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The necessity to reduce CO2 emission in the environment has encouraged people to search for solutions for its safe capture and storage. Known methods for carbon dioxide mineral sequestration are based primarily on the use of its binding reaction with metal oxides, mainly earth metals. Increasingly important, due to the availability and price, are processes based on the suspension of various wastes such as fly ash, cement dust or furnace slag. Due to the complexity of the mineral sequestration of CO2 in water-waste suspensions, an important issue is to determine the reaction mechanisms. This applies mainly to the initial period of the transformation phase of mineral wastes, and consequently with the occurrence of a number of transition states of ionic equilibria. The mechanisms and reaction rates in the various stages of the process of CO2 mineral sequestration in heterogeneous systems containing selected wastes are defined herein. This paper presents a method of modeling kinetics of this type of process, developed on the basis of the results of the absorption of CO2 thanks to the aqueous suspension of fly ash and cement dust. This allowed for the transfer of obtained experimental results into the mathematical formula, using the invariant function method, used to describe the processes.
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Bibliogr. 22 poz.
Twórcy
autor
- Department of Post-Industrial Sites and Waste Management, Central Mining Institute (Katowice, Poland)
autor
- Institute of Informatics, Silesian University of Technology (Gliwice, Poland)
autor
- Faculty of Mining and Geoengineering, AGH University of Science and Technology (Kraków, Poland)
Bibliografia
- 1. Aksielrud G.A., Pohobenko L.A. (1966): Kinetics of heterogeneous reaction between solid and liquid accompanied by the formation of insoluble solid phase. Journal of Physical Chemistry, Vol. 40, No 2, pp. 346-350 (in Russian).
- 2. Aksielrud G.A., Mołczanow A.D. (1981): Rozpuszczanie ciał stałych (Dissolution of the solids). Warszawa, WNT.
- 3. Antemir A., Gunning P.J., Hills C.D., Carey P.J. (2008): Acceleration carbonation for the treatment of landfilled cement kiln dust. Proceedings of 2nd International Conference on Accelerated Carbonation for Environmental and Materials Engineering, 1–3 October, Roma, Italy, pp. 281–289.
- 4. Baciciocchi R., Costa G., Polettini A., Pomi R., Prigiobbe V. (2009): Comparison of different reaction routes for carbonation of APC residues. Energy Procedia 1, pp. 4851–4856.
- 5. Back M., Kühn M., Stanjek H., Peiffer S. (2008): Reactivity of alkaline lignite fly ashes towards CO2 in water. Environmental Science & Technology No 42, pp. 4520–4526.
- 6. Duchesne J., Reardon E.J. (1998): Determination controls on element concentrations in cement kiln dust leachate. Waste Management Vol. 18, pp. 339–350.
- 7. Huijgen W.J.J., Comans R.N.J. (2006): Carbonation of steel slag for CO2 sequestration: Leaching of products and reaction mechanisms. Environmental Science and Technology Vol. 40, pp. 2790–2796.
- 8. Huntzinger D.H., Eatmon T.D. (2009a): A life assessment of Portland cement manufacturing: comparing tha traditional process with alternative technologies. Journal of Cleaner Produc-tion Vol. 17, pp. 668–675.
- 9. Huntzinger D.H., Gierke J.S., Kawatra S.K., Eisele T.C., Sutter L.L. (2009b): Carbon dioxide sequestration in cement kiln dust trough mineral carbonation. Environmental Science & Technology Vol. 43, pp. 1986–1992.
- 10. Huntzinger D.H., Gierke J.S., Kawatra S.K., Eisele T.C., Sutter L.L. (2009c): Mineral carbonation for carbon sequestration in cement kiln dust from waste piles. Journal of Hazardous Materials, Vol. 168, Iss. 1, pp. 31-37.
- 11. IPCC Special Report on Carbon Dioxide Capture and Storage, part 7. Mineral Carbonation and Industrial uses of Carbon Dioxide. Coordinating Lead Author: Marco Mazzotti, 2005.
- 12. Lackner K.S., Wendt C.H., Butt D.P., Joyce L.E., Sharp D.H. (1995): Carbon dioxide disposal in carbonate minerals. Energy Vol. 20, No 11, pp. 1153–1170.
- 13. Lackner K.S., Butt D.P., Wendt C.H. (1997): Progress of binding CO2 in mineral substrates. Energy Conversion and Management Vol. 38, pp. 259–264.
- 14. Peethamparan S., Olek J., Lovelli J. (2008): Influence of chemical and physical characteristics of cement kiln dust (CKDs) on their hydration behavior and potential suitability for soil stabilization. Cement and Concrete Research 38, pp. 803–815.
- 15. Seifritz W. (1990): CO2 disposal by means of silicates. Nature No 345, pp. 486.
- 16. Świnder H., Uliasz-Bocheńczyk A. (2010): Kinetyczny model sekwestracji dwutlenku węgla w wodnych roztworach wybranych odpadów przemysłowych (Kinetic model of carbon sequestration in aqueous solutions of selected industrial waste). Prace Naukowe GIG. Górnictwo i Środowisko nr 4, pp. 75–85.
- 17. Uliasz-Bocheńczyk A. (2009): Mineralna sekwestracja CO2 w wybranych odpadach (Mineral sequestration of CO2 in selected waste). Studia, Rozprawy, Monografie 153, Wydaw. Instytutu Gospodarki Surowcami Mineralnymi i Energią PAN, Kraków.
- 18. Uliasz-Bocheńczyk A. (2008): Możliwości zastosowania popiołów lotnych ze spalania węgla kamiennego w kotłach wodnych do sekwestracji CO2 w drodze mineralnej karbonatyzacji (Possible applications of fly ash from coal combustion in the boiler water to CO2 sequestration by mineral carbonation). Ochrona Środowiska Vol. 10, pp. 567–574.
- 19. Uliasz-Bocheńczyk A., Cempa M. (2010): A thermodynamic model of CO2 sequestration in aqueous solutions of selected waste. Gospodarka Surowcami Mineralnymi Vol. 26, issue 4, pp. 119–132.
- 20. Uliasz-Bocheńczyk A., Mokrzycki E. (2009): CO2 sequestration with the use of fly ash from hard coal and lignite combustion. Slovak Geological Magazine, spec. issue, pp. 19–22.
- 21. Uliasz-Bocheńczyk A., Piotrowski Z. (2008): Wpływ mineralnej karbonatyzacji na wymywalność zanieczyszczeń (Effect of mineral carbonation in the leachability of pollutants). Rocznik Ochrony Środowiska Vol. 11, part 1, pp. 1083–1094.
- 22. Uliasz-Bocheńczyk A., Mokrzycki E., Piotrowski Z., Pomykała R. eds. (2007): Składowanie CO2 z zawiesinami popiołowo-wodnymi pod ziemią (Storage of CO2 from suspensions of ash and water under the ground). Kraków, Wydaw. IGSMiE PAN.
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Bibliografia
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