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Development of a Nanoscale (Mg/Al)-LDH Coated Waterworks Sludge Sorbent for Efficient Congo Red Dye Removal – Batch Kinetics and Isotherm Studies

Treść / Zawartość
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The study’s aim was to develop a novel sorbent for removing the color Congo red (CR) from water by precipitating (Mg/Al)-layered double hydroxide (LDH) at the nanoscale onto the waterworks sludge surface as a byproduct. To achieve an effective sorbent with the removal of over 91.19%, The utilization of nanoparticles, the addition of 1 g of sludge to 50 mL of water, and a molar ratio of 2 (Mg/Al) were the optimal production conditions for sorbent. In batch experiments, the optimal operating parameters were found to be 0.5 g of adsorbent in 50 mL of CR, pH of CR solution equal to 3, and a contact time of 3 hours at 200 rpm with 25 mg/L dyes. According to the study, the adsorption capacity was 23.576 mg/g. Additionally, the pseudo-second-order and Langmuir models provided accurate descriptions of the sorption data.
Rocznik
Strony
145--155
Opis fizyczny
Bibliogr. 34 poz., rys.
Twórcy
  • Chemical Engineering Department, University of Baghdad, Baghdad, Iraq
  • Chemical Engineering Department, University of Baghdad, Baghdad, Iraq
Bibliografia
  • 1. Ahmed D.N.,Naji L.A., Faisal A.A.H., Al-Ansari N., Naushad M.2020.Waste foundry sand/MgFe-layered double hydroxides composite material for efficient removal of Congo red dye from aqueous solution.Scientific Reports, 10. https://doi.org/10.1038/s41598-020-58866-y
  • 2. Alshammari M., Al Juboury M.F., Naji L.A., Faisal A.A.H., Zhu H., Al-Ansari N., NaushadM.2020. Synthesis of a Novel Composite Sorbent Coated with Siderite Nanoparticles and its Application for Remediation of Water Contaminated with Congo Red Dye.International Journal of Environmental Research, 14, 177–191. https://doi.org/10.1007/s41742-020-00245-6
  • 3. Aoulad El Hadj Ali Y., Ahrouch M., AitLahcen A., DembaN’diaye A., El Yousfi F., Stitou M.2021.Dried sewage sludge as an efficient adsorbent for pollutants: cationic methylene blue removal case study. Nanotechnology for Environmental Engineering, 6, 17. https://doi.org/10.1007/s41204-021-00111-6
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  • 5. Faisal A.A.H., Al-Wakel S.F.A., Assi H.A., Naji L.A., Naushad M.2020a. Waterworks sludge-filter sand permeable reactive barrier for removal of toxic lead ions from contaminated groundwater.Journal of Water Process Engineering, 33, 101112. https://doi.org/10.1016/j.jwpe.2019.101112
  • 6. Faisal A.A.H., Jasim H.K., Naji L.A., Naushad M., Ahamad T. 2020b.Cement kiln dust-sand permeable reactive barrier for remediation of groundwater contaminated with dissolved benzene.Separation Science and Technology, 1–14. https://doi.org/10.1080/01496395.2020.1746341
  • 7. Faisal A.A.H., Naji L.A., Chaudhary A.A., Saleh B.2021.Removal of ammoniacal nitrogen from contaminated groundwater using waste foundry sand in the permeable reactive barrier.Desalination and Water Treatment, 230, 227–239. https://doi.org/10.5004/dwt.2021.27436
  • 8. Faisal A.A.H., Ramadhan Z.K., Al-Ansari N., Sharma G., Naushad M., Bathula C.2022.Precipitation of Mg/Fe-CTAB - Layered double hydroxide nanoparticles onto sewage sludge for producing novel sorbent to remove Congo red and methylene blue dyes from aqueous environment.Chemosphere, 291, 132693. https://doi.org/10.1016/j.chemosphere.2021.132693
  • 9. Finish Q.G., Naife T.M.2021.Adsorption Desulfurization of Iraqi Light Naphtha Using Metals Modified Activated Carbon.Journal of Engineering, 27, 24–41. https://doi.org/10.31026/j.eng.2021.07.03
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  • 14. Jawad N., NaifeM.T.2022.Mathematical Modeling and Kinetics of Removing Metal Ions from Industrial Wastewater.Iraqi Journal of Chemical and Petroleum Engineering, 23, 59–69. https://doi.org/10.31699/IJCPE.2022.4.8
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  • 18. Ma J., Lei Y., Khan M.A., Wang F., Chu Y., Lei W., Xia M., Zhu S.2019.Adsorption properties, kinetics & thermodynamics of tetracycline on carboxymethyl-chitosan reformed montmorillonite.International Journal of Biological Macromolecules, 124, 557–567. https://doi.org/10.1016/j.ijbiomac.2018.11.235
  • 19. Majeed N.S.2017.Inverse fluidized bed for chromium ions removal from wastewater and produced water using peanut shells as adsorbent.in 2017 International Conference on Environmental Impacts of the Oil and Gas Industries: Kurdistan Region of Iraq as a Case Study EIOGI, IEEE, 9–14. https://doi.org/10.1109/EIOGI.2017.8267617.
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  • 22. Othmani M., Aissa A., Bac C.G., Rachdi F., Debbabi M.2013.Surface modification of calcium hydroxyapatite by grafting of etidronic acid.Applied Surface Science, 274, 151–157. https://doi.org/10.1016/j.apsusc.2013.03.002
  • 23. Pengthamkeerati P., Satapanajaru T., Chatsatapattayakul N., Chairattanamanokorn P., Sananwai N.2010.Alkaline treatment of biomass fly ash for reactive dye removal from aqueous solution.Desalination. https://doi.org/10.1016/j.desal.2010.05.050
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  • 27. Saha S., Ray S., Ghosh S., Chakraborty J.2018.pH‐dependent facile synthesis of CaAl‐layered double hydroxides and its effect on the growth inhibition of cancer cells. Journal of the American Ceramic Society, 101, 3924–3935. https://doi.org/10.1111/jace.15555
  • 28. Salleh M.A.M., Mahmoud D.K., Karim W.A.W.A., Idris A.2011. Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review. Desalination, 280, 1–13. https://doi.org/10.1016/j.desal.2011.07.019
  • 29. Thabede P.M., Shooto N.D., Naidoo E.B.2020.Removal of methylene blue dye and lead ions from aqueous solution using activated carbon from black cumin seeds.South African Journal of Chemical Engineering, 33, 39–50.
  • 30. Waleed Khalid M., Salman D.S.2019.Adsorption of Chromium Ions on Activated Carbon Produced from Cow Bones.Iraqi Journal of Chemical and Petroleum Engineering, 20, 23–32. https://doi.org/10.31699/IJCPE.2019.2.4
  • 31. Wang S., Ning H., Hu N., Huang K., Weng S., Wu X., Wu L., Liu J., Alamusi. 2019.Preparation and characterization of graphene oxide/silk fibroin hybrid aerogel for dye and heavy metal adsorption. Compos. Part., 163, 716–722.
  • 32. Wawrzkiewicz M., Hubicki Z.2009.Removal of tartrazine from aqueous solutions by strongly basic polystyrene anion exchange resins.Journal of Hazardous Materials, 164, 502–509. https://doi.org/10.1016/j.jhazmat.2008.08.021
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  • 34. Yagub M.T., Sen T.K., Ang H.M.2012.Equilibrium, kinetics, and thermodynamics of methylene blue adsorption by pine tree leaves.Water, Air, and Soil Pollution. https://doi.org/10.1007/s11270-012-1277-3
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-6747d268-8ab4-411a-b12d-d5634f61d2b2
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