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Thermal methods of sludge disintegration can be divided into high temperature (over 100°C) and low temperature (below this temperature). They consist in the supply or removal of thermal energy, contributing to the changes in sludge structure and physicochemical properties. During the chemical disintegration of excess sludge with sodium hydroxide, there is an increase in the pH value, as well as changes in their structure. The OH- ions are highly toxic to the microorganisms living in the excess sludge and affect the decline of biological activity of most microorganisms. The aim of the conducted research was to prove the impact of the thermal and alkaline disintegration of excess sludge on the susceptibility of organic substances to biodegradation. The thermal disintegration of excess sludge was carried out in a shaking water bath, in which the sludge placed in laboratory flasks with an active volume of 0.5 L were heated for a specified period within the scope of the so-called low temperatures, i.e. 65–95 °C. The sludge was heated for a period of 0.5–12 h. The alkaline disintegration of the sludge was carried out with sodium hydroxide in the form of dust at ambient temperature, in sealed plastic bottles with an active volume of 5L, the contents of which were mixed manually every few hours. The regent doses in the range of 0.05–1.3 g NaOH/g VSS and disintegration time 12h were used. As a result of subjecting the excess sludge to disintegration by means of the selected methods, an increase in the concentration of organic substances in the dissolved form in the supernatant liquid was noted. On the basis of the increase in SCOD, TOC value and VFAs concentration, the most favorable modification conditions were determined. As a result of disintegration of the sludge and subsequent methane fermentation, the supporting effects of the applied modification methods were observed, in relation to the conventional methane fermentation of excess sludge.
Czasopismo
Rocznik
Tom
Strony
172--182
Opis fizyczny
Bibliogr. 31 poz., rys., tab.
Twórcy
autor
- Czestochowa University of Technology, Faculty of Infrastructure and Environment, Institute of Environmental Engineering, Brzeznicka 60a, 42-200 Czestochowa, Poland
Bibliografia
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- 3. Erden G., Filibeli A. 2010. Ultrasonic pre-treatment of biological sludge: consequences for disintegration, anaerobic biodegradability and filterability. Journal of Chemical Technology and Biotechnology, 85(1), 145–150.
- 4. Grübel K., Machnicka A., Nowicka E., Wacławek S. 2013. Mesophilic – thermophyte fermentation of disintegrated sludge in a hybrid process. Proceedings of ECOpole, 7(2), 567–573.
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- 6. Karczmarek A. M., Gaca J. 2015. Effect of twostage thermal disintegration on particle size distribution in sewage sludge. Polish Journal of Chemical Technology, 3, 69-73.
- 7. Kidak R., Wilhelm A.M., Delmas H.. 2009. Effect of process parameters on the energy requirement in ultrasonical treatment of waste sludge. Chemical Engineering and Processing, 2009, 48, 1346–1352.
- 8. Kim J., Park C., Kim T.H., Lee M., Kim S., Kim S.W., Lee J. 2003. Effects of various pretreatments for enhanced anaerobic digestion with waste activated sludge. J. Biosci. Bioeng., 95, 271–275.
- 9. Marcinkowski T. 2004. Alkaline stabilization of municipal sewage sludge. Scientific Works of the Institute of Engineering and Environmental Protection of the Wroclaw University of Technology, Publishing House of the Wroclaw University of Technology, Poland, Wroclaw.
- 10. Müller J. Mechanischer Kläschammaufschluss, Dissertation, TU Braunschweig, Shaker-Verlag, Aachen 1996.
- 11. Myszograj S., Jędrczak A., Suchowska-Kisielewicz M., Sadecka Z. 2013. Thermal and chemical disintegration of excessive sewage sludge. 1 st Global Virtual Conference, http://www.gv-conference.com
- 12. Nanzai B., Okitsu K., Takenaka N., Bandow H., Tajima N., Maeda Y. 2009. Effect of reaction vessel diameter on sonochemical efficiency and cavitation dynamics, Ultrasonics Sonochemistry, 16, 163–168.
- 13. Penaund V., Delgenès J. P., Moletta R. 1999. Thermo-chemical pretreatment of microbial biomass: influence of sodium hydroxide addition on solubilization and anaerobic biodegradability. Enzyme Microb. Technol., 25, 1999, 258–263.
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- 18. Riyadh S. Almukhtar, Asawer A. Alwasiti , Mohammed T. Naser. 2012. Enhancement of Biogas production and organic reduction of sludge by different pretreatment processes, Iraqi Journal of Chemical and Petroleum Engineering,13(1), 19–31.
- 19. Saktaywin W., Tsuno H., Nagare H., Soyama T., Weerapakkaroon J. 2005. Advanced sewage treatment process with excess sludge reduction and phosphorus recovery. Water Res., 39, 902–910.
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- 23. Tak-Hyun Kim, Sang-Ryul Lee, Youn-Ku Nam, Jeongmok Yang, Chulhwan Parkc, Myunjoo Lee. 2009. Disintegration of excess activated sludge by hydrogen peroxide oxidation. Desalination, 246, 275–284.
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- 26. Zawieja I. Wolski P. 2013. Effect of hybrid method of excess sludge disintegration on the increase of their biodegradalibity. Environment Protection Engineering, 39(2), 153–165.
- 27. Zawieja I., Barański M., Małkowski M. 2010. Biogas generation during the anaerobic stabilization of thermally modified sewage sludge,. Engineering and Environmental Protection, 13(3), 2010, 185–196.
- 28. Zawieja I., Wolski P. 2013. Impact of chemical-thermal modification of excess sludge on the generation of volatile fatty acids in the methane fermentation process. Annual Set of Environmental Study, 15(3), 2054–2070.
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-6a659752-63a0-4018-8da8-f3431336aa4a