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Production of high quality magnesium chloride from recycled waste magnesite powder

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Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This study investigates the production of high-quality MgCl2 from recycled waste magnesite powder with an average particle size of d50 0.079 mm using the HCl acid leaching method. The experimental parameters were, leaching temperature, leaching time, amount of the acid, liquid-to-solid ratio, scale-up factor, acid concentration, particle size and mixing speed. The experiments were performed under reproducible conditions. The results showed that optimum leaching parameters were: temperature of 70 °C, 180 min leaching time, 130 cm3 acid consumption, 3.6 cm3/g liquid-to-solid ratio, scale-up factor of 1, 10.17 M acid concentration, 0.079 mm average particle size and a mixing speed 60 rpm. Under these optimum conditions, the leaching yield was 96.72%. The produced MgCl2 solution contained 0.04% SiO2, 0.36% CaO, 0% Fe2O3, 0% Al2O3, 46.73% MgCl2, 52.87% L.O.I. and 99.60% MgCl2+L.O.I. (= MgCl2·6H2O). These results indicated that high-quality magnesium chloride can be produced from waste magnesite powder.
Rocznik
Strony
557--566
Opis fizyczny
Bibliogr. 14 poz., rys., tab.
Twórcy
autor
  • Aksaray University, Department of Mining Engineering, Aksaray, Turkey
autor
  • Canakkale Onsekiz Mart University, Department of Mining Engineering, Canakkale, Turkey
autor
  • Ministry of Energy and Natural Resources, Ankara, Turkey
autor
  • Ministry of Energy and Natural Resources, Ankara, Turkey
autor
  • Gediz University, Faculty of Engineering and Architechure, Izmir, Turkey
Bibliografia
  • 1. ABALI Y., COPUR M., YAVUZ M., 2006, Determination of the optimum conditions for dissolution of magnesite with H2SO4 solution, Indian Journal of Chemical Technology, Vol 13, July 2006, 391–397.
  • 2. ABALI Y., BAYCAN S., ARISOY K., VAIZOGULLAR A., 2011, Optimization of Dolomite Ore Leaching in Hydrochloric Acid Solutions, Physicochem. Probl. Miner. Process. 46 (2011) 253–262.
  • 3. ABDEL-AAL E. A., IBRAHIM I. A., RASHAD M. M., ISMAIL A. K., 1996, Hydrometallurgical processing of Egyptian magnesite ore, Physicochemical Problems of Mineral Processing, 30 (1996) 207–216.
  • 4. ATAK S., 1982, Flotasyon uygulamaları ve ilkeleri (in Turkish), ITU, Istanbul.
  • 5. BREUSCH, F. L., ULUSOY, E., 1987, Genel ve Anorganik Kimya, (in Turkish), İstanbul.
  • 6. CHOU L., GARRELS R. M., WOLLAST R., 1989, Comparative study of the kinetics and mechanism of dissolution of carbonate minerals, Chem. Geology, 78: 269–282.
  • 7. DONMEZ B., DEMIR F., LACIN O., 2009, Leaching kinetics of calcined magnesite in acetic acid solutions, Journal of Industrial and Engineering Chemistry 15 (2009), 865–869.
  • 8. ERDOGAN N., 2002, Kumas Elektro-Filtre Manyezit Tozu Artıklarından Magnezyum Bilesikleri (Magnezyum Oksit, Magnezyum Hidroksit, Magnezyum Klorür ve Magnezyum Diborit) Üretimi, (in Turkish) PhD, Osmangazi University, 180, Eskisehir, Turkey.
  • 9. HARRIS G. B., PEACEY J. G., MONETTE S., 1988, Manufacture of concentrated magnesium chloride solution from magnesite for production of magnesium, Chem. Abst., 109: 24855c.
  • 10. KAYA M., 1993, Magnezit ve Bazik Refrakter Teknolojisi, (in Turkish), Publications of Anadolu University, 450, Eskisehir, Turkey, p. 290
  • 11. OZBEK H., ABALI Y., ÇOLAK S., CEYHUN I., KARAGOLGE Z., 1999, Dissolution kinetics of magnesite mineral in water saturated by chlorine gas, Hydrometallurgy, 51: 173.
  • 12. OZDEMIR M., CAKIR D., KIPCAK I., 2009, Magnesium recovery from magnesite tailings by acid leaching and production of magnesium chloride hexahydrate from leaching solution by evaporation, Int. J. Miner. Process. 93 (2009), 209–212.
  • 13. PALCO S., RIGUAD M., 2002, Metallurgy refractories and environment conference, Slovakia: Technical University of Kosice, p. 275
  • 14. SHIKANO H., 1998, Refractories handbook, Japan, Technical Association of Refractories, p. 127.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-6a6e6b20-dd05-4cd7-834f-a2c3c3a4c003
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