Paracetamol and ibuprofen removal from aqueous solutions by ozonation and photochemical processes

• Autorzy: Trousil V. , Palarčík J. , Blažková Z. , Kořínková J. , Machalický O. , Cakl J.

Identyfikatory

DOI

10.5277/epe180411

• Języki publikacji: EN

Abstrakty

EN

The comparative experimental study has been performed of removal of pharmaceuticals such as paracetamol and ibuprofen from aqueous solution by ozonation and photochemical degradation in several types of reactors. Ozone, oxygen, and hydrogen peroxide were used as oxidizing agents. Heterogeneous photocatalysis was carried out in the presence of anatase type TiO₂ catalyst. To determine the amount of radiation emitted by the UV lamps and transferred into the reactor, chemical feroxioxalate actinometric experiments were performed. The degree of the pollutant removal was monitored by HPLC, COD, BOD₅, and TOC. An ecotoxic biological test of process products with Parachlorella kessleri was also evaluated. The results indicate that the removal of both pharmaceuticals is most effective by heterogeneous photocatalysis. In the UV processes, the degradation rate increased considerably when H₂O₂ was added. However, the addition of peroxide into the ozonation system improved the ozonation only slightly. All products of the processes tested showed improved biodegradability according to the BOD₅/COD ratio and low toxicity to Parachlorella kessleri.

Słowa kluczowe

EN

Parachlorella kessleri; paracetamol; ibuprofen; heterogeneous photocatalysis

PL

Parachlorella kessleri; paracetamol; ibuprofen; fotokataliza heterogeniczna

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Environment Protection Engineering
• Rocznik: 2018
• Tom: Vol. 44, nr 4
• Strony: 159--175
• Opis fizyczny: Bibliogr. 23 poz., tab., rys.

Twórcy

autor

Trousil V.

• University of Pardubice, Faculty of Chemical Technology, Institute of Environmental and Chemical Engineering, Pardubice, 532 10, Czech Republic

autor

Palarčík J.

• University of Pardubice, Faculty of Chemical Technology, Institute of Environmental and Chemical Engineering, Pardubice, 532 10, Czech Republic

autor

Blažková Z.

• University of Pardubice, Faculty of Chemical Technology, Institute of Environmental and Chemical Engineering, Pardubice, 532 10, Czech Republic

autor

Kořínková J.

• University of Pardubice, Faculty of Chemical Technology, Institute of Environmental and Chemical Engineering, Pardubice, 532 10, Czech Republic

autor

Machalický O.

• University of Pardubice, Faculty of Chemical Technology, Institute of Organic Chemistry and Technology, Pardubice, 532 10, Czech Republic

autor

Cakl J.

• University of Pardubice, Faculty of Chemical Technology, Institute of Environmental and Chemical Engineering, Pardubice, 532 10, Czech Republic

Bibliografia

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).