Intermediates derived from p-terphenyl in the methyltributylammonium bis[(trifluoromethyl)sulfonyl]imide ionic liquid saturated with carbon dioxide : pulse radiolysis study

• Autorzy: Kocia Rafał

Identyfikatory

DOI

10.2478/nuka-2022-0006

• Języki publikacji: EN

Abstrakty

EN

Radiation-induced processes in ionic liquid (IL) methyltributylammonium bis[(trifl uoromethyl)sulfonyl] imide ([MeBu3N][NTf2]) solutions containing p-terphenyl (TP) and saturated with carbon dioxide (CO2) were studied using nanosecond pulse radiolysis technique with UV-vis detection. The transient absorption spectra generated in these solutions were assigned to TP radical anions (TP•–) and triplet excited states (3TP*). Saturation of [MeBu3N][NTf2] solutions with carbon dioxide efficiently takes out presolvated electrons (e–presolv) and solvated electrons (e–solv). On the other hand CO2 is not a scavenger of excited states of TP (1TP*, 3TP*), which in the reaction with triethylamine (TEA) leads to the formation of TP•-.

Słowa kluczowe

EN

carbon dioxide; ionic liquid; methyltributylammonium bis[(trifl uoromethyl)sulfonyl]imide; p-Terphenyl; pulse radiolysis; radical ions

• Wydawca: Institute of Nuclear Chemistry and Technology
• Czasopismo: Nukleonika
• Rocznik: 2022
• Tom: Vol. 67, No. 4
• Strony: 73--80
• Opis fizyczny: Bibliogr. 72 poz., rys.

Twórcy

autor

Kocia Rafał

• Laboratory for Detection of Irradiated Food Institute of Nuclear Chemistry and Technology Dorodna 16 Str., 03-195 Warsaw, Poland

• https://orcid.org/0000-0003-1906-5579

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Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).