Utilization of Calcined Gypsum in Water and Wastewater Treatment: Removal of Phenol

Igwegbe, Chinenye Adaobi; Al-Rawajfeh, Aiman Eid; Al-Itawi, H.I.; Sharadqah, S.; Al-Qazaqi, Shahd; Abu Hashish, Esraa; Al-Qatatsheh, Malak; Sillanpaa, Mika

doi:10.12911/22998993/108694

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Tytuł artykułu

Utilization of Calcined Gypsum in Water and Wastewater Treatment: Removal of Phenol

Autorzy

Igwegbe Chinenye Adaobi , Al-Rawajfeh Aiman Eid , Al-Itawi H.I. , Sharadqah S. , Al-Qazaqi Shahd , Abu Hashish Esraa , Al-Qatatsheh Malak , Sillanpaa Mika

Treść / Zawartość

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Identyfikatory

DOI

10.12911/22998993/108694

Warianty tytułu

Języki publikacji

Abstrakty

The release of phenol-containing effluents above the phenol permissible limit has triggered a lot of concern over the world due to their toxic nature. The adsorptive potential of gypsum on the removal of phenol was investigated. The effect of gypsum loading (0.5–3 g), contact time (2.5–20 min) and solution temperature (298 to 318 K) on the removal of phenol by gypsum was studied at neutral pH. The thermodynamics of the adsorption process was also studied. The kinetic data were fitted into the pseudo-second-order, Elovich, and intraparticle diffusion models. The removal efficiency of phenol increased along with the mass of gypsum, contact time and temperature. The results of the thermodynamics study indicate that the adsorption process is spontaneous and endothermic in nature. The change in free energy (ΔG⁰) was found to increase with temperature. The values of the estimated ΔG⁰ suggest that the phenol adsorption on gypsum is a physical adsorption process. Additionally, the kinetic data fitted best into the pseudo-second-order than the other kinetic models. This study proved that phenol can be used effectively for the reduction of phenol concentrations in water and wastewater.

Słowa kluczowe

calcined gypsum phenol removal thermodynamics parameters

Wydawca

Polskie Towarzystwo Inżynierii Ekologicznej
Lublin University of Technology

Czasopismo

Journal of Ecological Engineering

Rocznik

2019

Tom

Vol. 20, nr 7

Strony

1--10

Opis fizyczny

Bibliogr. 78 poz., rys., tab.

Twórcy

autor

Igwegbe Chinenye Adaobi

Department of Chemical Engineering, Nnamdi Azikiwe University, Awka, Nigeria

autor

Al-Rawajfeh Aiman Eid

aimanr@yahoo.com

Tafila Technical University (TTU), Department of Chemical Engineering, P.O. Box 179, 66110 Tafila, Jordan

autor

Al-Itawi H.I.

Tafila Technical University (TTU), Department of Chemical Engineering, P.O. Box 179, 66110 Tafila, Jordan

autor

Sharadqah S.

Tafila Technical University (TTU), Department of Chemical Engineering, P.O. Box 179, 66110 Tafila, Jordan

autor

Al-Qazaqi Shahd

Tafila Technical University (TTU), Department of Chemical Engineering, P.O. Box 179, 66110 Tafila, Jordan

autor

Abu Hashish Esraa

Tafila Technical University (TTU), Department of Chemical Engineering, P.O. Box 179, 66110 Tafila, Jordan

autor

Al-Qatatsheh Malak

Tafila Technical University (TTU), Department of Chemistry, Tafila, Jordan

autor

Sillanpaa Mika

Department of Green Chemistry, Lappeenranta University of Technology, Sammonkatu 12, FI-50130 Mikkeli, Finland

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