycji związków rtęci wyznaczono wartość współczynnika depozycji rtęci. Współczynnik ten można scharakteryzować jako udział natężeń strumieni TGM i TPM napływającymi z masami powietrza do punktu pomiarowego w stosunku do suchej i mokrej depozycji rtęci w danym punkcie pomiarowym. Rozwiązanie dotyczące wyznaczenia współczynnika depozycji, które opiera się na analizie przepływów rtęci w powietrzu jest podjęte po raz pierwszy zarówno na świecie, jak i w Polsce. W przeprowadzonych badaniach wartości współczynnika depozycji rtęci nie przekroczyła 0,2%. Zaproponowany współczynnik depozycji daje możliwość powiązania w sposób ilościowy informacji o poziomach stężeń analizowanego zanieczyszczenia w powietrzu atmosferycznym z możliwością jego oddziaływania w wyniku depozycji. Rozwój idei współczynnika depozycji może w przyszłości prowadzić do stworzenia systemu oceny oddziaływania zanieczyszczeń zwartych w powietrzu atmosferycznym na inne komponenty środowiska poprzez analizę strumieni napływu tych zanieczyszczeń.
Rocznik
Strony
43--60
Opis fizyczny
Bibliogr. 42 poz., rys., tab., wykr.
Twórcy
autor
  • Institute for Ecology of Industrial Areas, Kossutha 6, 40-844 Katowice, Poland
  • Institute for Ecology of Industrial Areas, Kossutha 6, 40-844 Katowice, Poland
autor
  • Institute for Ecology of Industrial Areas, Kossutha 6, 40-844 Katowice, Poland
Bibliografia
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  • [4] Nowak, B. & Zielonka, U. (2010). Changes in the content of Total Gaseous Mercury (TGM) and Total Particulate Mercury (TPM) in 2009 at the Upper Silesia Region, Poland. Proceedings of 15th International Conference on Heavy Metals in the Environment, 238–241.
  • [5] Schroeder, W.H. & Munthe, J. (1998). Atmospheric mercury – an overview, Atmospheric Environment, 29, 809–822.
  • [6] Berg, T., Bartnicki, J., Munthe, J., Lattaila, H., Hrehoruk, J. & Mazur, A. (2001). Atmospheric mercury species in the European Arctic: measurements and modeling, Atmospheric Environment, 35, 2569–2582.
  • [7] Brosst, C. & Lord, E. (1995). Methylmercury in ambient air. Method of determination and some measurement result. Water, Air, and Soil Pollution, 82, 739–750.
  • [8] Ariya, P. & Khalizov, A. (2002). Reactions of gaseous mercury with atomic and molecular halogens: kinetics, product studies and atmospheric implications, The Journal of Physical Chemistry, 106, 7310–7320.
  • [9] Sommar, J., Gardfeldt, K., Stromberg, D., Feng, X., (2001). A kinetic study of the gas-phase reaction between the hydroxyl radical and atomic mercury, Atmospheric Environment, 35, 3049–3054.
  • [10] Plijel, K. & Munthe, J. (2003). Modeling the atmospheric mercury cycles – chemistry in fog droplets, Atmospheric Environment, 29, 1441–1457.
  • [11] Fu, X., Feng, X., Zhu, W., Wang, S. & Lu, J. (2008). Total gaseous mercury concentrations in ambient air in the eastern slope of t. Gongga, South-Eastern fringe of the Tibetan plateau, China, Atmospheric Environment, 42, 970–979.
  • [12] Choi, E.M., Ki, S.H., Holsen, T. & Yi, S.M. (2009). Total gaseous concentration in mercury in Seoul, Korea: Local sources compared to long-range transport from China and Japan, Environmental Pollution, 157, 816–822.
  • [13] Nakagawa, R. & Hirooto, M. (1997). Geographical distribution and background levels of total mercury in air in Japan and neighboring countries, Chemosphere, 34, 801–806.
  • [14] Lynam, M.M. & Keeler, G.J. (2006). Source-receptor relationships for mercury in Urban Detroit, Michigan. Atmospheric Environment, 39, 3144–3155.
  • [15] Fu, X., Feng, X., Wang, S., Rothenberg, S., Shang, L., Li, Z. & Qui, G. (2009). Temporal and spatial distributions of total gaseous mercury concentrations in ambient air in a mountainous area in southwestern China: Implications for industrial and domestic mercury emissions in remote areas in China, Science of the Total Environment, 407, 2306–2314.
  • [16] Mazur, M., Mintz, R., Lapalme, M. & Wiens, B. (2009). Ambient air total gaseous mercury concentrations in the vicinity of coal-fired power plants in Alberta, Canada. Science of the Total Environment, 408, 373–381.
  • [17] Liu, S., Nadim, F., Perkins, C.H., Carley, R., Hoag, G., Lin, Y. & Chen, L. (2002). Atmospheric mercury monitoring survey in Beijing, China. Chemosphere, 48, 97–107.
  • [18] Gabriel, M.C., Willason, D.G., Brooks, S. & Lindberg, S. (2005). Atmospheric speciation of mercury in two contrasting Southeastern US airsheds, Atmospheric Environment, 39, 4947–4958.
  • [19] Lynam, M.M. & Keeler, G.J. (2005a). Artifacts associated with the measurement of particulate mercury in an urban environment: the influence of elevated ozone concentrations. Atmospheric Environment, 39, 3081–3088.
  • [20] Kim, S.H., Han, Y.J., Holsen, T.M. & Yi, S.M. (2009). Characteristics of atmospheric speciated mercury concentrations (TGM, Hg(II) and Hg(p)) in Seoul, Korea. Atmospheric Environment, 43, 3267–3274.
  • [21] Fang, F., Wang, Q. & Li, J. (2004). Urban environmental mercury in Changchun, a metropolitan city in northeastern China: source, cycle, and fate, Science of the Total Environment, 330, 159–170.
  • [22] Fu, X. Feng, X., Zhu, W., Zheng, W., Wang, S. & Lu, J.Y. (2008). Total particulate and reactive gaseous mercury in ambient air on the eastern slope of the Mt. Gongga area, China. Applied Geochemistry, 23, 408–418.
  • [23] Pacyna, E.G., Pacyna, J.M., Fudała, J., Strzelecka-Jastrząb, E., Hławiczka, S. & Panasiuk, D. (2006). Mercury emissions to the atmosphere from anthropogenic sources in Europe in 2000 and their scenarios until 2020, The Science of the Total Environment, 370, 147–156.
  • [24] Pacyna, E., Pacyna, J., Sundseth, K., Munthe, J., Kindborn, K., Wilson, S., Steenhuisen, F. & Maxson, P. (2010). Global emission of mercury to the atmosphere from anthropogenic sources in 2005 and projections to 2020, Atmospheric Environment, 44, 2487–2499.
  • [25] Ebinghaus, R., Jennings, S.G., Schroeder, W.H., Berg, T., Donaghy, T., Guentzel, J., Kenny, C., Kock, H.H., Kvietkus, K., Landing, W., Munthe, J., Prestbo, E.M., Schneberger, D., Slemr, F., Sommar, J., Urba, A., Wallschlanger, R D., Xioa, Z., 1999, International field intercomparison measurements of atmospheric mercury species at Mace Head, Ireland. Atmospheric Environment, 33, 3063–3073.
  • [26] Li, J., Sommar, J., Wangberg, I., Lindqvist, O. & Wei, S. (2008). Short-time variation of mercury speciation in urban of Göteborg during GÖTE-2005, Atmospheric Environment, 42, 8382–8388.
  • [27] Hladikova, V., Petrik, J., Jursa, S., Ursinova, M. & Kocan, J. (2001). Atmospheric mercury levels in Slovak Republic, Chemosphere, 45, 801–806.
  • [28] Wangberg, I. & Munthe, J. (2001). Atmospheric mercury in Sweden, Northern Finland and Northern Europe. Results from National Monitoring and European Research. Report IVL, Göteborg, Sweden.
  • [29] Zielonka, U., Hławiczka, S., Fudała, J., Wangberg, I. & Munthe, J. (2005). Seasonal mercury concentrations measured in rural air in Southern Poland. Contribution from local and regional coal combustion, Atmospheric Environment, 39, 7580–7586.
  • [30] Marks, R. & Bełdowska, M., (2001). Air-sea exchange of mercury vapour over the Gulf of Gdańsk and southern Baltic Sea, Journal of Marine Systems, 27, 315–324.
  • [31] Pyta, H., C. Rosik-Dulewska & Czaplicka, M. (2009). Speciation of Ambient Mercury in the Upper Silesia Region, Poland, Water, Air, & Soil Pollution, 197, 233–240.
  • [32] Hławiczka, S. et al. (2008). Analysis of air pollution by particulate matter PM10 and PM2.5, taking into account the chemical composition of particulate matter, including heavy metals and PAHs. Raport (in Poland).
  • [33] Beldowska, M., Saniewska, D., Falkowska, L., Lewandowska, A. (2012). Mercury in particulate matter over Polish zone of the southern Baltic Sea, Atmospheric Environment, 46, 397–404.
  • [34] Bełdowska, M., Zawalich, K., Falkowska, L., Siudek, P. & Magulski, R. (2008). Total gaseous mercury in the area of southern Baltic and in the coastal zone of the Gulf of Gdańsk during spring and autumn, Environment Protection Engineering, 4, 130–139.
  • [35] Pyta, H., C., Rosik-Dulewska. & Czaplicka, M. (2009). Speciation of Ambient Mercury in the Upper Silesia Region, Poland, Water, Air, & Soil Pollution, 197, 233–240.
  • [36] Sakata, A. & Marumoto, K., (2005). Wet and dry deposition fluxes of mercury in Japan. Atmospheric Environment 39, 3139–3146.
  • [37] Vanarsdale, A., Weiss, J., Keeler, G., Miller, E., Boulet, G., Brultte, R. & Poissant, L. (2005). Patterns of mercury deposition and concentration in northeastern North America, Ecotoxicology, 14, 37–52.
  • [38] Gratz, L. E., Keeler, G.J. & Miller, E.K. (2009). Long-term relationships between mercury wet deposition and meteorology, Atmospheric Environment, 43, 6218–6229.
  • [39] Guo, Y. Feng, X., Li, Z., He, T., Yan, H., Meng, B., Zhang, J., Qiu, G., 2008. Distribution and wet deposition fluxes of total and methyl mercury in Wujing River Basin, Guizhou, China. Atmospheric Environment 42, 7096–7103.
  • [40] Wangberg, I. & Munthe, J. (2001). Atmospheric mercury in Sweden, Northern Finland and Northern Europe. Results from National Monitoring and European Research. Report IVL, Göteborg, Sweden.
  • [41] Nowak B., Czaplicka M., Grzegorczyk M. & Zielonka U. (2013). Comparison of mercury measurement methods in wet deposition, Environment Protection Engineering1, 39, 75–85.
  • [42] Sholupov, S., Pogarev, S., Ryzhov, V., Mashyanov, N & Stroganov, A. (2004). Zeeman atomic absorption spectrometer RA-915+ for direct determination of mercury in air and complex matrix samples. Fuel Processing Technology, 85, 473–485.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-6f4aa8c7-af96-41fc-8e98-c1079c00b0b8
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