Application of ultrasound-assisted deep eutectic solvent extraction combined with liquid-liquid extraction method to the extraction of three pesticide residues from fruit and vegetable samples

• Autorzy: Chen Sue , An Qi , Sun Hong , Mao Mengqian

Identyfikatory

DOI

10.1556/1326.2020.00727

• Języki publikacji: EN

Abstrakty

EN

A simple, inexpensive and sensitive method was developed for the simultaneous determination of three pesticide residues (carbendazim, thiophanate-methyl, and imidacloprid) in fruit and vegetable samples using high performance liquid chromatography (HPLC) based on a combined pretreatment of ultrasoundassisted deep eutectic solvent extraction (UA-DES-E) and liquid-liquid extraction (LLE). In this study, various types of deep eutectic solvents (DESs) were synthesized and the extraction efficiency was compared as extraction solvents. Results showed that glycerol-proline 5 9:4 (GP-5) obtained the highest extraction efficiency among different types of DESs. Experiment conditions, including DES volume, extraction time and pH, were systematically optimized using single-factor experiment. Under the optimum conditions, the limits of detection (LODs) and quantification (LOQs) were in the ranges of 0.05– 0.2 mg$mL1 and 0.1–0.5 mg$mL1, respectively. The relative recoveries of the three pesticides in the fruit and vegetable samples ranged from 85.7 to 113.0% at two spiked levels. Meanwhile, the method achieved excellent linearity with determination coefficients (r) greater than 0.999. Furthermore, the method was successfully applied to the analysis of the pesticides in real fruit and vegetable samples (apple, tomato, and grape).

Słowa kluczowe

EN

deep eutectic solvents; pesticide residue; ultrasound-assisted extraction; liquid-liquid extraction; fruit samples; vegetable samples

• Wydawca: University of Silesia in Katowice ; Akademiai Kiado
• Czasopismo: Acta Chromatographica
• Rocznik: 2021
• Tom: Vol. 33, no. 1
• Strony: 30--36
• Opis fizyczny: Bibliogr. 39 poz., rys., tab.

Twórcy

autor

Chen Sue

• Department of Pharmacy, Shanxi Health Vocational College, Jinzhong, Shanxi Province, 030619, PR China

autor

An Qi

• Department of Pharmacy, Shanxi Health Vocational College, Jinzhong, Shanxi Province, 030619, PR China

autor

Sun Hong

• Department of Pharmacy, Shanxi Health Vocational College, Jinzhong, Shanxi Province, 030619, PR China

autor

Mao Mengqian

• Department of Pharmacy, Shanxi Health Vocational College, Jinzhong, Shanxi Province, 030619, PR China

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).