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Environmentally friendly natural polymers for modification of wood adhesives

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Języki publikacji
EN
Abstrakty
EN
Urea formaldehyde (UF) adhesives are the most commonly used for wood-based panels, but their main disadvantage is an intensive formaldehyde emission. The aim of the investigation was to reduce the release of formaldehyde from UF bonded wood materials by developing and testing new methyl-ol pre-condensate additives with varying ratios of glutaraldehyde and urea. Pre-condensates were modifying by hydrolysates collagen and keratin, polymer polyphenolic molecules of vegetable tannins. Results of laboratory tests confirmed, that natural bio-polymers are suitable additives for lowering of formaldehyde emission from wood products glued with UF adhesive. Methylol pre-condensate additives and their modifications with antioxidant properties significantly reduced formaldehyde emissions from urea-formaldehyde adhesives. The most significant decrease of formaldehyde emission up to 34.7% was achieved with the application sample No. 9 – UF resin + 20% technical flour + 2% (methylol pre-condensate MOD-II+ keratin) + 4% hardener into UF adhesive standard. Formaldehyde emissions were assessed from five-layer plywood according to JIS A 1460 (2001).“Building boards. Desiccator method” Quality of gluing was tested according to standards EN 314-1 and EN 314-2. Tested plywood fulfils the requirements of the standard for class of gluing 1 – they are suitable for application in normal interior environment.
Twórcy
  • VIPO a.s., Partizánske, Gen. Svobodu1069/4, 958 01 Partizánske, Slovakia
autor
  • VIPO a.s., Partizánske, Gen. Svobodu1069/4, 958 01 Partizánske, Slovakia
autor
  • VIPO a.s., Partizánske, Gen. Svobodu1069/4, 958 01 Partizánske, Slovakia
  • Faculty of Wood Sciences and Technology, Technical University, Masaryka 24, 960 53 Zvolen, Slovakia
Bibliografia
  • 1. PŘÍHODA, P., JECH, L. 1988. Hygienické aspekty problematiky formaldehydu unikajícího z výrobků dřevozpracujícího průmyslu. In Syntema – Chemizace dřevo průmyslu. Dom techniky ČSVTS Brno. 1988, p. 45-53.
  • 2. PÜNTERER, A., 1995: The Ecological challenge of producing leather. JALCA 90, 206-215.
  • 3. BULJAN, J. et al. 1997: Mass balance in leather processing. Proceedings of the Centenary Congress of the IULCS, London, 138-156.
  • 4. MATYAŠOVSKÝ, J. et al. 2011: De-chroming of Chromium Shavings without Oxidation to Hazardous Cr6+. JALCA 106, 8-17.
  • 5. MATYAŠOVSKÝ J., KOPNÝ J., MELUŠ P., SEDLIAČIK J., SEDLIAČIK M., 2001: Modifikácia polykondenzačných lepidiel bielkovinami. In: Pokroky vo výrobe a použití lepidiel v drevopriemysle. TU Zvolen, s. 37-42.
  • 6. BLAŽEJ A. et al., 1980: Polyméry v kožiarskom, obuvníckom a galantérnom priemysle. Praha: SNTL, Bratislava: ALFA. p. 279-283.
  • 7. SEDLIAČIK J., SEDLIAČIKOVÁ M., 2009: Innovation tendencies at application of adhesives in wood working industry. In: Annals of Warsaw University of Life Sciences – SGGW. Forestry and Wood Technology, Warszawa, No 69, s. 262-266.
  • 8. ŠMIDRIAKOVÁ, M., SEDLIAČIK J., MATYAŠOVSKÝ J., 2011: Prírodné polyméry na báze modifikovaného kolagénu ako čiastočná náhrada UF lepidla In Adhesives in Woodworking Industry. Zvolen, p.14-20.
  • 9. LANGMAIER, F. at al. 2004. Curing of urea-formaldehyde adhesives with collagen type hydrolysates under acid condition. In Journal of Thermal Analysis and Calorimetry. 2004, 76, p. 1015-1023.
  • 10. MAMINSKI, M.L. at al. 2006. Improved water resistance and adhesive performance of a commercial UF resin blended with glutaraldehyde. In The Journal of Adhesion. 2006, 82, p. 629-641.
  • 11. WANG, S., PIZZI, A. 1997. Succinaldehyde-induced water resistance improvements of UF wood adhesives. In Holz Roh-Werkst 55, p. 9–12.
  • 12. ŠIMON, P., et al. 2001: DSC study of oxidation induction periods. Journal of Thermal Analysis and Calorimetry 64, 813-820.
  • 13. ŠIMON, P., et al. 2006: Induction periods – theory and applications. Journal of Thermal Analysis and Calorimetry 84, 263-270.
Uwagi
Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-67637cf3-937d-4a3d-868c-6128e2e7b193
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