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Thermodynamic description of the Fe-B-C system in its iron-rich corner is developed in the context of a new Fe-B-X (X = Cr, Ni, Mn, Si, Ti, V, C) database. The thermodynamic parameters of the binary sub-systems, Fe-B, Fe-C and B-C, are taken from earlier assessments modifying the B-C description. The parameters of the Fe-B-C system are optimized in this study using experimental thermodynamic and phase equilibrium data from the literature. Liquid, beta-rhombo-B and graphite phases are described using the substitutional solution model, while the ferrite (bcc), the austenite (fcc), the cementite (M3C) and the M23C6 phases are described with the sublattice model and the borides, Fe2B, FeB and B4C, are treated as stoichiometric phases. A good correlation was obtained between the calculated and the experimental thermodynamic and phase equilibrium data. The description is recommended to be used at the composition region of wt% C + wt% B < 15 and at temperatures below 2700°C.
Wydawca
Czasopismo
Rocznik
Tom
Strony
923--933
Opis fizyczny
Bibliogr. 67 poz., rys., tab.
Twórcy
autor
- University of Oulu, Process Metallurgy Research Unit, P.O. Box 4300, 90014 University of Oulu, Finland
autor
- University of Oulu, Process Metallurgy Research Unit, P.O. Box 4300, 90014 University of Oulu, Finland
autor
- University of Oulu, Process Metallurgy Research Unit, P.O. Box 4300, 90014 University of Oulu, Finland
autor
- University of Plovdiv, Faculty of Chemistry, 24 Tsar Asen Str., 4000 Plovdiv, Bulgaria
Bibliografia
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Uwagi
EN
1. This study was executed within the framework of the Genome of Steel profiling project. The Academy of Finland (project 311934) and Walter Ahlström Foundation are acknowledged for funding this work.
PL
2. Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-6ab1ccef-b423-4f66-9fdb-9b30296b940e