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Chloroorganic Pesticide Adsorption from Water Solution Using Sewage Sludge Vermicompost as a Natural Sorbent

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Dozens of thousands of tons of pesticide waste have been stored since 1950s. The corrosion of concrete bunkers and wells where the expired pesticides are deposited causes the risk of toxic leakage due to deteriorating conditions of these constructions. Such hazardous spill might be transported by underground waters in the form of so-called underground inflow and subsequently might reach a network of surface waters. Evaluating the adsorption potential of natural sorbent for pesticide was the main goal of this research. The adsorption balance was examined in order to analyze the influence of the adsorption mechanism of HCH molecules on vermicompost. The adsorption of HCH isotherms by vermicompost at constant temperature was tested experimentally. The Freundlich, Langmuir and BET’s adsorption isotherm models describe the experimental data within the acceptable error ranges. The Freundlich model proved to be more suitable for the experimental data. The form of isotherms indicates that HCH is adsorbed as a monolayer; therefore no obstacles occur in order for water and pesticide molecules to cover the adsorption surface.
Słowa kluczowe
Rocznik
Strony
123--128
Opis fizyczny
Bibliogr. 18 poz., rys., tab.
Twórcy
  • Department of Technology in Engineering and Environmental Protection, Białystok University of Technology, ul. Wiejska 45a, 15-351 Białystok, Poland
Bibliografia
  • 1. Atkins P.W., 2006. Physical chemistry, 8th ed., Oxford University Press
  • 2. Balinova A. 1996. Strategies for chromatographic analysis of pesticide residues in water. J. Chromatogr. A 754, 125-135.
  • 3. Chin-Pampillo J.S., Masís-Mora M., Ruiz-Hidalgo K., Carazo-Rojas E., Rodríguez C.E., 2016, Removal of carbofuran is not affected by co-application of chlorpyrifos in a coconut fiber/compost based biomixture after aging or pre-exposure. J Environ. Sci., 46, 182-189.
  • 4. El-Sharkawy I.I., Saha B.B., Koyama S., Choon Ng K., 2006, A study on the kinetics of ethanolactivated carbon fiber: Theory and experiments, Int. J Heat and Mass Tran. 49, 3104-3110.
  • 5. Głowacki M., Ciesielczuk T., 2014, Assessment of pahs and selected pesticides in shallow groundwater in the highest protected areas in the Opole region, Poland. J. Ecol. Eng.15(2), 17-24.
  • 6. Hamadi N.K., Swaminathan S., Chen X.D., 2004, Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon Part I. Two-par ameter models and equations allowing determination of thermodynamic parameters. J. Hazard. Mater. B112, 133-141.
  • 7. Hamdaoui O., Naffrechoux E., 2007 Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon – Part I. Two-parameter models and equations allowing determination of thermodynamic parameters. J. Hazard. Mater. 147, 381-394.
  • 8. Hussen A., Westbom R., Megersa N., Mathiasson L., Bjorklund E. 2007. J Chromatogr. A 1152, 247-251.
  • 9. Ignatowicz K. 2017. The impact of sewage sludge treatment on the content of selected heavy metals and their fractions. Environ. Res. 156, 19-22.
  • 10. Ignatowicz K., 2011, Metals content chosen for environmental component monitoring in graveyards, Fresen. Environ. Bull. 20 (1a), 270-273.
  • 11. Kogut P., Piekarski J., Ignatowicz K., 2014 Start-up of Biogas Plant with Inoculating Sludge Application, Rocznik Ochrona Środowiska, 16, 534-545.
  • 12. Kumar A., Kumar S., Kumar S. 2003. Adsorption of resorcinol and catechol on granular activated carbon: Equilibrium and kinetics. Carbon 41, 3015-3025.
  • 13. Moawed E.A.,. Radwan A.M, 2017, Application of acid modified polyurethane foam surface for detection and removing of organochlorine pesticides from wastewater. Journal of Chromatogr. B, 15, 1044-1045.
  • 14. Neethu Narayanan, Suman Gupta, Gajbhiye V.T., Manjaiah K.M., 2017. Optimization of isotherm models for pesticide sorption on biopolymer-nanoclay composite by error analysis, Chemosphere, 173, 502-511.
  • 15. Ochsner T.E., Stephens B.M., Koskinen W.C., Kookana R.S., 2006 Sorption of a hydrophilic pesticide. Soil Sci. Soc. Am. 70, 1991-1997.
  • 16. Sahaa B.B., Chakraborty A., Koyama S., Yoon S., Mochida I., Kumja M., Yap C., Choon Ng 2008, , Isotherms and thermodynamics for the adsorption of n-butane on pitch based activated carbon, Int. J Heat and Mass Tran. 51, 1582-1589.
  • 17. Witbowo N., Setyadhi L., Witbowo D., J. Setiawan, S. Ismadji 2007, Adsorption of benzene and toluene from aqueous solutions onto activated carbon and its acid and heat treated forms: Influence of surface chemistry on adsorption. J. Hazard. Mater. 146, 237-242.
  • 18. Yuh-Shan Ho, 2006 Isotherms for the sorption of lead onto peat: comparison of linear and non-linear methods. Pol. J. Environ. Stud. 15, 81-86.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-6af2b5f1-9906-4692-8751-86f995090b48
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