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Thermodynamic Description of Ternary Fe-B-X Systems. Part 8: Fe-B-Mo, with Extension to Quaternary Fe-B-Cr-Mo System

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EN
Abstrakty
EN
Thermodynamic optimizations of the ternary Fe-B-Mo system and its binary sub-system B-Mo are presented. The Fe-B-Mo description is then extended to the quaternary Fe-B-Cr-Mo system by assessing the ternary B-Cr-Mo system. The thermodynamic descriptions of the other binaries (Fe-B, Fe-Cr, Fe-Mo, B-Cr, and Cr-Mo) and the other ternaries (Fe-B-Cr and Fe-Cr-Mo) are taken from earlier studies. In this study, the adjustable parameters of the B-Mo, Fe-B-Mo, and B-Cr-Mo systems were optimized using the experimental thermodynamic and the phase equilibrium data from the literature. The solution phases of the system (liquid, bcc and fcc) are described with the substitutional solution model, and most borides are treated as stoichiometric phases or semistoichiometric phases, using a simple two-sublattice model for the latter. The system’s intermetallic phases, Chi, Mu, R, and Sigma (not dissolving boron) as well as boride M3B2, based on a formulation of (Cr,Fe)(Cr,Fe,Mo)2(B)2, are described with a three-sublattice model. Reasonable agreement is obtained between the calculated and measured phase equilibria in all four systems: B-Mo; Fe-B-Mo; B-Cr-Mo; and Fe-B-Cr-Mo.
Twórcy
  • University of Oulu, Process Metallurgy Research Unit, P.O. Box 4300, FI-90014 University of Oulu, Finland
  • University of Oulu, Process Metallurgy Research Unit, P.O. Box 4300, FI-90014 University of Oulu, Finland
  • University of Oulu, Process Metallurgy Research Unit, P.O. Box 4300, FI-90014 University of Oulu, Finland
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Uwagi
1. This study was executed within the framework of the Genome of Steel profiling project. The Academy of Finland (project 311934) is acknowledged for funding this study.
2. Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-6ac1a057-cf27-4d72-9e1b-19971d3f1290
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