Thermodynamic Description of Ternary Fe-B-X Systems. Part 8: Fe-B-Mo, with Extension to Quaternary Fe-B-Cr-Mo System

• Autorzy: Miettinen Jyrki , Visuri Ville-Valtteri , Fabritius Timo

Identyfikatory

DOI

10.24425/amm.2021.134786

• Języki publikacji: EN

Abstrakty

EN

Thermodynamic optimizations of the ternary Fe-B-Mo system and its binary sub-system B-Mo are presented. The Fe-B-Mo description is then extended to the quaternary Fe-B-Cr-Mo system by assessing the ternary B-Cr-Mo system. The thermodynamic descriptions of the other binaries (Fe-B, Fe-Cr, Fe-Mo, B-Cr, and Cr-Mo) and the other ternaries (Fe-B-Cr and Fe-Cr-Mo) are taken from earlier studies. In this study, the adjustable parameters of the B-Mo, Fe-B-Mo, and B-Cr-Mo systems were optimized using the experimental thermodynamic and the phase equilibrium data from the literature. The solution phases of the system (liquid, bcc and fcc) are described with the substitutional solution model, and most borides are treated as stoichiometric phases or semistoichiometric phases, using a simple two-sublattice model for the latter. The system’s intermetallic phases, Chi, Mu, R, and Sigma (not dissolving boron) as well as boride M₃B₂, based on a formulation of (Cr,Fe)(Cr,Fe,Mo)₂(B)₂, are described with a three-sublattice model. Reasonable agreement is obtained between the calculated and measured phase equilibria in all four systems: B-Mo; Fe-B-Mo; B-Cr-Mo; and Fe-B-Cr-Mo.

Słowa kluczowe

EN

phase diagrams; thermodynamic modeling; thermodynamic database; Fe-based systems; Fe-B-X systems; Fe-B-Mo system; Fe-B-Cr-Mo system

• Wydawca: Institute of Metallurgy and Materials Science of Polish Academy of Sciences ; Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences
• Czasopismo: Archives of Metallurgy and Materials
• Rocznik: 2021
• Tom: Vol. 66, iss. 1
• Strony: 281--295
• Opis fizyczny: Bibliogr. 53 poz., rys., tab., wykr.

Twórcy

autor

Miettinen Jyrki

• University of Oulu, Process Metallurgy Research Unit, P.O. Box 4300, FI-90014 University of Oulu, Finland

autor

Visuri Ville-Valtteri

• University of Oulu, Process Metallurgy Research Unit, P.O. Box 4300, FI-90014 University of Oulu, Finland

autor

Fabritius Timo

• University of Oulu, Process Metallurgy Research Unit, P.O. Box 4300, FI-90014 University of Oulu, Finland

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Uwagi

1. This study was executed within the framework of the Genome of Steel profiling project. The Academy of Finland (project 311934) is acknowledged for funding this study.

2. Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).